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471.
Late Alpine fissures and fractures in amphibolite-facies basement gneisses at Arvigo (Val Calanca, Swiss Alps) show distinct
cm-sized reaction selvages parallel to the fracture walls that composed of subgreenschist facies assemblages produced by the
interaction of water present in the fracture porosity with the old high-grade gneiss assemblages. The process of selvage or
reaction-vein formation occurred in the brittle deformation regime and at temperatures characteristic of, first the prehnite-pumpellyite
facies and then later of the zeolite facies. The vein formation occurred during uplift and cooling at very late stages of
the Alpine orogeny. The reaction veins are composed of a selvage of altered gneiss on both sides of the central fracture and
a central zone with fissure minerals that have been growing in the open fracture pore space. The central zone of the Arvigo
veins contains an early assemblage with epidote, prehnite and chlorite and a late succession sequence of various species of
zeolite. The veins of the Arvigo quarry are convincing evidence that fracture fluids in gneiss and granite have the potential
to precipitate Ca–zeolite. This is an important find because many fluids recovered from deep continental drill holes and from
geothermal energy exploration are found to be oversaturated in respect to a number of Ca–zeolite species. Vein formation during
late uplift and cooling of the Alps occurred at continuously decreasing T and at hydrostatic pressure: (1) coexisting prehnite/epidote records temperatures of 330–380°C, (2) chlorite formation at
temperature of 333 ± 32°C and (3) formation of zeolites <250°C. In the selvages the prime reaction is the replacement of plagioclase
by albite along a sharp reaction front that separates the selvage from unaltered gneiss. In addition to albitisation, chloritisation
of biotite is the second important reaction in the alteration process. The reactions release components for the formation
of Ca–Al silicates. The water–rock interaction is associated with a depletion of Al, Si, Ca, Fe and K in the altered wall
rock. The overall reaction is associated with an increase in porosity of up to 14.2 ± 2.2% in the selvage zone (altered wall
rock), caused by the volume decrease during albitisation and the removal of biotite. The propagation of the sharp reaction
front through the gneiss matrix occurred via a dissolution-reprecipitation mechanism. Zeolite formation is tied to the plagioclase
alteration reaction in the rock matrix, which releases components for zeolite formation to a CO2-poor aqueous liquid. 相似文献
472.
A set of sheeted quartz veins cutting 380 Ma monzogranite at Sandwich Point, Nova Scotia, Canada, provide an opportunity to
address issues regarding fluid reservoirs and genesis of intrusion-related gold deposits. The quartz veins, locally with arsenopyrite
(≤5%) and elevated Au–(Bi–Sb–Cu–Zn), occur within the reduced South Mountain Batholith, which also has other zones of anomalous
gold enrichment. The host granite intruded (P = 3.5 kbars) Lower Paleozoic metaturbiditic rocks of the Meguma Supergroup, well known for orogenic vein gold mineralization.
Relevant field observations include the following: (1) the granite contains pegmatite segregations and is cut by aplitic dykes
and zones (≤1–2 m) of spaced fracture cleavage; (2) sheeted veins containing coarse, comb-textured quartz extend into a pegmatite
zone; (3) arsenopyrite-bearing greisens dominated by F-rich muscovite occur adjacent the quartz veins; and (4) vein and greisen
formation is consistent with Riedel shear geometry. Although these features suggest a magmatic origin for the vein-forming
fluids, geochemical studies indicate a more complex origin. Vein quartz contains two types of aqueous fluid inclusion assemblages
(FIA). Type 1 is a low-salinity (≤3 wt.% equivalent NaCl) with minor CO2 (≤2 mol%) and has T
h = 280–340°C. In contrast, type 2 is a high-salinity (20–25 wt.% equivalent NaCl), Ca-rich fluid with T
h = 160–200°C. Pressure-corrected fluid inclusion data reflect expulsion of a magmatic fluid near the granite solidus (650°C)
that cooled and mixed with a lower temperature (400°C), wall rock equilibrated, Ca-rich fluid. Evidence for fluid unmixing,
an important process in some intrusion-related gold deposit settings, is lacking. Stable isotopic (O, D, S) analyses for quartz,
muscovite and arsenopyrite samples from vein and greisens indicate the following: (1) δ18Oqtz = +11.7‰ to 17.8‰ and δ18Omusc = +10.7‰ to +11.2‰; (2) δDmusc = −44‰ to−54‰; and (3) δ34Saspy = +7.8‰ to +10.3‰. These data are interpreted, in conjunction with fluid inclusion data, to reflect contamination of a magmatic-derived
fluid (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} ≤ +10‰) by an external fluid (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} ≥ +15‰), the latter having equilibrated with the surrounding metasedimentary rocks. The δ34S data are inconsistent with a direct igneous source based on other studies for the host intrusion (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} = +5‰) and are, instead, consistent with an external reservoir for sulphur based on δ34SH2S data for the surrounding metasedimentary rocks. Divergent fluid reservoirs are also supported by analyses of Pb isotopes
for pegmatitic K-feldspar and vein arsenopyrite. Collectively the data indicate that the vein- and greisen-forming fluids
had a complex origin and reflect both magmatic and non-magmatic reservoirs. Thus, although the geological setting suggests
a magmatic origin, the geochemical data indicate involvement of multiple reservoirs. These results suggest multiple reservoirs
for this intrusion-related gold deposit setting and caution against interpreting the genesis of intrusion-related gold deposit
mineralization in somewhat analogous settings based on a limited geochemical data set. 相似文献
473.
Sampling of quartz vein material from two gold deposits of similar geological setting but different ages (The Ovens, 408?Ma; Dufferin, 380?Ma) in the Meguma Terrane of Nova Scotia has been done to compare and contrast their ??18Oquartz signatures. Despite different ages of formation, quartz from all vein types in each of the deposits (i.e. saddle-reef, bedding-concordant leg reefs, en echelon, discordant) shows limited intra-deposit variation with similar average ??18O values of +15.2?±?0.9?? (n?=?16) for The Ovens and +15.7?±?0.6?? (n?=?12) for Dufferin. Using an average ??18O value of +15.4?? for the two deposits, the corresponding ??18OH2O values, calculated for 400°C and 350°C based on constraints from mineral assemblages and fluid inclusion studies, indicate averages of 11.4?±?0.2?? and +10.2?±?0.2??, respectively. The isotopic data indicate that: (1) the vein-forming fluids have a metamorphic signature, (2) all vein types in the two deposits represent formation from a single, isotopically homogeneous fluid, and (3) a fluid of similar isotopic signature was generated by two contrasting tectono-thermal events in the Meguma Terrane that were separated by 30?Ma. Integration of these results with previously published data for 14 Meguma gold deposits indicate a general stratigaphic dependence in ??18OH2O values for deposits when arranged in their relative stratigraphic position such that ??18OH2O values increase upwards in the stratigraphy. This apparent trend cannot be explained by models involving either fluid mixing or cooling of the vein-forming fluids, but instead is modelled using fluid/rock interaction taking into account a change in the modal mineralogy of the metasedimentary rocks upwards in the stratigraphy. 相似文献
474.
Ninfa Bennington Clifford Thurber Kurt L. Feigl Jessica Murray-Moraleda 《Pure and Applied Geophysics》2011,168(10):1553-1565
Several studies of the 2004 Parkfield earthquake have linked the spatial distribution of the event’s aftershocks to the mainshock
slip distribution on the fault. Using geodetic data, we find a model of coseismic slip for the 2004 Parkfield earthquake with
the constraint that the edges of coseismic slip patches align with aftershocks. The constraint is applied by encouraging the
curvature of coseismic slip in each model cell to be equal to the negative of the curvature of seismicity density. The large
patch of peak slip about 15 km northwest of the 2004 hypocenter found in the curvature-constrained model is in good agreement
in location and amplitude with previous geodetic studies and the majority of strong motion studies. The curvature-constrained
solution shows slip primarily between aftershock “streaks” with the continuation of moderate levels of slip to the southeast.
These observations are in good agreement with strong motion studies, but inconsistent with the majority of published geodetic
slip models. Southeast of the 2004 hypocenter, a patch of peak slip observed in strong motion studies is absent from our curvature-constrained
model, but the available GPS data do not resolve slip in this region. We conclude that the geodetic slip model constrained
by the aftershock distribution fits the geodetic data quite well and that inconsistencies between models derived from seismic
and geodetic data can be attributed largely to resolution issues. 相似文献
475.
Marie-Laure Pesch Iso Christl Kurt Barmettler Stephan M Kraemer Ruben Kretzschmar 《Geochemical transactions》2011,12(1):2
Background
The isolation of highly pure copper-free methanobactin is a prerequisite for the investigation of the biogeochemical functions of this chalkophore molecule produced by methane oxidizing bacteria. Here, we report a purification method for methanobactin from Methylosinus trichosporium OB3b cultures based on reversed-phase HPLC fractionation used in combination with a previously reported resin extraction. HPLC eluent fractions of the resin extracted product were collected and characterized with UV-vis, FT-IR, and C-1s NEXAFS spectroscopy, as well as with elemental analysis and ESI-MS. 相似文献476.
二氧化碳沿井筒渗漏是二氧化碳地质埋存过程中所面临的重要风险之一.尤其是对于已经封堵的废弃井,由于获取井下的信息比较困难,因此评价废弃井的完整性是一个比较大的挑战.本文为评估二氧化碳沿废弃井渗漏提出了风险分析的方法.该方法包括了三个主要步骤:渗漏方案的制定,定量模拟及结果分析.所制定的渗漏方案将通过数值模拟进行定量分析及评价.本文将阐述该评价方法的第一步骤:渗漏方案的制定.该步骤为渗漏的定量模拟提供了理论基础.该方法被广泛接受并现场应用于德国某大型二氧化碳存储及提高天然气采收率项目中. 相似文献
477.
Reservoirs as sentinels of catchments: the Rappbode Reservoir Observatory (Harz Mountains, Germany) 总被引:2,自引:2,他引:0
Karsten Rinke Burkhard Kuehn Serghei Bocaniov Katrin Wendt-Potthoff Olaf Büttner Jörg Tittel Martin Schultze Peter Herzsprung Helmut Rönicke Karsten Rink Kristine Rinke Maren Dietze Marco Matthes Lothar Paul Kurt Friese 《Environmental Earth Sciences》2013,69(2):523-536
Reservoirs can be viewed as sentinels of their catchments and a detailed monitoring of reservoir systems informs about biogeochemical and hydrological processes at the catchment scale. We developed a comprehensive online monitoring system at Rappbode reservoir, the largest drinking water reservoir in Germany, and its inflows. The Rappbode Reservoir Observatory comprises of a set of online-sensors for the measurement of physical, chemical, and biological variables and is complemented by a biweekly limnological sampling schedule. Measurement stations are deployed at the four major inflows into the system, at the outlets of all pre-reservoirs, as well as in the main reservoir. The newly installed monitoring system serves both scientific monitoring and process studies, as well as reservoir management. Particular emphasis is paid to the monitoring of short-term dynamics and many variables are measured at high temporal resolution. As an example, we quantitatively documented a flood event which mobilised high loads of dissolved organic carbon and changed the characteristics of the receiving reservoir from eutrophic to dystrophic within a few days. This event could have been completely missed by conventional biweekly sampling programs, but is relevant for biogeochemical fluxes at the catchment scale. We also show that the high frequency data provide a deeper insight into ecosystem dynamics and lake metabolism. The Rappbode Reservoir Observatory; moreover, offers a unique study site to apply, validate, and develop state of the art lake models to improve their predictive capabilities. 相似文献
478.
Hydraulic fracturing in unconventional gas reservoirs: risks in the geological system part 1 总被引:2,自引:2,他引:0
Torsten Lange Martin Sauter Michael Heitfeld Kurt Schetelig Karolin Brosig Wiebke Jahnke Alexander Kissinger Rainer Helmig Anozie Ebigbo Holger Class 《Environmental Earth Sciences》2013,70(8):3839-3853
Hydraulic fracturing of unconventional gas reservoirs rapidly developed especially in the USA to an industrial scale during the last decade. Potential adverse effects such as the deterioration of the quality of exploitable groundwater resources, areal footprints, or even the climate impact were not assessed. Because hydraulic fracturing has already been practised for a long time also in conventional reservoirs, the expansion into the unconventional domain was considered to be just a minor but not a technological step, with potential environmental risks. Thus, safety and environmental protection regulations were not critically developed or refined. Consequently, virtually no baseline conditions were documented before on-site applications as proof of evidence for the net effect of environmental impacts. Not only growing concerns in the general public, but also in the administrations in Germany promoted the commissioning of several expert opinions, evaluating safety, potential risks, and footprints of the technology in focus. The first two publications of the workgroup “Risks in the Geological System” of the independent “Information and Dialogue process on hydraulic fracturing” (commissioned by ExxonMobil Production Deutschland GmbH) comprises the strategy and approaches to identify and assess the potential risks of groundwater contamination of the exploitable groundwater system in the context of hydraulic fracturing operations in the Münsterland cretaceous basin and the Lower Saxony Basin, Germany. While being specific with respect to local geology and the estimation of effective hydraulic parameters, generalized concepts for the contamination risk assessment were developed. The work focuses on barrier effectiveness of different units of the overburden with respect to the migration of fracking fluids and methane, and considers fault zones as potential fluid pathway structures. 相似文献
479.
Timothy Quinn Kirk Krueger Ken Pierce Daniel Penttila Kurt Perry Tiffany Hicks Dayv Lowry 《Estuaries and Coasts》2012,35(5):1214-1228
Surf smelt Hypomesus pretiosus are an important part of the Salish Sea food web and obligate beach spawners, yet little is known about the spatiotemporal distribution of spawning and beach characteristics related to spawning success. We counted smelt eggs at 51 sites around Camano Island, Puget Sound, Washington every 2?weeks for 1?year and at 13 of those 51 sites each month in the following year. At each site, we measured beach characteristics hypothesized to affect spawning habitat suitability as measured by egg abundance and mortality. Eggs were collected at 45 sites and pooled by month for analyses. Few sites (N?=?10, 19.6?%) contributed 87?% of total eggs and 89?% of all live eggs collected. Mean total egg counts at sites were higher (p?<?0.019) in Jul?CSep (1,790.7, SE?=?829.5) than in Jan?CMar (26.1, SE?=?10.2). Principal component and regression analyses suggested that aspect, fetch, solar radiation, and beach temperature predicted egg abundance but not mortality. Because a small proportion of sites appear to support most spawning activity, a conclusion consistent with year?2 egg counts, impacts to relatively few beaches could greatly affect surf smelt production. 相似文献
480.
Nitric oxide emissions from soils: a case study with temperate soils from Saxony, Germany 总被引:1,自引:1,他引:0
Cornelius Oertel Kurt Herklotz J?rg Matschullat Frank Zimmermann 《Environmental Earth Sciences》2012,66(8):2343-2351
Nitrogen oxides (NO x ) are involved in acid rain and ozone formation, as well as destruction. NO x are climate-relevant trace gases in the atmosphere. Atmospheric NO x originate from anthropogenic emissions (mainly combustion processes). NO from natural processes derives from thunderstorms and soil microbial processes. They may play a crucial role in soil?Catmosphere feedback processes. This study aims to investigate NO x -emissions from soils under different land use, geographical and meteorological conditions. NO x -emissions were quantified in both field and laboratory experiments with a closed static chamber. Disturbed soil samples have been used for laboratory experiments. A climate chamber was used to regulate soil temperature of the samples. Field experiments showed that NO-soil emissions strongly depend on soil temperature. NO-emissions from a soil under meadow showed significant daily variations, unlike soil below spruce forest. Peak emission values were 18???g NO?CN?m?2?h?1 above meadow and 1.3???g NO?CN?m?2?h?1 under forest canopy. In addition, NO-emissions of meadow and forest soil were studied in a climate chamber, enhanced by an additional experiment with agricultural soil. These experiments revealed strong exponential correlations of NO-emissions and soil temperature. Maximum values reached above 400???g NO?CN?m?2?h?1 from agricultural soils at soil temperatures above 50°C. This study shows that soil NO-emissions strongly depend on temperature, vegetation type and geographical position. Consequently, NO-emissions may have a positive feedback effect on climate change. 相似文献