Carbon-13 NMR spectra of macerals separated from individual coals

The density gradient centrifugation technique has recently been applied to the separation of macerals from whole coals. Sufficient quantities have been separated to permit examination of pure exinite, vitrinite and inertinite fractions by combined cross polarization and magic angle sample spinning (CP/MASS) carbon-13 NMR techniques. The similarities and differences observed in the maceral groups of two coals are discussed. Diversity in precursors or in differential chemical maturation or a combination of both of these factors can be used to account for subtle spectral differences in the two coals and macerals studied even though the gross spectral features are very similar for a given maceral type. The data show that CP/MASS is a technique that can address such interesting geochemical questions.     

First terrestrial occurrence of roedderite in volcanic ejecta of the Eifel,Germany

Idiomorphic crystals of roedderite occur in melt-coated cavities of xenoliths of contact-altered quartz-sillimanite and quartz-feldspar gneisses which were ejected with the tephritic lava of the Bellerberg volcano. Physical and chemical properties of three different sets of crystals agree generally with those of roedderites from meteorites, in which so far the mineral had been found exclusively. In detail, however, there are characteristic chemical differences amongst the Eifel roedderites with one set of crystals matching closely the ideal formula (Na,K)₂Mg₅ Si₁₂O₃₀, a second set containing excess alkalies according to the substitution Na⁺0.5 Mg²⁺, and a third set richer in iron having an alkali deficiency following Fe³⁺Fe²⁺+Na⁺.The terrestrial roedderites are considered to be precipitates from highly alkaline, MgSi-rich, but Aldeficient gas phases that evolved through contact heating of the gneisses by the tephrite magma.     

The lunar fossil bulge hypothesis revisited

The lunar gravity field can be satisfactorily explained by relatively-small wavelength, density anomalies located near the lunar surface. The exceptions to this are the second degree harmonics and we postulate a dual origin for these terms; they are partly a consequence of the same near-surface anomalies as the remainder of the gravity field and partly a measure of a fossil bulge. This latter contribution represents an equilibrium condition preserved from a time when the synchronously rotating Moon was approximately 25 Earth-radii from the Earth. If this shape was acquired at some time soon after 4.0 · 10⁹ years ago, then the rate of dissipation of tidal energy in the Earth has been much lower in the past then it is now. The implications of this on the evolution of the Earth-Moon system are briefly discussed.     

A simple method for calculating displacements and stresses around tunnel openings an application for the microcomputer

SummaryA Simple Method for Calculating Displacements and Stresses Around Tunnel Openings — An Application for the Microcomputer The paper describes a program, written for an Apple-II/Plus Microcomputer, and designed to calculate the perimetral elastic deformations and tangential stresses around underground openings of non-circular section. The mathematical basis used in this program first appeared in a paper by Dr. E. Wisser, published in Rock Mechanics. The Appendix gives the list of the program and all instructions which a user, familiar with computers, may require.With 5 Figures     

Flexure of the ocean lithosphere from island uplift, bathymetry and geoid height observations: the Society Islands

Summary. The response of a stratified elastic medium can be conveniently characterized by the Green's tensor for the medium. For coupled seismic wave propagation ( P—SV or fully anisotropic), the Green's tensor may be constructed directly from two matrices of linearly independent displacement solutions. Rather simple forms for the Green's tensor can be found if each displacement matrix satisfies one of the boundary conditions on the seismic field. This approach relates directly to 'reflection matrix' representations of the seismic field.
For a stratified elastic half space the Green's tensor is used to give a spectral representation for coupled seismic waves. By means of a contour integration a general completeness relation is obtained for the 'body wave' and 'surface wave' parts of the seismic field. This relation is appropriate for SH and P–SV waves in an isotropic medium and also for full anisotropy.