Evolution of the eastern margin of Korea: Constraints on the opening of the East Sea (Japan Sea)

We interpreted marine seismic profiles in conjunction with swath bathymetric and magnetic data to investigate rifting to breakup processes at the eastern Korean margin that led to the separation of the southwestern Japan Arc. The eastern Korean margin is rimmed by fundamental elements of rift architecture comprising a seaward succession of a rift basin and an uplifted rift flank passing into the slope, typical of a passive continental margin. In the northern part, rifting occurred in the Korea Plateau that is a continental fragment extended and partially segmented from the Korean Peninsula. Two distinguished rift basins (Onnuri and Bandal Basins) in the Korea Plateau are bounded by major synthetic and smaller antithetic faults, creating wide and considerably symmetric profiles. The large-offset border fault zones of these basins have convex dip slopes and demonstrate a zig-zag arrangement along strike. In contrast, the southern margin is engraved along its length with a single narrow rift basin (Hupo Basin) that is an elongated asymmetric half-graben. Analysis of rift fault patterns suggests that rifting at the Korean margin was primarily controlled by normal faulting resulting from extension rather than strike-slip deformation. Two extension directions for rifting are recognized: the Onnuri and Hupo Basins were rifted in the east-west direction; the Bandal Basin in the east–west and northwest–southeast directions, suggesting two rift stages. We interpret that the east–west direction represents initial rifting at the inner margin; while the Japan Basin widened, rifting propagated southeastward repeatedly from the Japan Basin toward the Korean margin but could not penetrate the strong continental lithosphere of the Korean Shield and changed the direction to the south, resulting in east–west extension to create the rift basins at the Korean margin. The northwest–southeast direction probably represents the direction of rifting orthogonal to the inferred line of breakup along the base of the slope of the Korea Plateau; after breakup the southwestern Japan Arc separated in the southeast direction, indicating a response to tensional tectonics associated with the subduction of the Pacific Plate in the northwest direction. No significant volcanism was involved in initial rifting. In contrast, the inception of sea floor spreading documents a pronounced volcanic phase which appears to reflect asthenospheric upwelling as well as rift-induced convection particularly in the narrow southern margin. We suggest that structural and igneous evolution of the Korean margin, although it is in a back-arc setting, can be explained by the processes occurring at the passive continental margin with magmatism influenced by asthenospheric upwelling.     

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

Geochemical survey of rare earth elements (REEs) in the concealed ore body of Hongcheon,Korea

Because of the risk of diminishing supplies of rare earth elements (REEs) worldwide due to China’s dominance over REE supply, the necessity of developing domestic resources of REE has been realized in other countries. To explore new ore bodies, a geochemical survey was conducted at one existing carbonatite REE deposit in the Hongcheon area of Korea. Proper sampling strategies and baseline data for the interpretation of the results were determined through a pilot study conducted in the area. Enrichment in the concentration of light REE (LREE) over that of heavy REE, which is typical in carbonatite-type deposits, was observed in stream sediments and heavy mineral samples collected during the geochemical survey. Maximum concentrations of LREE were 2,299 and 27,798 mg/kg for stream sediments and heavy minerals, respectively. Among LREEs, La and Ce are the dominant components of all REEs, comprising approximately 68 % of mean concentrations. Considering the distribution pattern of La + Ce contents and the associations with the existing outcropping ore bodies, the zone of prospective REE mineralization was determined to be in the south-western part of the area. A detailed follow-up soil survey of the zone found even higher concentrations of La and Ce (2,450 and 3,100 mg/kg, respectively), and suggested the possible extension of the existing ore bodies. Likewise, a systematic geochemical survey for REE is feasible for locating concealed ore bodies in the area, where the mineralization is mostly covered with soil, and rock outcrops are scarce.     

A linear projection for the timing of unprecedented climate in Korea

Recently we have had abnormal weather events worldwide that are attributed by climate scientists to the global warming induced by human activities. If the global warming continues in the future and such events occur more frequently and someday become normal, we will have an unprecedented climate. This study intends to answer when we will have an unprecedented warm climate, focusing more on the regional characteristics of the timing of unprecedented climate. Using an in-situ observational data from weather stations of annual-mean surface air temperature in Korea from 1973 to 2015, we estimate a timing of unprecedented climate with a linear regression method. Based on the in-situ data with statistically significant warming trends at 95% confidence level, an unprecedented climate in Korea is projected to occur first in Cheongju by 2043 and last in Haenam by 2168. This 125-year gap in the timing indicates that a regional difference in timing of unprecedented climate is considerably large in Korea. Despite the high sensitivity of linear estimation to the data period and resolution, our findings on the large regional difference in timing of unprecedented climate can give an insight into making policies for climate change mitigation and adaptation, not only for the central government but for provincial governments.     

Source identification of PM2.5 particles measured in Gwangju, Korea

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.     

Temperature trends in the skin/surface, mid-troposphere and low stratosphere near Korea from satellite and ground measurements

Various types of satellite (AIRS/AMSU, MODIS) and ground measurements are used to analyze temperature trends in the four vertical layers (skin/surface, mid-troposphere, and low stratosphere) around the Korean Peninsula (123–132°E, 33–44°N) during the period from September 2002 to August 2010. The ground-based observations include 72 Surface Meteorological Stations (SMSs), 6 radiosonde stations (RAOBs), 457 Automatic Weather Stations (AWSs) over the land, and 5 buoy stations over the ocean. A strong warming (0.052 K yr^?1) at the surface, and a weak warming (0.004～0.010 K yr^?1) in the mid-troposphere and low stratosphere have been found from satellite data, leading to an unstable atmospheric layer. The AIRS/AMSU warming trend over the ocean surface around the Korean Peninsula is about 2.5 times greater than that over the land surface. The ground measurements from both SMS and AWS over the land surface of South Korea also show a warming of 0.043～0.082 K yr^?1, consistent with the satellite observations. The correlation average (r = 0.80) between MODIS skin temperature and ground measurement is significant. The correlations between AMSU and RAOB are very high (0.91～0.95) in the anomaly time series, calculated from the spatial averages of monthly mean temperature values. However, the warming found in the AMSU data is stronger than that from the RAOB at the surface. The opposite feature is present above the mid-troposphere, indicating that there is a systematic difference. Warming phenomena (0.012～0.078 K yr^?1) are observed from all three data sets (SMS, AWS, MODIS), which have been corroborated by the coincident measurements at five ground stations. However, it should also be noted that the observed trends are subject to large uncertainty as the corresponding 95% confidence intervals tend to be larger than the observed signals due to large thermal variability and the relatively short periods of the satellitebased temperature records. The EOF analysis of monthly mean temperature anomalies indicates that the tropospheric temperature variability near Korea is primarily linked to the Arctic Oscillation (AO), and secondarily to ENSO (El Niño and Southern Oscillation). However, the low stratospheric temperature variability is mainly associated with Southern Oscillation and then additionally with Quasi-Biennial Oscillation (QBO). Uncertainties from the different spatial resolutions between satellite data are discussed in the trends.     

Real Data Assimilation Using the Local Ensemble Transform Kalman Filter (LETKF) System for a Global Non-hydrostatic NWP model on the Cubed-sphere

An ensemble data assimilation system using the 4-dimensional Local Ensemble Transform Kalman Filter is implemented to a global non-hydrostatic Numerical Weather Prediction model on the cubed-sphere. The ensemble data assimilation system is coupled to the Korea Institute of Atmospheric Prediction Systems Package for Observation Processing, for real observation data from diverse resources, including satellites. For computational efficiency in a parallel computing environment, we employ some advanced software engineering techniques in the handling of a large number of files. The ensemble data assimilation system is tested in a semi-operational mode, and its performance is verified using the Integrated Forecast System analysis from the European Centre for Medium-Range Weather Forecasts. It is found that the system can be stabilized effectively by additive inflation to account for sampling errors, especially when radiance satellite data are additionally used.     

Chemical weathering of granite under acid rainfall environment, Korea

Chemical weathering was investigated by collecting samples from five selected weathering profiles in a high elevation granitic environment located in Seoul, Korea. The overall changes of chemistry and mineralogical textures were examined reflecting weathering degrees of the samples, using polarization microscopy, X-ray diffraction (XRD), electron probe micro analysis (EPMA), X-ray fluorescence spectroscopy (XRF), and inductively coupled plasma–mass spectroscopy (ICP–MS). The chemical distribution in the weathering profiles shows that few trace elements are slightly immobile, whereas most major (particularly Ca and Na) and trace elements are mobile from the beginning of the granite weathering. On the other hand, there were mineralogical changes initiated from a plagioclase breakdown, which shows a characteristic circular dissolved pattern caused by a preferential leaching of Ca cation along grain boundaries and zoning. The biotite in that region is also supposed to be sensitive to exterior environmental condition and may be easily dissolved by acidic percolated water. As a result, it seems that some rock-forming minerals in the granitic rock located in Seoul are significantly unstable due to the environmental condition of acidic rainfall and steep slopes, where they are susceptible to be dissolved incongruently leading some elements to be highly depleted.     

Formation and development of salt crusts on soil surfaces

The salt concentration gradually increases at the soil free surface when the evaporation rate exceeds the diffusive counter transport. Eventually, salt precipitates and crystals form a porous sodium chloride crust with a porosity of 0.43 ± 0.14. After detaching from soils, the salt crust still experiences water condensation and salt deliquescence at the bottom, brine transport across the crust driven by the humidity gradient, and continued air-side precipitation. This transport mechanism allows salt crust migration away from the soil surface at a rate of 5 μm/h forming salt domes above soil surfaces. The surface characteristics of mineral substrates and the evaporation rate affect the morphology and the crystal size of precipitated salt. In particular, substrate hydrophobicity and low evaporation rate suppress salt spreading.