Über das Verhalten und die Herkunft der in den Gewässern und in der Atmosphäre vorhandenen himmelblauen Fluoreszenz

Zusammenfassung Überall in der Natur im Bereich der Erdrinde findet sich ein im ultravioletten Licht hellblau fluoreszierender Stoff. Nachgewiesen wurde er bisher in der Atmosphäre, in allen in der Natur vorhandenen Wasservorkommen: im Nebel, Schnee, Regen, Rauhreif, Gletschereis, in Quellen, Bächen, Flüssen, Seen und im Oberflächen- und Tiefenwasser des Weltmeeres. Ferner ließ er sich nachweisen im Staub, in Gesteinen und in Filtrierpapier (reiner Cellulose), wie er überhaupt ein ständiger Begleitstoff der in der Natur weit verbreiteten Kohlenhydrate ist. Aus der Atmosphäre schlägt er sich bereits in wenigen Tagen in merklichem Maße an gereinigten Glasoberflächen nieder. Durch eingehende Versuche wird wahrscheinlich gemacht, daß der Fluoreszenz zwei organische Verbindungen zu Grunde liegen, die sich spontan aus den langsam in der Natur sich bildenden Zerfallsprodukten der Kohlenhydrate (Methylglyoxal) durch Eigenkondensation aufbauen. Auf die Bildung der fluoreszierenden Stoffe wirken ähnlich wie bei dem verwandten Vorgang der Melanoïdin-Bildung (Maillard-Reaktion) neben der Erhöhung der Temperatur und der Erhöhung der Konzentration der Ausgangssubstanzen (beispielsweise beim Verdunstungsvorgang der atmosphärischen Wassertröpfchen) alkalische Reaktion und in besonderem Maße die Gegenwart von Stickstoff-Verbindungen (Ammonium-Ion, Aminosäuren) fördernd ein.

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On the behaviour and the origin of the azure fluorescence present in all kinds of waters and in the atmosphere

Summary Everywhere in nature and in the vicinity of the earth's crust there is a substance to be found from which a light blue fluorescence is emanating when it is exposed to ultraviolet radiation. Until now this substance has been verified in the atmosphere and in all the manifestations of water, viz. in fog, snow, rain, soft rime, glacier ice, springs, brooks, rivers, lakes, and in the surface water and deep water of the oceans. Besides, the presence of this substance has been proved in dust, rocks and in filter paper (pure cellulose) and it has been revealed as a permanently attendant substance of carbon hydrates frequently occurring in nature. It is precipating to a considerable extent within a few days from the atmosphere on cleaned glass surfaces. From careful experiments it appears to be probable that the fluorescent substance is based on two organic compounds that are spontaneously springing by self-condensation from the dissociated constituents of carbonhydrates (metyhlglyoxal) that are slowly forming everywhere in nature. Similar to the related process of the formation of melanoidin (Maillard-reaction) and in addition to the increase in temperature and concentration of the initial substances (as e.g. is observed during the process of evaporation of atmospheric water drops), alkaline reaction and especially the presence of nitrogen compounds (ammonium-ion, amino-acids) are promoting the formation of fluorescent substances.

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Sur le comportement et l'origine de la fluorescence azure rencontrée dans les eaux et dans l'atmosphère

Résumé Partout dans la nature on trouve près de la croute terrestre une substance produisant de la fluorescence bleue claire lorsqu'on l'expose à la radiation ultra-violette. On a jusqu'ici démontré la présence de cette substance dans l'atmosphère et dans toutes les formes que l'eau peut adopter dans la nature, c.a.d. dans la brume, la neige, la pluie, le givre mou, dans la glace des glaciers, les sources, cours-d'eau, rivières, lacs et dans les eaux superficielles et profondes des océans. De plus, on peut prouver son existence dans la poussière, dans les roches et dans le papier à filtrer (cellulose pure); d'ailleurs, cette substance est surtout une matière d'accompagnement permanent des hydrates de carbon très répandus dans la nature. Venant de l'atmosphère, elle se précipite en quantité considérable sur des surfaces nettoyées de verre. Des essais approfondis nous font supposer que la substance fluorescente est basée sur deux combinaisons organiques qui se forment spontanément par condensation propre des produits de dissociation des hydrates carboniques (méthylglyoxal) qui se developpent lentement dans la nature. Comme dans le processus analogue de la formation du mélanoïdin (réaction Maillard) et à côté de l'élévation de la température et de la concentration des matières de départ (par exemple aux processus de l'évaporation des gouttes d'eau dans l'atmosphère) la réaction alcaline et surtout la présence des combinaisons de nitrogène (ammonium-ion, acides d'aminés) favorisent la production des substances fluorescentes.

     

An Eruv for St Ives? Religion,identity, place and conflict on the Sydney north shore

Religious identity, when marked by physical changes to urban landscapes, has been a cause of tension and conflict in many cities. In the Sydney suburb of St Ives, an attempt to create an eruv, a symbolic and only partly physical boundary around orthodox Jewish space, was vigorously opposed and eventually defeated through the planning system. The religious and physical significance of the eruv resulted in diverse rationales of opposition, centred on the physical and environmental impact, the conceptual nature of boundaries and the role of religion and ‘modernity’ in everyday suburban life. The place of an eruv was opposed with reference to spatial imaginaries of the nation, the suburb and the secular public, as religion and worship intersected with the politics of urban citizenship and belonging. Each of these spatial imaginaries was constructed by opponents in such a way as to deny a place for an eruv in St Ives, and reinforced through the application of planning instruments which eventually refused permission for an eruv. To many residents, public space was seen to be at risk, raising complex questions over amenity, the politics and perception of difference and what is in or out of place. The planning framework adjudicating such development proposals must transcend such imaginaries in the production of public spaces in multicultural cities.     

Exploring the Tourism Experience of Beginner Skiers in the Emerging Ski Market

The skiing economy is a typical experience economy, so understanding the experience of ski tourists is essential to the development of the destination. To enrich the tourism experience research in the emerging ski market, this paper studies the 7118 online reviews of beginner skiers by selecting the main ski resorts in China as a case study. The content analysis method and sentiment analysis based on the domain lexicon and custom rules are combined to explore the perception characteristics of the beginners from the two aspects of experience dimension and experience satisfaction. Three main results were found. (1) The five main dimensions that affect the ski tourism experience of beginners are interaction perception, price perception, reputation perception, risk perception and functional perception. (2) For beginners, skiing is the primary purpose of tourism instead of being the critical factor of the positive reviews. They pay more attention to the pleasure produced by interpersonal interactions. (3) From 2014/2015 ski season to 2010/2021 ski season, the positive sentiment of beginners had no obvious change, while the negative sentiment showed a continuous downward trend, and the negative sentiment was mainly distributed among reviews on price, low temperature and service. This paper not only expands the research perspective of ski tourism, but also provides managerial inspiration for ski destinations interested in attracting beginners from the emerging ski markets.     

Subglacially precipitated carbonates record geochemical interactions and pollen preservation at the base of the Laurentide Ice Sheet on central Baffin Island,eastern Canadian Arctic

The mineralogy and isotopic compositions of subglacially precipitated carbonate crusts (SPCCs) provide information on conditions and processes beneath former glaciers and ice sheets. Here we describe SPCCs formed on gneissic bedrock at the bed of the Laurentide Ice Sheet (LIS) during the last glacial maximum on central Baffin Island. Geochemical data indicate that the Ca in the crusts was likely derived from the subglacial chemical weathering Ca-bearing minerals in the local bedrock. C and Sr isotopic analyses reveal that the C in the calcite was derived predominantly from older plant debris. The δ¹⁸O values of the SPCCs suggest that these crusts formed in isotopic equilibrium with basal ice LIS preserved in the Barnes Ice Cap (BIC). Columnar crystal fabric and the predominance of sparite over micrite in the SPCCs are indicative of carbonate precipitation under open-system conditions. However, the mean δ¹⁸O value of the calcite crusts is ~ 10‰ higher than those of primary LIS ice preserved in the BIC, demonstrating that SPCCs record the isotopic composition of only basal ice. Palynomorph assemblages preserved within the calcite and basal BIC ice include species last endemic to the Arctic in the early Tertiary. The source of these palynomorphs remains enigmatic.     

Robust optimisation of CO2 sequestration strategies under geological uncertainty using adaptive sparse grid surrogates

Geologic CO₂ sequestration in deep saline aquifers is a promising technique to mitigate the effect of greenhouse gas emissions. Designing optimal CO₂ injection strategy becomes a challenging problem in the presence of geological uncertainty. We propose a surrogate assisted optimisation technique for robust optimisation of CO₂ injection strategies. The surrogate is built using Adaptive Sparse Grid Interpolation (ASGI) to accelerate the optimisation of CO₂ injection rates. The surrogate model is adaptively built with different numbers of evaluation points (simulation runs) in different dimensions to allow automatic refinement in the dimension where added resolution is needed. This technique is referred to as dimensional adaptivity and provides a good balance between the accuracy of the surrogate model and the number of simulation runs to save computational costs. For a robust design, we propose a utility function which comprises the statistical moment of the objective function. Numerical testing of the proposed approach applied to benchmark functions and reservoir models shows the efficiency of the method for the robust optimisation of CO₂ injection strategies under geological uncertainty.     

Using Discriminant Analysis and Logistic Regression in Mapping Quaternary Sediments

Mapping the occurrence and thickness of layers within a soil profile is a prerequisite for soil characterization. The objective of this paper is to compare the applicability of two statistical methods—discriminant analysis (DA) and logistic regression (LR)—used to calculate the thickness of Quaternary sediments in a formal way and to identify parameters controlling the occurrence of these sediments. The investigations were carried out in southern Bavaria in an area of about 150 ha presenting a large variability in relief and parent material (Tertiary material, Pleistocene loess, colluvial/alluvial sediments). Comparisons between the two statistical methods were carried out with a training dataset and an evaluation dataset. The results show that DA was preferable under the assumptions of normality and equal variance/covariance matrices. The analyses produced models with 80 % and 79 % correctly reclassified assignments and a canonical correlation coefficient of approximately 0.60. From the simulations, it was found (i) that the determining predictors were altitude, slope, and upslope catchment area (partly expressed as topographical wetness index), SAGA wetness index and specific catchment area; and (ii) that a disadvantage of LR was that trial and error was frequently necessary to find the optimal composition of variables. In this study, a hierarchical combination of binary and ordinal LR was used and revealed (iii) that when the probabilities in LR between adjacent categories were similar, the possibility of incorrect calculations increased and (iv) that visual inspections as well as RMSE showed that DA with weighted depths (5 cm-stepwise DA) provided the best prediction accuracy. This information can help improve soil surveys and the predictability of the spatial heterogeneity in landscapes.     

Kaolin-Kohlentonsteine im flözführenden Oberkarbon des Niederrheinisch-Westfälischen Steinkohlenreviers

Starting from general considerations of the rocks existing in the Ruhr Carboniferous and the mineral layers in coal seams, an informative review is given about the definition of clay stones and kaolin coal tonsteins as well as about the stratigraphic distribution of key horizons with special regard to the kaolin coal tonsteins. Information follows about the first evidence of individual kaolin coal tonsteins, their existence in the normal geologic columns and more recent stratigraphic sections as well as about the concentration of repositories. Besides, the kaolin coal tonsteins are characterized according to their macroscopic and microscopic external form. The paper reports about their material constituents (mineral components, trace elements, anorganic chemical constituents and organic substances in form of coal hydrates and amino acids). The paper closes with some statements about the importance and utilization of kaolin coal tonsteins to solve local and regional duties in mining geology.     

西阿尔卑斯Zermatt-Saas洋壳深俯冲超高压变质带与我国新疆西南天山超高压变质带的比较

根据对西阿尔卑斯Zernatt-Saas带的野外地质考察及有关资料的总结,详细地介绍了西阿尔卑斯Zermatt-Saas洋壳深俯冲超高压变质带的地质概括、岩石组成和变质作用演化过程,并着重与我国新疆西南天山洋壳深俯冲超高压变质带进行了比较,探讨了这两个洋壳深俯冲超高压变质带在变质作用和地质演化方面的异同。在此基础上,总结了这两个目前世界上已知最典型的洋壳深俯冲超高压变质带的基本地质特征是都具有保存完好的洋壳岩石组合特征和较低的地热梯度。