Identification and characterization of the encrusting materials in a coastal liquefied petroleum gas storage cavern

An examination was carried out of the encrusting materials on the seepage removal pumps in a bottom sump of an undersea liquefied petroleum gas (LPG) cavern. The studied cavern, constructed at 8 km off the western coast of Korea, facing the Yellow Sea, is at 130–150 m below the seabed. Since the first filling of the LPG into the cavern, it has suffered from the unexpected problem of a thick encrustation of unknown materials on the seepage removal pumps of the cavern. The XRD and XRF analyses revealed that the encrustation materials were mainly iron (hydro)oxides and carbonate mineral (aragonite). Based on the geological setting below the cavern site, it was inferred that iron oxides found in the Pleistocene sandy sediment and the Precambrian gneiss might be supplying ferrous iron to the cavern waters under an anaerobic condition, evidenced by low dissolved oxygen and negative redox potential in the cavern water. A significant change in the hydraulic condition near the pump intake and mixing the cavern water with oxic waters supplied through re-circulated seawater and terrestrial groundwater discharge, would precipitate the dissolved iron. Precipitation of the carbonate mineral is thought to have occurred due to over-saturation of calcium and bicarbonate, which may have resulted from the dissolution of cement grouting materials used during the undersea cavern construction and submarine groundwater discharge (SGD). This study reports the iron and carbonate precipitation in the man-made undersea cavern, which is affected by the surrounding hydrogeological condition and the SGD.     

Landsat data to evaluate urban expansion and determine land use/land cover changes in Penang Island,Malaysia

Land surface temperature (LST) plays an important role in local, regional and global climate studies. LST controls the distribution of the budget for radiation heat between the atmosphere and the earth’s surface. Therefore, it is important to evaluate abrupt changes in land use/land cover (LULC). Penang Island, Malaysia has been experiencing a rapid and drastic change in urban expansion over the past two decades due to growth in industrial and residential areas. The aim of this study was to investigate and evaluate the impact of LST with respect to land use changes in Penang Island, Malaysia. Three supervised classification techniques known as maximum likelihood, minimum distance-to-mean and parallelepiped were applied to the images to extract thematic information from the acquired scene by using PCI Geomatica 10.1 image processing software. These remote sensing classification techniques help to examine land-use changes in Penang Island using multi-temporal Landsat data for the period of 1999–2007. Training sites were selected within each scene and seven land cover classes were assigned to each classifier. The relative performance of each technique was evaluated. The accuracy of each classification map was assessed using a reference data set consisting of a large number of samples collected per category. Two Landsat satellite images captured in 1999 and 2007 were chosen to classify the LULC types using the maximum likelihood classification method, determined from visible and near-infrared bands. The study revealed that the maximum likelihood classifier produced superior results and achieved a high degree of accuracy. The LST and normalised difference vegetation index (NDVI) were computed based on changes in LULC. The results showed that the urban (highly built-up) area increased dramatically, and grassland area increased moderately. Inversely, barren land decreased obviously, and forest area decreased moderately. While urban (minimally built-up) area decreased slightly. These changes in LULC caused at significant difference in LST between urban and rural areas. Strong correlation values were observed between LST and NDVI for all LULC classes. The remote sensing technique used in this study was found to be efficient; it reduced the time for the analysis of the urban expansion, and it was found to be a useful tool to evaluate the impact of urbanisation with LST.     

A preliminary study of natural environmental change and its impact on early Late Paleolithic people in the northeast central Korean Peninsula during Marine Istope Stage 3 (40–30k cal a bp)

We comprehensively analyzed sediments obtained from an archeological excavation. A trench sediment profile of Maedun Cave (MC), South Korea, was analyzed geoarchaeologically. Multi-proxy analyses (palynomorphs, grain size, magnetic susceptibility, animal bones and artifacts) reflected the vegetation, hydroclimate and lives of prehistoric people at Marine Isotope Stage (MIS) 3 (ca. 40–30k cal a bp ) in the early Late Paleolithic. The palynoflora consisted of pollen and non-pollen palynomorphs. Under the air-circulation system in the cave, anemophilous pollen flowed in during the day, whereas waterborne pollen and spores, and freshwater algae, were transported by flooding during the summer monsoon rainy season. Mixed conifer and deciduous broad-leaved forest with an understory of pteridophytes flourished around the north-east central Korean Peninsula during MIS 3. Freshwater algae and grass pollen records may reflect precipitation intensity. It is assumed that they had flowed in during flooding caused by high precipitation during the enhanced East Asian summer monsoon, corresponding to Dansgaard–Oeschger (D/O) events 5 and 8 of δ¹⁸O GISP2 and Hulu Cave. The prehistoric people hunted herbivorous animals in the area around MC and sheltered inside it seasonally. They also used the grains of oats growing near the dwelling as a source of food.