Assessment of the impact of anthropogenic activities on the groundwater hydrology and chemistry in Tarsus coastal plain (Mersin,SE Turkey) using fuzzy clustering,multivariate statistics and GIS techniques

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Highlights? Four distinct groundwater classes resulted from the fuzzy c-means clustering method. ? Both geogenic and anthropogenic processes affect the groundwater quality in the area. ? Salinization in the area is due to seawater intrusion and dissolution of evaporites. ? Near the coastal zone, the groundwater level is lowered 2–5 m below the sea level. ? Ancient subsurface hydrological features act as conduits for groundwater flow.     

Decoding the complex internal chemical structure of garnet porphyroblasts from the Zermatt area,Western Alps

Garnet is a prototypical mineral in metamorphic rocks because it commonly preserves chemical and textural features that can be used for untangling its metamorphic development. Large garnet porphyroblasts may show extremely complex internal structures as a result of a polycyclic growth history, deformation, and modification of growth structures by intra‐ and intercrystalline diffusion. The complex internal structure of garnet porphyroblasts from garnet–phengite schists (GPS) of the Zermatt area (Western Alps) has been successfully decoded. The centimetre‐sized garnet porphyroblasts are composed of granulite facies garnet fragments overgrown by a younger generation of grossular‐rich eclogite facies garnet. The early granulite facies garnet (G‐Grt) formed from low‐P, high‐T metamorphism during a pre‐Alpine orogenic event. The late garnet (E‐Grt) is typical of high‐pressure, low‐temperature (HPLT) metamorphism and can be related to Alpine subduction of the schists. Thus, the garnet of the GPS are polycyclic (polymetamorphic). G‐Grt formation occurred at ~670 MPa and 780°C, E‐Grt formed at ~1.7 GPa and 530°C. The G‐Grt is relatively rich in Prp and poor in Grs, while E‐Grt is rich in Grs and poor in Prp. The Alm content (mol.%) of G‐Grt is 68 of E‐Grt 55. After formation of E‐Grt between and around fragmented G‐Grt at 530°C, the GPS have been further subducted and reached a maximum temperature of 580°C before exhumation started. Garnet composition profiles indicate that the initially very sharp contacts between the granulite facies fragments of G‐Grt and fracture seals of HPLT garnet (E‐Grt) have been modified by cation diffusion. The profiles suggest that Ca did not exchange at the scale of 1 µm, whereas Fe and Mg did efficiently diffuse at the derived maximum temperature of 580°C for the GPS at the scale of 7–8 µm. The Grt–Grt diffusion profiles resulted from spending c. 10 Ma at 530–580°C along the P–T–t path. The measured Grt composition profiles are consistent with diffusivities of log D_MgFe = ?25.8 m²/s from modelled diffusion profiles. Mg loss by diffusion from G‐Grt is compensated by Fe gain by diffusion from E‐Grt to maintain charge balance. This leads to a distinctive Fe concentration profile typical of uphill diffusion.     

Algal-silica cycling and pigment diagenesis in recent alpine lake sediments: mechanisms and paleoecological implications

The quality and interpretability of the paleobiological record depends on the preservation of morphological and geochemical fossils. Siliceous microfossils and sedimentary pigments are often cornerstones in paleoecology, although the microbial and geochemical processes conducive to their preservation remain poorly constrained. We examined sediments from an alpine lake in Banff National Park (Alberta, Canada) where diatom frustules are completely dissolved within 50 years of deposition. Diatom dissolution, silica recycling, and diagenetic alteration of algal pigments were investigated, in conjunction with porewater geochemistry and microelectrode profiling of the sediment–water interface. Analysis of sediment trap material showed ~90% of biogenic silica (BSi) production is lost prior to burial. Silica flux calculations, based on dissolved silica (as H₄SiO₄) in pore-waters, show a further ~6% of total BSi is returned to the water column from the upper 4 cm of sediments, implying that only ~4% of total BSi is permanently archived in sediments. In situ sediment pH and O₂ profiles reveal that aerobic respiration by bacteria fully consumes oxygen by a depth of 4 mm into the sediment, with associated strong pH and redox gradients. During sedimentation and early diagenesis, diatoms undergo loss of extracellular polymeric substances that coat their frustules, promoting silica dissolution and leading to the loss of the microfossil record by a depth of 3.25 cm. Sedimentary pigments similarly undergo rapid degradation, but diatom-related carotenoids persist below the depth of silica dissolution. This work provides new insights on diagenetic processes in lakes, with broad implications for the interpretation of sedimentary proxies for algal production.     

Ground level enhancements of solar cosmic rays during the last three solar cycles

The catalog of ground level enhancements of solar cosmic rays during cycles 21—23 of solar activity has been presented. The main properties, time distribution, and relation of these events to solar sources and proton enhancements observed on satellites have been studied.     

Hornblenden aus Eklogiten und Amphiboliten der südlichen Koralpe

Inhalt Hornblenden aus Eklogiten und Amphiboliten der südlichen Koralpe werden chemisch und optisch untersucht; außerdem sind die Gitterkonstanten der Hornblenden bestimmt worden.Herrn Prof. Dr.K. H. Scheumann in Verehrung zum 80. Geburtstag gewidmet.     

A survey to determine levels of chlorinated pesticides and PCBs in mussels and seawater from the Mid-Black Sea Coast of Turkey

A mussel and seawater monitoring survey was conducted at six sampling points between Yalikoy (Ordu) and Sinop in 1999-2000 along the Mid-Black Sea Coast of Turkey in order to assess concentrations of organochlorine pesticides (OCs) and polychlorinated biphenyls (PCBs). Chlorinated pesticides and PCBs were measured in the mussel Mytilus Galloprovincialis and in seawater. In the mussel samples, the most common pollutants in terms of average concentration per g of wet weight (ww), were DDT (max. 1800 pg/gww, min. 240 pg/gww) and its metabolites DDD (max. 5400 pg/gww, min. 240 pg/gww) and DDE (max. 2800 pg/gww, min. 70 pg/gww). Also, dieldrin, heptachlor and HCB were notable contaminants in the mussel samples. PCBs were determined in none of the biota or seawater samples. The concentrations of the OCs and PCBs in mussels were higher in coastal areas receiving river discharges and close to the largest city of the region, Samsun (especially in sampling points in the harbour area). The well-known long persistence of DDTs and other chlorinated compounds was confirmed by residues of these pollutants measured in mussels. On the other hand, even though the usage of such kind of persistent compounds in Turkey was banned, there may still be illegal usage and it is not certain whether the application of these compounds did end in the region.     

Schroeter's ratios for Martian craters: Radar results

Schroeter's ratios (ratios of the rim volume to the apparent volume) are determined for a sample of 29 large, degraded Martian craters selected from the Goldstone Mars radar altimetry data. On the average, the values of the calculated Schroeter's ratios are about two orders of magnitude smaller than the same ratios for fresh lunar craters. This indicates a severe rim volume deficit in degraded Martian craters and it provides an additional support to the notion of a widespread resurfacing of intercrater plains on Mars. Schroeter's ratios for degraded craters could provide a semi-quantitative measure of the effects of the modification processes that had been active on Mars and on the other planetary bodies.     

Launch window study for the highly eccentric orbit satellite HEOS-1

A satellite with a high eccentricitye0.95 is strongly perturbed by the sun and the moon. This fact and mission constraints restrict considerably the possible launch times for such a satellte. The launch window calculations can be performed in two steps in order to save computing time. An approximate analytical solution provides a general survey of the launch opportunities. An accurate numerical approach is then necessary for the exact definition of the launch window. In the case of the orbit of HEOS-1 (satellite 68 10901), moreover the consideration of the injection errors has been of great importance.Presented at the Conference on Celestial Mechanics, Oberwolfach, Germany, August 17–23, 1969.