Eoalpine tectonics of the Eastern Alps: implications from the evolution of monometamorphic Austroalpine units (Schneeberg and Radenthein Complex)

Monometamorphic metasediments of Paleozoic or Mesozoic age constituting Schneeberg and Radenthein Complex experienced coherent deformation and metamorphism during Late Cretaceous times. Both complexes are part of the Eoalpine high-pressure wedge that formed an intracontinental suture and occur between the polymetamorphosed Ötztal–Bundschuh nappe system on top and the Texel–Millstatt Complex below. During Eoalpine orogeny Schneeberg and Radenthein Complexes were south-dipping and they experienced a common tectonometamorphic history from ca. 115 Ma onwards until unroofing of the Tauern Window in Miocene times. This evolution is subdivided into four distinct tectonometamorphic phases. Deformation stage D1 is characterized by WNW-directed shearing at high temperature conditions (550–600°C) and related to the initial exhumation of the high-pressure wedge. D2 and D3 are largely coaxial and evolved during high- to medium-temperature conditions (ca. 450 to ≥550°C). These stages are related to advanced exhumation and associated with large-scale folding of the high-pressure wedge including the Ötztal-Bundschuh nappe system above and the Texel–Millstatt Complex below. For the area west of the Tauern Window, F2/F3 fold interference results in the formation of large-scale sheath-folds in the frontal part of the nappe stack (formerly called “Schlingentektonik” by previous authors). Earlier thrusts were reactivated during Late Cretaceous normal faulting at the base of the Ötztal–Bundschuh nappe system and its cover. Deformation stage D4 is of Oligo-Miocene age and accounted for tilting of individual basement blocks along large-scale strike-slip shear zones. This tilting phase resulted from indentation of the Southern Alps accompanied by the formation of the Tauern Window.     

Lunar atmospheric H2 detections by the LAMP UV spectrograph on the Lunar Reconnaissance Orbiter

We report on the detection of H₂ as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H₂ in the native lunar atmosphere, for the first time. We derive a surface density for H₂ of 1.2 ± 0.4 × 10³ cm⁻³ at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.     

TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions

We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe²⁺ to Fe³⁺ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.     

Fluid-induced mineral composition adjustments during exhumation: the case of Alpine stilbite

Stilbite is locally present as a very late mineral on fractures and fissures of granitic basement in the Central Swiss Alps. Stilbite samples from the Gotthard rail base tunnel provide evidence that they originally formed as a K-absent variety at depth. However, all stilbite samples from surface outcrops above the tunnel display significant potassium concentrations. Interestingly, water from fractures in the tunnel (at 50 °C) is oversaturated with respect to stilbite and essentially potassium-free whereas waters from high-Alpine brooks above the tunnel (and at other high-Alpine areas) have unusually high K/Na ratios. The data suggest that stilbite that may actively form on fissures at tunnel level as a K-absent variety by precipitation from water. Older stilbite that originally formed as coatings on fracture walls was gradually exhumed and uplifted and finally reached the today’s erosion surface about 2,000 m above the tunnel. However, the stilbite reaches the erosion surface as a K-rich variety as a result of interaction of the original low-K stilbite with surface water and near-surface groundwater. This leads to the conclusion that minerals once formed at depth may significantly change their composition once they reach the ground water zone on their way to the erosion surface. In the case of the stilbite, if surface outcrops would have been the only source of samples and data, the K-rich composition could have been mistaken for the composition of the mineral when it formed, which is not the case. Late-stage compositional readjustments may be difficult to discern in samples from surface outcrops. The provided data show that original mineral compositions may be adjusted by late-stage water–rock interaction in a highly selective way.     

Increasing levels and biomagnification of persistent organic pollutants (POPs) in Antarctic biota

Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.     

Bristen granite: a highly differentiated,fluorite-bearing A-type granite from the Aar massif,Central Alps,Switzerland

Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C.     

哀牢山-红河剪切带左行走滑作用起始时间约束

位于哀牢山-红河剪切带NW延伸方向上的点苍山变质杂岩体遭受强烈的左行走滑剪切变形、变质作用改造,岩石中保存了典型的高温矿物组合以及由它们构成的宏观和微观高温变形构造特征,其中糜棱岩中具有极其发育的长石矿物拉伸线理而形成典型的L与LS型构造岩是其一个明显的特征。本文对点苍山地区高温糜棱岩主要矿物开展了显微构造与矿物变形、变形机制及组构分析,并对于遭受高温糜棱岩化改造的一个花岗质岩体开展了SHRIMP锆石U-Pb定年分析。结果表明岩石中长石、角闪石、石英等主要矿物具有典型的达角闪岩相条件下的高温晶质塑性变形和动态生长特征,它们也为走滑剪切变形活动提供了充分的微观构造证据。对于点苍山高温糜棱岩化改造的眼球状或似斑状二长花岗岩的显微构造分析结果表明,这套花岗质岩石从走滑剪切前期岩浆的侵位之后经历了早期强烈的岩浆期后交代作用—亚岩浆流动—高温固态塑性剪切变形的递进演化过程。由此可见,岩浆的上升与就位受左行走滑剪切作用的制约,岩体又遭受了强烈剪切变形改造。同时对这套构造前期就位花岗质岩石中的锆石进行定年分析,获得33.88±0.32Ma的岩浆结晶年龄,为此,我们有充分的理由认为,在点苍山地区哀牢山-红河剪切带左行走滑剪切作用的起始时间至少应该为早渐新世30.88±0.32Ma。     

Diatom assemblages from Costa Rican lakes: an initial ecological assessment

We compared the distributions of 59 diatom species in surface sediments of 25 Costa Rican lakes with 21 environmental variables using canonical correspondence analysis (CCA). The distribution of taxa was related to the chemical and physical characteristics of the lakes. The most influential chemical variables were cation concentrations (especially magnesium) and related variables such as water hardness, pH, and temperature. Lake area and lake depth were among the most important physical variables.A number of taxa were identified as potential environmental indicators. The diatoms Brachysira serians var. brachysira and Frustulia rhomboides seem to be associated with low values of alkalinity, hardness, Ca, Mg, and SiO2. Cymbella minuta var. silesiaca is associated with low to moderate values of alkalinity, hardness, Ca, and Mg. Nitzschia cf. amphibia may be an indicator of moderate-to-high concentrations of Mg. Pinnularia braunii var. amphicephala seems to prefer low values of hardness, Ca, Mg, and SiO2.In many closed lakes, these environmental variables (Mg/Ca/hardness/alkalinity) increase with effective evaporation. Consequently, these diatoms may be indirectly tracking P:E ratios. Results from this initial, small data set indicate the potential of diatoms for inferring lake paleochemistry, and perhaps P:E ratios, in Costa Rica.