A numerical model of the partitioning of trace chemical solutes during drop freezing

Partitioning of volatile chemicals among the gas, liquid, and solid phases during freezing of liquid water in clouds can impact trace chemical distributions in the troposphere and in precipitation. We describe here a numerical model of this partitioning during the freezing of a supercooled liquid drop. Our model includes the time-dependent calculation of the coupled processes of crystallization kinetics, heat transport, and solute mass transport, for a freezing hydrometeor particle. We demonstrate the model for tracer partitioning during the freezing of a 1000 μm radius drop on a 100 μm ice substrate, under a few ambient condition scenarios. The model effectively simulates particle freezing and solute transport, yielding results that are qualitatively and quantitatively consistent with previous experimental and theoretical work. Results suggest that the ice shell formation time is governed by heat loss to air and not by dendrite propagation, and that the location of ice nucleation is not important to freezing times or the effective partitioning of chemical solutes. Even for the case of nucleation at the center of the drop, we found that dendrites propagated rapidly to form surface ice. Freezing then proceeded from the outside in. Results also indicate that the solid-liquid interfacial surface area is not important to freezing times or the effective partitioning of chemical solutes, and that the rate aspects of trapping are more important than equilibrium solid-liquid partitioning to the effective partitioning resulting from freezing.     

A mass ratio limit for primordial black holes

We augment our scenario for the formation of astronomical objects from macroscopic superstrings by the assumption that the central matter keeps its identity in the fragmentation. From the condition that the angular momentum per mass squared of this matter should be less than the Kerr limit G/c, we obtain upper limits for the ratio of the mass of central black holes M(BH) to the mass M of the host object. This limit is M(BH)/M ≈ 0.001, and, expressed in observed quantities, approximately M(BH)/M ≈ σ²/(v · c) where σ is the r.m.s. velocity, v the rotational velocity and c the velocity of light. The valuesM(BH) agree with the observed behaviour both in order of magnitude and in the variation with velocity dispersion. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Observations of OH maser lines at an 18-cm wavelength in 9P/Temper1 and Lulin C/2007 N3 comets with RT-22 at the Crimean Astrophysical Observatory

Investigations on OH maser lines in comets have been performed with the RT-22 at CrAO. The results of observations of 9P/Temper1 and Lulin C/2007 N3 comets in the OH molecule line at a wavelength of 18 cm are presented. An original technique for observation data analysis has been developed. The gas production rate of OH molecules in these comets is estimated.     

Numerical simulation of the interaction between two high-energy plasma bunches in the ionosphere

The 3D MHD algorithm developed by us has been adapted to modeling the interaction between two plasma bunches in the ionosphere, mainly in order to sufficiently correctly describe the physics of the interaction between two plasma regions with regard to the ionospheric inhomogeneity and the geomagnetic field action. Modeling has been performed for several versions of location of the plasma region centers.     

Archaeal Communities of Frozen Quaternary Sediments of Marine Origin on the Coast of Western Spitsbergen

Izvestiya, Atmospheric and Oceanic Physics - The archaeal composition of permafrost samples taken during the drilling of frozen marine sediments in the area of the Barentsburg coal mine on the east...     

Rock salt mass in the Paleoproterozoic sequence of the Onega trough in Karelia (from the Onega parametric well data)

A thick (200 m) rock salt mass covering Late Archean granitoids was exposed for the first time in the Early Proterozoic volcanogenic-sedimentary formations in the Onega trough of the east Baltic Shield by the Onega parametric well. The mineral composition of salts, their geochemical features, and the isotopic composition of carbonate carbon and oxygen have been studied. After fluid inclusions present in salts, their metamorphism temperature and isotopic composition of helium and argon were determined. The obtained results give evidence of the fact that rock salts and magnesites associated with them were formed in an evaporate basin with participation of deep crustal processes. The age of the underlying granitoids (2.716 ± 9 Ma) is determined using the Pb—Pb method.     

The Karoo Basin of South Africa: type basin for the coal-bearing deposits of southern Africa

The coal-bearing sediments and coal seams of the Karoo Basin, Southern Africa are described and discussed. The Karoo Basin is bounded on its southern margin by the Cape Fold Belt, onlaps onto the Kaapvaal Craton in the north and is classified as a foreland basin. Coal seams are present within the Early Permian Vryheid Formation and the Triassic Molteno Formation.The peats of the Vryheid Formation accumulated within swamps in a cool temperate climatic regime. Lower and upper delta plain, back-barrier and fluvial environments were associated with peat formation. Thick, laterally extensive coal seams have preferentially accumulated in fluvial environments. The coals are in general inertinite-rich and high in ash. However, increasing vitrinite and decreasing ash contents within seams occur from west to east across the coalfields. The Triassic Molteno coal seams accumulated with aerially restricted swamps in fluvial environments. These Molteno coals are thin, laterally impersistent, vitrinite-rich and shaly, and formed under a warm temperate climatic regime.Palaeoclimate, depositional systems, differential subsidence and basin tectonics influence to varying degrees, the maceral content, thickness and lateral extent of coal seams. However, the geographic position of peat-forming swamps within a foreland basin, coupled with basin tectonics and differential subsidence are envisaged as the primary controls on coal parameters. The Permian coals are situated in proximal positions on the passive margin of the foreland basin. Here, subsidence was limited which enhanced oxidation of organic matter and hence the formation of inertinitic coals. The coals in this tectonic setting are thick and laterally extensive. The Triassci coals are situated within the tectonically active foreland basin margin. Rapid subsidence and sedimentation rates occurred during peat formation which resulted in the preservation of thin, laterally impersistent, high ash, vitrinite-rich, shaly coals.