Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m2. The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.
A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.
Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic 187Os/188Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.
A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.
If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events. 相似文献
Scottish Dinantian transitional to mildly alkaline volcanism is represented by abundant outcrops in the Midland Valley, Southern Uplands and Highlands provinces. Dinantian volcanic rocks from Kintyre in the Scottish Highlands range in composition from basalt through basaltic hawaiite, hawaiite, mugearite and benmoreite to trachyte, the compositions of the evolved types being largely due to differentiation from the basaltic parents.Recent geochemical investigations of Scottish Caledonian granitoids, Siluro-Devonian Old Red Sandstone (ORS) lavas and xenolith suites from numerous vents and dykes of Permo-Carboniferous to Tertiary age have revealed that the Scottish crust and upper mantle both increase in age and are increasingly enriched in incompatible elements towards the north and northwest. The upper mantle and lower crust below the Highlands province are therefore largely considered to be more enriched and in parts older than those below the Midland Valley and Southern Uplands. Dinantian alkali basalts from these latter two provinces have Nd values predominantly in the range +3 to +6, initial 87Sr/86Sr values of 0.7029–0.7041 and 207Pb/ 204Pb values of 15.48–15.60. However, similar basalts from Kintyre and Arran in the Highlands have lower Nd (+0.1 to +3.4) and 207Pb/204Pb (for given 206Pb/204Pb ratios; 15.49–15.51) and slightly higher 87Sr/86Sr (0.7033–0.7046). This regional variation correlates well with the differences seen between Midland Valley and Highland magmas in the ORS calc-alkaline suite (Thirlwall 1986) and it is suggested that both the ORS and Dinantian basic rocks are derived from similar types of mantle, although no lithospheric slab component is present in the later Dinantian suites. Isotopically-distinct portions of mantle therefore appear to have been present below the Highland and Midland Valley-Southern Upland provinces from at least Caledonian to Carboniferous times. The combined incompatible element and Sr-Nd-Pd isotopic evidence from Kintyre and Arran basaltic rocks does not allow unequivocal distinction between a lithospheric mantle and a sublithospheric mantle source. The observed correlation between isotopic composition of Dinantian basalts and the chemical composition of the lithosphere, together with the apparent involvement of long-term separated source reservoirs suggests that Kintyre and Arran lavas were derived largely from a lithospheric mantle source. On the other hand, the isotopic enrichment of Kintyre basaltic rocks is not extreme; trace element and isotopic compositions are still comparable to modem OIB. Sublithospheric mantle could therefore also be a viable source for Kintyre and Arran Dinantian volcanism. 相似文献
The Huaniushan granite is located at the Beishan orogenic belt, northwestern China. At the contact zone between the granite and marble, a hydrothermal Pb-Zn and skarn Au deposit is formed. LA-ICP-MS zircon U-Pb dating yielded a weighted mean 206Pb/238U age of 229.5±2.6 Ma (MSDW=0.93) for the Huaniushan granite, imply-ing its Late Triassic intrusion. Geochemistry analyses show that the Huaniushan granite is enriched in Si, K, Na, and REE, and depleted in Mg and Ca, with contents of SiO2 (70.8% to 74.4%), Na2O+K2O (8.8% to 10.2%), CaO (0.93% to 1.44%), and MgO (0.14% to 0.48%). REE is characterized by obvious negative Eu anomaly. Rb, Th, U, K, Pb, Nb, Zr and Hf elements are rich in the granite while Ba, Sr, P, Ti and Eu are deplete. The granite has a high (Zr+Nb+Ce+Y) abundance and 104 Ga/Al ratios. Petrology, major and trace elements data all indicate that the Hua-niushan granite is A-type granite which intruded in a post-collisional extensional tectonic setting. The magma was dominantly sourced from partial melting of crustal intermediate-felsic igneous rocks. Intensive magmatic activities and Au-Cu-Mo mineralization occurred throughout the Beishan orogenic belt during the period from ca. 240 to 220 Ma. 相似文献
The fluorescence properties of groundwaters from sites in two UK aquifers, the Penrith Sandstone of Cumbria and the Sherwood Sandstone of South Yorkshire, were investigated using excitation–emission matrix (EEM) fluorescence spectroscopy. Both aquifers are regionally important sources of public supply water and are locally impacted by pollution. The Penrith Sandstone site is in a rural setting while the Sherwood Sandstone site is in suburban Doncaster. Fluorescence analysis of samples from discrete sample depths in the Penrith Sandstone shows decreasing fulvic-like intensities with depth and also shows a good correlation with CFC-12, an anthropogenic groundwater tracer. Tryptophan-like fluorescence centres in the depth profile may also provide evidence of rapid routing of relatively recent applications of organic slurry along fractures. Fluorescence analysis of groundwater sampled from multi-level piezometers installed within the Sherwood Sandstone aquifer also shows regions of tryptophan-like and relatively higher fulvic-like signatures. The fluorescence intensity profile in the piezometers shows tryptophan-like peaks at depths in excess of 50 m and mirrors the pattern exhibited by microbial species and CFCs highlighting the deep and rapid penetration of modern recharge due to rapid fracture flow. Fluorescence analysis has allowed the rapid assessment of different types and relative abundances of dissolved organic matter (DOM), and the fingerprinting of different sources of organic C within the groundwater system. The tryptophan:fulvic ratios found in the Penrith Sandstone were found to be between 0.5 and 3.0 and are characteristic of ratios from sheep waste sources. The Sherwood Sandstone has the lowest ratios (0.2–0.4) indicating a different source of DOM, most likely a mixture of terrestrial and microbial sources, although there is little evidence of pollution from leaking urban sewage systems. Results from these two studies suggest that intrinsic fluorescence may be used as a proxy for, or complementary tool to, other groundwater investigation methods in helping provide a conceptual model of groundwater flow and identifying different sources of DOM within the groundwater system. 相似文献
The three-dimensional nonlinear quasi-geostrophic potential vorticity equation is reduced to a linear form in the stream function in spherical coordinates for the permanent wave solutions consisting of zonal wavenumbers from 0 to n and rn vertical components with a given degree n. This equation is solved by treating the coefficient of the Coriolis parameter square in the equation as the eigenvalue both for sinusoidal and hyperbolic variations in vertical direction. It is found that these solutions can represent the observed long term flow patterns at the surface and aloft over the globe closely. In addition, the sinusoidal vertical solutions with large eigenvalue G are trapped in low latitude, and the scales of these trapped modes are longer than 10 deg. lat. even for the top layer of the ocean and hence they are much larger than that given by the equatorial β-plane solutions. Therefore such baroclinic disturb-ances in the ocean can easily interact with those in the atmosphere.Solutions of the shallow water potential vorticity equation are treated in a similar manner but with the effective depth H = RT / g taken as limited within a small range for the atmosphere.The propagation of the flow energy of the wave packet consisting of more than one degree is found to be along the great circle around the globe both for barotropic and for baroclinic flows in the atmosphere. 相似文献
The Dynamical-Statistical-Analog Ensemble Forecast model for landfalling tropical cyclones (TCs) precipitation (DSAEF_LTP) utilises an operational numerical weather prediction (NWP) model for the forecast track, while the precipitation forecast is obtained by finding analog cyclones, and making a precipitation forecast from an ensemble of the analogs. This study addresses TCs that occurred from 2004 to 2019 in Southeast China with 47 TCs as training samples and 18 TCs for independent forecast experiments. Experiments use four model versions. The control experiment DSAEF_LTP_1 includes three factors including TC track, landfall season, and TC intensity to determine analogs. Versions DSAEF_LTP_2, DSAEF_LTP_3, and DSAEF_LTP_4 respectively integrate improved similarity region, improved ensemble method, and improvements in both parameters. Results show that the DSAEF_LTP model with new values of similarity region and ensemble method (DSAEF_LTP_4) performs best in the simulation experiment, while the DSAEF_LTP model with new values only of ensemble method (DSAEF_LTP_3) performs best in the forecast experiment. The reason for the difference between simulation (training sample) and forecast (independent sample) may be that the proportion of TC with typical tracks (southeast to northwest movement or landfall over Southeast China) has changed significantly between samples. Forecast performance is compared with that of three global dynamical models (ECMWF, GRAPES, and GFS) and a regional dynamical model (SMS-WARMS). The DSAEF_LTP model performs better than the dynamical models and tends to produce more false alarms in accumulated forecast precipitation above 250 mm and 100 mm. Compared with TCs without heavy precipitation or typical tracks, TCs with these characteristics are better forecasted by the DSAEF_LTP model. 相似文献