40Ar/39Ar and oxygen isotope studies of polymetamorphism from Tinos Island, Cycladic blueschist belt, Greece

Abstract Petrological, oxygen isotope and ⁴⁰Ar/³⁹Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some ⁴⁰Ar/³⁹Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ¹⁸O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ¹⁸O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion.     

Shakedown in layered pavements under moving surface loads

Elastic–plastic deformations in pavements consisting of layers of different frictional materials are investigated. The upper bound, kinematic shakedown theorem is used to obtain estimates of the critical shakedown loads. Fully general three-dimensional deformations are considered. The influence of the loading distribution, interactions between loads, and the effect of varying the thickness, stiffness and strength of the layers are explored. Consequences of this investigation for particular existing designs of flexible pavements are investigated. In particular, it is found that the strength of the subgrade has no effect on the magnitude of the critical shakedown load.     

Upscaling of elastic properties for large scale geomechanical simulations

Large scale geomechanical simulations are being increasingly used to model the compaction of stress dependent reservoirs, predict the long term integrity of under‐ground radioactive waste disposals, and analyse the viability of hot‐dry rock geothermal sites. These large scale simulations require the definition of homogenous mechanical properties for each geomechanical cell whereas the rock properties are expected to vary at a smaller scale. Therefore, this paper proposes a new methodology that makes possible to define the equivalent mechanical properties of the geomechanical cells using the fine scale information given in the geological model. This methodology is implemented on a synthetic reservoir case and two upscaling procedures providing the effective elastic properties of the Hooke's law are tested. The first upscaling procedure is an analytical method for perfectly stratified rock mass, whereas the second procedure computes lower and upper bounds of the equivalent properties with no assumption on the small scale heterogeneity distribution. Both procedures are applied to one geomechanical cell extracted from the reservoir structure. The results show that the analytical and numerical upscaling procedures provide accurate estimations of the effective parameters. Furthermore, a large scale simulation using the homogenized properties of each geomechanical cell calculated with the analytical method demonstrates that the overall behaviour of the reservoir structure is well reproduced for two different loading cases. Copyright © 2004 John Wiley & Sons, Ltd.     

Preliminary organic petrography of Palaeozoic rocks from the Grand Banks,Newfoundland

Samples of lower Palaeozoic bedrock from the Grand Banks of Newfoundland were examined using reflected light microscopy and Rock-Eval pyrolysis. These samples contained organic material which included bitumen (structureless organic material), acritarchs, chitinozoa, scolecodonts and graptolites. The reflectance of the organic material increased from acritarchs towards graptolites with bitumen showing a wide range of reflectance. Multiple phases of oil migration through one sample were inferred by examination of the bitumens: the lowest reflecting being more recent than the highest reflecting bitumen. Combined reflectance and Rock-Eval analysis indicate that these samples are mature to overmature. The two oldest samples (Arenig-Llanvirn, Ordovician) are assessed as mature and as having potential for generation of liquid hydrocarbons, but must be considered as mainly gas prone.     

Hydrodynamic control of phytoplankton in low salinity waters of the James River estuary,Virginia, U.S.A.

Autotrophic biomass and productivity as well as nutrient distributions and phytoplankton cell populations in the James River estuary, Virginia, were quantified both spatially and temporally over a 17-month period. Emphasis was placed on the very low salinity region of the estuary in order to gain information on the fate of freshwater phytoplankters. Differing amounts of freshwater plant biomass are advected into the estuary as living material, DOC or POC and the demonstrated variability of this input must play an important role in marine biogeochemical cycling.Late summer and fall maxima in both chlorophyll a and the photosynthetic production of particulate organic carbon in very low salinity regions were inversely correlated with river discharge.During periods of low river discharge greater than 50% of the chlorophyll a biomass measured at 0‰ disappeared within a narrow range of salinity (0–2‰). Cell enumeration data suggest that species introduced from the freshwater end-member tend to comprise the bulk of the biomass removed. Confounding factors, which may contribute to the regulation of both the abundance and species of phytoplankters mid-river, include the flocculation of colloidal material with phytoplankton cells, the presence of the turbidity maximum and the growth of endemic phytoplankton populations.An inverse relationship exists between the phytoplankton abundance in very low salinity waters and the abundance of biomass measured in the lower portion of the river (estuary). Thus, autotrophic production in the fresh and very low salinity areas may indirectly regulate the onset on the spring bloom in the estuary by controlling the amount of nutrients available.     

A dated cave sediment record of Pleistocene transgressions on Berry Head,Southwest England

Berry Head, a limestone headland in Torbay, southwest England, exhibits a series of subaerial marine erosion platforms and raised beaches spanning an altitude range of 97 m. Solution caves on the headland show preferred horizontal development at elevations that are correlated with the marine erosion platforms, and developed in a marine/freshwater mixing zone whose position was controlled by high sea-level still-stands. Corbridge Cave in Berry Head Quarry lies below the raised beaches in Torbay, and contains evidence of three marine transgressions in the form of fine-grained marine ponding deposits with a marine microfauna. Uranium-series dating of intercalated speleothems indicates that a transgression during oxygen isotope stage 5e reached an elevation of 5.8 m OD, while an earlier transgression (probably during stage 7) reached at least 7.2 m OD. These findings are used to constrain possible interpretations of the aminostratigraphy of raised beaches in Southwest Britain, and a correlation of the Unnamed Stage of Bowen, Sykes, Reeves, Miller, Andrews, Brew and Hare with oxygen isotope stage 5e is proposed.     

Cokriging nonstationary data

Universal cokriging is used to obtain predictions when dealing with multivariate random functions. An important type of nonstationarity is defined in terms of multivariate random functions with increments which are stationary of orderk. The covariance between increments of different variables is modeled by means of the pseudo-cross-covariance function. Criteria are formulated to which the parameters of pseudo-cross-covariance functions must comply so as to ensure positive-definiteness. Cokriging equations and the induced cokriging equations are given. The study is illustrated by an example from soil science.     

Seismotectonic significance of the 29 January 1989 Etne earthquake, SW Norway

The integrated analysis of geological, seismological and field observations with lineament data derived from satellite images allows the identification of a possible seismogenic fault zone for an earthquake which occurred near Etne in southwestern Norway, on 29 February 1989. The hypocentre of the earthquake was located at the mid-crust at a depth of 13.8±0.9 km which is typical of small intraplate earthquakes. The Etne earthquake occurred as a result of normal faulting with a dextral strike-slip component on a NW–SE trending fault. Available geological and lineament data indicate correlation of the inferred seismogenic fault with the NW–SE trending Etne fault zone. An aeromagnetic anomaly related to the Etne fault zone forms a regional feature intersecting both Precambrian basement and allochthonous Caledonian rocks. Based on these associations the occurrence of the Etne event is ascribed to the reactivation of a zone of weakness along the Etne fault zone. Slope-instabilities developed in the superficial deposits during the Etne event demonstrate the existence of potentially hazardous secondary-effects of such earthquakes even in low seismicity areas such as southwestern Norway.     

Thaw modification of frost-fissure wedges,Richards Island,Pleistocene Mackenzie Delta,Western Arctic Canada

Thaw modification is the general process whereby frost-fissure wedges are modified during thaw, and by which frost-fissure pseudomorphs may develop. Specific processes of thaw modification are inferred from ice-wedge pseudomorphs, composite-wedge pseudomorphs and deformed sand wedges in the Pleistocene Mackenzie Delta: i.e. thermal erosion, collapse, subsidence, refreezing, loading, buoyancy, spreading, folding and shearing. Thaw modification is believed to result in selective preservation of pseudomorphs and wedges. Sand wedges are more likely to be preserved than are ice-wedge pseudomorphs or compositewedge pseudomorphs, because only those sand wedges that penetrate massive ice or icy sediments are prone to thaw modification. Furthermore, whereas ice wedges preferentially develop in ice-rich, fine-grained sediments (thaw-sensitive), their pseudomorphs appear to be selectively preserved in ice-poor, coarse-grained sediments (thaw-stable).