Normative quartz as an indicator of the mass transfer intensity during the postmagmatic alteration of the Botuobinskaya pipe kimberlites (Yakutia)

The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO₂–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds.     

Melt inclusions in eclogite garnet: experimental study of natural processes

Experiment with poikilitic garnet at 3 GPa and 800 °C showed dehydration melting of its mineral inclusions, which is accompanied by the growth of (sub)euhedral garnet crystals inside the inclusion and/or xenomorphic garnets replacing the host mineral. The newly formed and host garnets differ drastically in composition. The inclusion surface is complicated by specific wedge-like protrusions or thin branches composed of melt or its crystallization products. The above features have been discovered in polymineral inclusions in garnet from low-temperature (650 °C) eclogite from the Yukon-Tanana terrane, Canada. The inclusions are interpreted as the crystallization products of in situ formed melt.     

Climatic changes and alluvial-sedimentation settings in southeastern Transbaikalia in the Middle-Late Holocene (by the example of the Ilya floodplain)

Climatic changes in southeastern Transbaikalia in the Middle and Late Holocene and their influence on alluvial sedimentation environments are reconstructed from the results of study of the Ilya floodplain sediments (Alkhanai National Park). At the beginning of the Subboreal period, the regional climate became more arid, which led to a significant increase in steppe species communities in the landscapes. Intense climate aridization also took place at the beginning and at the end of the Subatlantic period of the Holocene. The alluvial-sedimentation rate increased during the weakening of aridization and decreased during cooling and the intensification of aridization. The obtained regional data are compared with data on the adjacent areas and the global climatic changes in the Northern Hemisphere.     

Intrayear irregularities of the Earth’s rotation

The methods of celestial mechanics can be used to construct a mathematical model for the perturbed rotational motions of the deformable Earth that can adequately describe the astrometric measurements of the International Earth Rotation Service (IERS). This model describes the gravitational and tidal influences of the Sun and Moon. Fine resonant interactions of long-period zonal tides (annual, semiannual, monthly, and biweekly) with the diurnal and semidiurnal tides are revealed. These interactions can be reliably confirmed via a spectral analysis of the IERS data. Numerical modeling of tidal irregularities of the Earth’s axial rotation was carried out, focusing on the analysis and forecasting of variations of the day length occurring within short time intervals of a year or shorter (intrayear variations).     

Timescales for mechanisms for the dynamical evolution of open star clusters

We have obtained the stellar velocity dispersion in three mutually perpendicular directions in the halos and cores of clusters as a function of time for several non-stationary open-cluster models. During the dynamical evolution of the open-cluster models, the velocity dispersions undergo oscillations that do not decay during 5–10 violent-relaxation timescales, τ _vr . We estimated the time for synchronization of the rotation of the open-cluster models and their motion around the center of the Galaxy, t _s , which, depending on the model parameters, is t _s ? (5–27)τ _vr . Synchronization mechanisms for the models are discussed. The disruption of the systems in the force field of the Galaxy is strongly affected by tidal friction. We have also estimated the time for the formation of a spherical stellar-velocity distribution in the cluster models, t _σ ? (6 ? 25)τ _vr . The impact of instability in the stellar motions in a cluster on the formation of a spherical velocity distribution in the open-cluster models is discussed. We have noted a tendency for a weakening of the dependence of the coarse phase density of the cluster on small initial perturbations of the stellar phase coordinates in the model cluster cores for times about five times longer than the violent-relaxation time.     

Mirdita Zone ophiolites and associated sediments in Albania reveal Neotethys Ocean origin

The Mirdita Ophiolite Zone in Albania is associated with widespread mélanges containing components of up to nappe-size. We dated matrix and components of the mélange by radiolarians, conodonts, and other taxa. The components consist of radiolarites, pelagic limestones and shallow-water limestones, all of Triassic age, as well as ophiolites. Triassic radiolarite as a primary cover of ophiolite material proves Middle Triassic onset of Mirdita ocean-floor formation. The mélange contains a turbiditic radiolarite-rich matrix (“radiolaritic flysch”), dated as Late Bajocian to Early Oxfordian. It formed as a synorogenic sediment during west-directed thrusting of ophiolite and sediment-cover nappes representing ocean floor and underplated fragments of the western continental margin. The tectonic structures formed during these orogenic events (“Younger Kimmeridian or Eohellenic Orogeny”) are sealed by Late Jurassic platform carbonates. The geological history conforms with that of the Inner Dinarides and adjoining areas; we therefore correlate the Mirdita-Pindos Ophiolite Zone with the Vardar Zone and explain its present position by far-distance west-directed thrusting.     

Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.     

Spatiotemporal Patterns of Subtidal Benthic Microalgal Biomass and Community Composition in Galveston Bay,Texas, USA

Many Gulf of Mexico estuaries have low ratios of water volume to bottom surface area, and benthic processes in these systems likely have a major influence on system structure and function. The purpose of this study was to determine the spatiotemporal distribution of biomass and community composition of subtidal benthic microalgal (BMA) communities in Galveston Bay, TX, USA, compare BMA community composition and biomass to phytoplankton in overlying waters, and estimate the potential contribution of BMA to the trophodynamics in this shallow, turbid, subtropical estuary. The estimates of BMA biomass (mean = 4.21 mg Chl a m⁻²) for Galveston Bay were within the range of the reported values for similar Gulf of Mexico estuaries. BMA biomass in the central part of the bay was essentially homogeneous, whereas biomass at the seaward and upper bay ends of the transect were significantly lower. Peridinin, fucoxanthin, and alloxanthin were the three carotenoids with the highest concentrations, with fucoxanthin having the highest mean concentration (1.82 mg m⁻²). The seaward and landward ends of the transect differed from the central region of the bay with respect to the relative abundances of chlorophytes, cyanobacteria, and photosynthetic bacteria. Benthic microalgal community composition also showed a gradual shift over time due to changes in the relative abundances of photosynthetic bacteria, cryptophytes, dinoflagellates, and cyanobacteria. Major changes in community composition occurred in the spring months (March to April). On an areal basis, BMA biomass in Galveston Bay occurred at minor concentrations (16.5%) relative to phytoplankton. Furthermore, the concentrations of carotenoid pigments for phytoplankton and BMA (fucoxanthin, alloxanthin, and zeaxanthin) were correlated (r = 0.48 to 0.61), suggesting a close linkage between microalgae in the water column and sediments. The contribution of BMA to the primary productivity of the deeper waters (>2 m) of Galveston Bay is probably very small in comparison to shallower waters along the bay margins. The significant similarities in the community composition of phytoplankton and BMA illustrate the potential importance of deposition and resuspension processes in this turbid, shallow estuary.