New age constraints on emplacement of the Cévenol granitoids, South French Massif Central

During the development of the Variscan orogeny, large amounts of granitic melt were produced, giving rise to the intrusion of granitoids at different structural levels. Despite numerous studies, ages available from previous work on the Cévennes granites remain largely imprecise. In order to better constrain the age and emplacement mode of these granites, we have combined U–Pb dating on monazites and zircons and ⁴⁰Ar/³⁹Ar dating on biotites with petrological observations, major element chemical analysis and SEM zircon imaging on five samples from the Aigoual–St Guiral–Liron and Mont Lozère granitic massifs. The results revealed that granitic intrusions and cooling in Southern Cévennes occurred in a short time span at ∼306 Ma after the main episode of regional metamorphism. Petrological and chemical data suggest that they result from a mixing between mantle-derived basic magmas (lamprophyres) and lower crust acid magmas. At a regional scale the production of these melts occurred at the end of crustal thickening induced by nappe stacking, at the same time as the late anatectic events recorded further north in the Velay dome and the granulite facies metamorphism recorded in metasedimentary granulite enclaves brought up by Tertiary volcanoes of the Velay area (Bournac).     

The qualitative zoning record of minerals. A method for determining the duration of metamorphic events?

Summary The efficacy of ion exchange in petrological systems, for example the Fe-Mg exchange between garnet and biotite, is a function of grainsize, temperature, rates of temperature change and diffusion parameters. The combination of these variables determines the final zoning profile of minerals. Therefore, zoning profiles may be used to derive one of these variables if the others are known. For example, a mineral grain that experienced a short thermal event may still preserve a zoning profile characteristic of the heating path. In contrast, if that grain experienced a long thermal event it may develop a zoning profile typical of the cooling path. Conversely, for the same temperature-time cycle, large grains may not completely equilibrate at the metamorphic peak, and in smaller grains any previous record may have been erased. This is commonly observed in natural rocks where different grains within one thin section preserve often qualitatively different zoning profiles. Thus, a critical grainsize,l _crit, may exist that separates grains with qualitatively different zoning profiles so that grains of sizel > l _crit still retain zoning information about the heating path and grains of sizel <l _crit contain only information about the cooling path. If the critical grainsize can be measured and an independent estimate for the peak metamorphic temperature exists, the duration of the thermal event may, in principle, be estimated.The applicability of this method to natural garnets is hampered by a range of uncertainties. However, a parameterisation of the critical grain size may be used to illustrate the relative importance of grain size, temperature and event duration to the equilibration of minerals. In this paper, the critical grainsize is parameterized for various temperature-time cycles and its dependence on diffusion parameters is discussed. It is shown that, for Barrovian conditions,l _crit between 0.1 and 1 mm separates garnets retaining prograde information from garnets retaining cooling path information. For illustration, we compare the results with the critical grainsize of garnets from two metamorphic terranes, the Prydz Bay region (Antarctica) and the Koralm complex (Eastern Alps). Despite the large range of uncertainties attached to the method, it is shown that the critical grainsize of garnets in both terranes is consistent with a very short duration of the last thermal event that affected the two regions.

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Die qualitative Form von Zonierungsprofilen in Mineralen. Information über die Dauer metamorpher Ereignisse?

Zusammenfassung Zonierungsprofile von Paragenesen im Ionenaustausch, zum Beispiel das Fe-Mg Austauschsgleichgewicht zwischen Granat und Biotit, sind eine Funktion von (i) Korngröße, (ii) Temperatur, (iii) Kühl- und Heizgeschwindigkeit sowie (iv) den Diffusionskonstanen. Es sollte daher möglich sein, Zonierungsprofile dazu zu verwenden, einen dieser Parameter zu bestimmen, wenn die anderen bekannt sind. Zonierungsprofile von Kristallen die ein kurzes thermisches Ereignis erfahren haben, mögen daher prograde Information beinhalten, wogegen derselbe Kristall ein retrogrades Profil aufweisen mag, wenn er einem langlebigen thermischen Ereignis unterlag (prograd und retrograd ist hier als: bei ansteigender Temperatur und bei abfallender Temperatur definiert). In Kristallen die dem gleichen Temperatur-Zeitpfad unterworfen waren, könnten kleine Körner nur die Kühlgeschichte dokumentieren, wogegen große noch Zonierungsinformation vom Heizpfad aufweisen. In natürlichen Gesteinen wird das oft dadurch beobachtet, daß verschiedene Körner auseinem Dünnschliff qualitativ verschiedene Zonierungsprofile aufweisen. Es ist daher möglich eine kritische Korngöße,l _crit, zu definieren, die Korngrößen mit qualitativ verschiedenen Zonierungsprofilen voneinander trennt. Körner mit einem Durchmesserl > l _crit haben, zumindest teilweise, noch prograde Profile, wogegen Körner mitl <l _crit nur retrograde Information dokumentieren. Wenn man diese kritische Korngröße messen kann, sollte sie dazu benutzt werden können, etwas über die Dauer des thermischen Ereignisses auszusagen.Die Anwendbarkeit dieser Methode ist durch eine Reihe von Fehlern limitiert. Nichtsdestotrotz, ist eine Parameterisierung der kritischen Korngröße nützlich um die relative Wichtigkeit von Korngröße, Temperatur und Zeit, für die Entwicklung von Zonierungsprofilen, zu illustrieren. Unser Modell kann dazu benutzt werden, um die Größenordnung von Granaten abzuschätzen, die noch prograde Information dokumentieren können. Die Abhängigkeit der kritischen Korngröße von Diffusionsparametern und der Form des Temperatur-Zeit Pfades wird ebenfalls diskutiert. Es wird gezeigt, daß für Metamorphose in der mittleren Grünschiefer und Amphibolit fazies,l _crit zwischen 0.1 and 1 mm prograd zonierte von retrograd zonierten Granaten trennt. Um das Modell zu illustrieren, werden die Ergebnisse auf die Prydz Bay Region (Antarktis) und den Koralm Komplex (Ostalpen) angewendet. Trotz der großen Fehlergrenzen der Methode glauben wir zeigen zu können, daß die kritische Korngröße beider Terrains andeutet, daß das letzte thermische Ereignis in beiden Gebieten kurzlebig war.

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With 5 Figures     

A window to the operation of microplate tectonics in the Tethys Ocean: the geochemistry of the Samothrace granite,Aegean Sea

Summary The island of Samothrace, northeastern Aegean Sea, consists of five main geological units: (i) A basement unit consisting of low grade metamorphic rocks (metapelites, marbles, metavolcanic rocks, and a metaconglomerate); (ii) an ophiolitic complex with K-Ar hornblende date of 154 ± 7 and 155 ± 7 Ma; (iii) A granite intrusion with biotite K-Ar dates of 14.5 ± 0.3 and 14.5 ± 0.5 Ma, and a contact metamorphic event dated at 40.9 + 2.2 Ma; (iv) a unit of Cenozoic volcanic rocks: orogenic volcanism apparently occurred in two cycles with Upper Eocene tholeiitic to calc-alkaline volcanic rocks and post-Eocene high-K andesites to trachytes. (v) Quaternary clastic sedimentary rocks which occur around the peripheral parts of the island. The granitic intrusion is predominantly a hornblende-biotite granite, granodiorite or quartz monzonite, with porphyritic variants and mafic enclaves. The pluton is cut by granophyre, aplite and rare granodioritic veins. All lithological units of the Samothrace intrusion show smooth and continuous major element trends and similar chondrite- and Ocean Ridge Granite-normalized incompatible element profiles. ORG-normalized incompatible element contents of Hf, Zr, Sm are explained with fractionation close to the normalizing values Y and Yb contents combined with high K/Yb ratios; Rb and Th are significantly enriched relative to Nb and Ta. In Y-Nb and Rb-SiO₂ space most samples of the Samothrace granite, plot in the volcanic arc and the syn-collisional granite fields. In Y + Nb-Rb space they are equally distributed within and transgress these two domains. The geochemical and regional data suggest a subduction or collision environment but biotite mineral data do not support a collisional setting for magma genesis. The Samothrace granite was probaby associated with a post-collisional domain after the closure of the Axios section of the Tethys Ocean.

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Ein Einblick in das Wirken von Mikroplattentektonik in der Tethys—Die Geochemie des Samothrake Granites, Agäisches Meer

Zusammenfassung Die Insel Samothrake in der nordöstlichen Ägäis besteht aus fünf geologischen Haupteinheiten: (i) einem schwach metamorphen Basement (Metapelite, Marmore, Metavulkanite und Metakonglomerate); (ii) einem ophiolithischem Komplex, der mit K-Ar Datierungen an Hornblende ein Alter von 154 ± 7 und 155 ± 7 Ma ergab; (iii) ein granitischer Intrusionskörper mit K-Ar Altern an Biotit von 14.0 ± 0.3 und 14.5 ± 0.5 Ma und einem kontaktmetamorphen Ereignis, das mit 40.9 ± 2.2 Ma datiert ist; (iv) eine Abfolge känozoischer Vulkanite, wobei der orogene Vulkanismus offensichtlich in zwei Zyklen ablief mit tholeiitischen bis kalkalkalischen Vulkaniten im oberen Eozän und high-K Andesiten bis Trachyten im post-Eozän; (v) quartären klastischen Sedimentgesteinen, die im Randbereich der Insel auftreten. Die Granitintrusion setzt sich hauptsächlich aus Hornblende-Biotitgraniten, Granodioriten oder Quarzmonzoniten mit teilweise porphyrischen und mafischen Enklaven enthaltenden Varietäten zusammen. Der Pluton wird von Granophyren, Apliten und seltener von granodioritischen Gängen durchschlagen. Alle lithologischen Einheiten der Samothrake Intrusion zeigen kontinuierliche Hauptelementtrends und ähnliche Chondrit und ORG-normalisierte inkompatible Elementprofile. Die Gehalte an den inkompatiblen Elementen Hf, Zr, Sm sind sehr ähnlich denen von ozeanischen Graniten (ORG). Die niedrigen Y und Yb-Gehalte und die hohen K/Yb Verhältnisse werden durch Fraktionierung erklärt. Rb und Th sind signifikant angereichert im Vergleich zu Nb und Ta. In Y-Nb und Rb-SiO₂ Diagrammen plotten die meisten Proben des Samothrake Granites im Feld der vulkanischen Inselbogen- und Synkollisionsgranite. Im Y + Nb-Rb Diagramm zeigt sich eine gleichmäßige und überlappende Verteilung. Die geochemischen und regionalen Daten weisen auf einen Subduktions- oder Kollisionsbereich hin, obwohl die Biotitzusammensetzungen nicht für eine Bildung der Magmen in einem Kollisionsbereich sprechen. Die Bildung des Samothrake Granites steht möglicherweise mit post-Kollisionstektonik nach dem Schließen der Axioszone in der Tethys in Zusammenhang.

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With 7 Figures     

Thermodynamic data from redox reactions at high temperatures. IV. Calibration of the Re-ReO2 oxygen buffer from EMF and NiO+Ni-Pd redox sensor measurements

The chemical potential of oxygen defined by the equilibrium:

Thermodynamic data from redox reactions at high temperatures. II. The MnO-0Mn3O4 oxygen buffer,and implications for the thermodynamic properties of MnO and Mn3O4

The \(\mu _{O_2 } \) defined by the reaction 6 MnO+O₂ =2 Mn₃O₄ has been determined from 917 to 1,433 K using electrochemical cells (with calcia-stabilized zirconta, CSZ) of the type: Steady emfs were achieved rapidly at all temperatures on both increasing and decreasing temperature, indicating that the MnO-Mn₃O₄ oxygen buffer equilibrates relatively easily. It therefore makes a useful alternative choice in experimental petrology to Fe₂O₃-Fe₃O₄ for buffering oxygen potentials at oxidized values. The results are (in J/mol, temperature in K, reference pressure 1 bar); \(\mu _{O_2 } \) (±200)=-563,241+1,761.758T-220.490T inT+0.101819T ² with an uncertainty of ±200 J/mol. Third law analysis of these data, including a correction for the deviations in stoichiometry of MnO, impliesS _298.15 for Mn₃O₄ of 166.6 J/K · mol, which is 2.5 J/K · mol higher than the calorimetric determination of Robie and Hemingway (1985). The low value of the calorimetric entropy may be due to incomplete ordering of the magnetic spins. The third law value of Δ _r H _298.15 ⁰ is-450.09 kJ/mol, which is significantly different from the calorimetric value of-457.5±3.4 kJ/mol, calculated from Δ _f H _298.15 ⁰ of MnO and Mn₃O₄, implying a small error in one or both of these latter.     

Geochemistry of the Grenville Dyke Swarm: role of plume-source mantle in magma genesis

Major and trace element data of samples from the approximately 590 Ma Grenville dyke swarm, in the southeastern parts of the Canadian Shield, were used to evaluate the extent of crustal contamination of the dyke magma and to model its probable mantle source. The dyke rocks are mostly saturated, quartz tholeiites. A few samples represent transitional basalts. Their overall chemistries are similar to those of continental flood basalts. Their compositions resemble those of liquids initially produced in the garnet peridotite mantle zone and then subjected to polybaric fractionation. However, fractionation models fail to mass-balance Ti, Fe, K, and P. Geochemical and isotopic criteria indicate that crustal contamination was minimal. The incompatible elements Zr, Y, K, Rb, Nb, V, Ta, Hf, and Th show hyperbolic elemental ratio-ratio distributions indicative of mixing between two end-members. One end-member has elemental ratios similar to those of a depleted N-MORB source and the second of a P-MORB i.e. ertile or plume MORB source. The more enriched dyke compositions can be successfully reproduced by mixing models in the ratio of 6:1 between the most depleted MORB-like dyke magma and a liquid composition similar to metasomatic glass veinlets coexisting with mica peridotite mantle xenoliths, and subsequent crystal fractionation. The Grenville dykes are probably a synrift swarm that was emplaced along a rift arm related to an Iapetan rrr triple junction that is thought to have formed over a mantle plume. The chemistry of the dyke swarm is consistent with its derivation from a plume head, in that the minor enriched source can be identified with plume-source mantle and the major depleted source with entrained mantle. The magma probably originated in the upper cooler parts of the plume head.     

Vulkanogene Glasscherben-Relikte in Kohlentonsteinen des Saar-Lothringer Oberkarbons sowie Herkunft und Menge der Pyroklastika

Zusammenfassung Obwohl Kohlentonsteine aus dem Saar-Lothringer Oberkarbon seit etwa 170 Jahren bekannt sind, gelang erst in jüngster Zeit der Nachweis und die Identifikation vulkanogener Relikte im petrographischen Stoffbestand. Diese befinden sich in Kohlentonsteinen des Stefan A: KTst 0=950; Westfal D: KTst 1=700; Westfal C: KTst 3 =400, KTst 4a=330, KTst 4aß=322, KTst 4=320, KTst 5=300 und im KTst 6=270. Das entspricht einem Anteil von ca. 18 % an der Gesamtzahl der in diesem limnischen Steinkohlenrevier beobachteten Kohlentonsteine, die hier große praktische und wissenschaftliche Bedeutung besitzen. Die pseudomorphen Relikte bestehen aus kleinen Splittern, kleinen und größeren Fragmenten mit teilweise gut erhaltenem blasigen Gefüge von Vitroklasten — sie zeigen die für Aschenschmelztuffe typisch verschweißte Scherbentextur. Die Glassubstanz ist meist zu mikrokristallinem Kaolinit devitrifiziert. Der eindeutige Nachweis dieser Relikte ist für die Genese bedeutungsvoll, liefern sie doch nun den sicheren Beweis, daß der primäre Stoffbestand aus aerisch abgelagertem pyroklastischen Material bestand, das intensive chemische Verwitterungs- und diagenetische Umbildungsprozesse erfahren hat. Für die 43 Kohlentonsteine des Saar-Lothringer Oberkarbons wird eine pyroklastische Eruptionsmenge von mindestens 8,2 km³ Festvolumen bzw. 20,5 km³ Lokkervolumen angenommen. Die Eruptionen erfolgten vermutlich aus der in der Nähe befindlichen Metz-Hunsrück-Südrand-Tiefenstörung, die nach Reflexionsseismik bis unter die Moho reicht.

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Tonsteins in the Carboniferous of the Saar-Lorraine basin are known since about 170 years. Volcanic glass remains, however, have been proven as constituents of the tonstein only recently. They occur in tonsteins of Stephanian A: KTst 0=950; Westphalian D: KTst 1=700; Westphalian C: KTst 3=400, KTst 4a=330, KTst 4aß= 322, KTst 4=320, KTst 5=300 and KTst 6=270. Tonsteins with volcanic glass fragments amount to 18% of the total tonsteins observed in the limnic Saar-Lorraine basin. They are important to applied geology, e.g. for seam identification and correlation, as well as for scientific reasons, namely for the determination of provenance and genesis of tonsteins.The volcanic remains consist of tiny glass splinters, glass fragments, and of fragments with well preserved gasbubble texture. The welded splinter texture is typical of welded pyroclastic ash deposits. Much of the glass has been devitrified to microcrystalline kaolinite. The indisputable evidence of volcanic remains is essential when considering the genesis of tonsteins, as they provide proof that tonsteins are primarily composed of eolian pyroclastic constituents which were altered by chemical weathering and diagenesis.For the 43 horizons of the coal tonsteins found in the Upper Carboniferous of the Saar-Lorraine basin, a pyroclastic eruption quantity of at least 8.2 km³ of solid volume or 20.5 km³ of bulk volume is assumed. The eruptions possibly took place along the nearby deep-seated Metz fault at the southern rim of the Hunsrück. This fault, reaches below the Moho according to reflection seismic.

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Résumé Bien que des tonstein du Carbonifère supérieur de SarreLorraine soient connus depuis 170 ans c'est seulement il y a peu de temps que des fragments de verre volcanique y ont été identifiés. Ces fragments ont été rencontrés dans les niveaux de tonstein suivants: Stephanien A: KTst 0=950; Westphalien D: KTst 1=700; Westphalien C: KTst 3=400, KTst 4a=330, KTst 4aß=322, KTst 4=320, KTst 5=300 et KTst 6=270. Ces niveaux représentent une proportion de l'ordre de 18% dans le total des couches de tonstein carbonifère rencontrées dans ce bassin houiller limnique où elles présentent un grand intérêt tant au point de vue pratique que scientifique. Les verres se présentent en esquilles et en fragments de tailles diverses, montrant parfois une structure bulleuse bien conservée; ils présentent également les structures d'agglomération propres aux tufs soudés à chaud. Le verre est le plus souvent dévitrifié en kaolinite microcristalline. La présence de ces fragments est d'un intérêt particulier pour la genèse du dépôt puisqu'elle fournit la preuve que celui-ci était constitué de matériaux primaires pyroclastiques sédimentés dans l'air, matériaux qui ont subi ensuite des altérations chimiques et des transformations diagénétiques intenses.Pour l'ensemble des 43 horizons de tonstein du Carbonifère supérieur de la Sarre-Lorraine, on admet un volume de matières pyroclastiques d'au moins 8,2 km³ (volume à l'état monolithique) ou de 20,5 km³ (volume à l'état fragmenté). Ces éruptions ont probablement pour origine la faille de Metz, située à proximité, qui forme la limite sud du Hunsrück et que la sismique-réflexion permet de prolonger jusqu'au Moho.

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, (²⁰⁶/²⁰⁴ > 20.0) . . , .. , , . , , 100 . . . , - 20°, , .: . , . Bouguer'a, .

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Das Thema dieser Arbeit war Gegenstand des KurzvortragesBurger &Wolf (1987) auf dem XI. ICC in Peking (31. 8. bis 4. 9. 1987). Vorliegende Bearbeitung stellt die originäre Fassung dar.     

Astron observations of the Rapid Burster MXB 1730-335 and constraints on burster parameters from spectra of trailing bursts

We report on eight X-ray bursts detected by ASTRON from the Rapid Burster (RB) on 13 and 28 April and 16 August, 1983. Six of them (trailing bursts), with durations of 1.5–2 min, rise times of 5–10 s and intervals of 1–1.5 hours, exhibit spectral softening during the burst decay and may be related to the type I bursts. Two of the bursts (triangle bursts) observed on 28 April at interval of 28 min with much longer rise times (30–50 s) and longer durations (3 min), do not show distinct spectral softening. Persistent flux from RB on 16 August was estimated asF _p(2.0–2.4)×10^–9 erg cm^–2 s^–1. Spectral evolution of two trailing bursts was investigated by fitting their spectra in consecutive time intervals with the blackbody (BB), isothermal scattering photosphere (SP) and thermal bremsstrahlung (TB) models. Around the burst maxima the SP model fits the data best whereas in the burst tails the TB model is generally better. The BB model is worse than at least one of the two others. Interpretation of the burst spectra in terms of the BB radiation leads to improbably small neutron star mass and radius (M<0.86M ,R _NS<5 km) if the peak luminosity does not exceed the Eddington limit. Interpretation of the spectra around the burst maxima (3–15 s from the burst onset) in terms of an isothermal SP yields reasonable constraints onM,R _NS, and distanceD. For instance, for the hydrogen photosphere we obtainedM=(1.0–2.1)M R _NS=(7.1–16.4) km ifD=11 kpc. If one postulatesM=1.4M , thenD=(8.5–13) kpc for hydrogen photosphere; if, besides,D=11 kpc, thenR _NS=(8.1–13.3) km. It follows also from the SP-interpretation that the photosphere radius may increase up to 20–30 km in maxima of the trailing bursts when the luminosity becomes close to the Eddington luminosity.     

Three-dimensional model and late stage warping of the Plattengneis Shear Zone in the Eastern Alps

The Plattengneis shear zone is a 250–600 m thick, flat lying, Cretaceous, eclogite facies, mylonitic shear zone, with north-over-south transport direction, that is exposed over almost 1000 km² in the Koralpe region along the eastern margin of the Alps. Although the shear zone is one of the largest in the Alps, its role in the Eoalpine metamorphic evolution and the subsequent exhumation of the region, remain enigmatic and its large-scale geometry is not well understood. The outcrop pattern suggests that the shear zone is made up of a single sheet that is folded into a series of open syn- and antiforms with wavelengths of about 10 km. Eclogite bodies occur above, within and below the shear zone and there is no metamorphic grade change across the shear zone. In the south, the fold axes strike east–west and plunge shallowly to the east. In the north, the fold axes are oriented in north–south direction and form a dome shaped structure of the shear zone. Total shortening during this late stage warping event was of the order of 5%. Indirect evidence constrains this folding event to have occurred between 80 and 50 Ma and the fold geometry implies that the final exhumation in the Koralpe occurred somewhat later than further north. Interestingly, the shear zone appears to strike out of the topography in the south and dip into the topography in the north, so that north of the shear zone only hanging-wall rocks are exposed and south of it only foot-wall rocks. Possibilities for the geometric relationship of the Plattengneis shear zone with the surrounding south dipping detachments are discussed.     

Initiation and development of pull-apart basins with Riedel shear mechanism: insights from scaled clay experiments

Typical pull-apart structures were created in scaled clay experiments with a pure strike-slip geometry (Riedel type experiments). A clay slab represents the sedimentary cover above a strike-slip fault in the rigid basement. At an early stage of the development of the deformation zone, synthetic shear fractures (Riedel shears) within the clay slab display dilatational behaviour. With increasing basal displacement the Riedel shears rotate and open further, developing into long, narrow and deep troughs. The shear displacement and the low angle with the prescribed principal basal fault set them apart from tension gashes. At a more evolved stage, synthetic segments (Y-shears) parallel to the basal principal fault develop and accommodate progressive strike-slip deformation. The Y-shears connect the tips of adjacent troughs developed from the earlier Riedel shears, resulting in the typical rhomb-shaped structures characteristic for pull-apart basins. The Strait of Sicily rift zone, with major strike-slip systems being active from the Miocene to the Present, comprises pull-apart basins at different length scales, for which the structural record suggests development by a mechanism similar to that observed in our experiments.