Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.     

Status of Macrobenthic Community and Its Relationships to Trace Metals and Natural Sediment Characteristics

Laizhou Bay, located in the northwest of Shandong Peninsula, has complex transitional environments between terrestrial and marine ecosystems. In the present study, a total of 122, 131, and 139 species were collected in spring, summer, and autumn 2011, respectively. Species constitutions of macrobenthos were grouped into four phyla, of which annelida were the most abundant phylum, the average biomass proportion of echinodermata was the lowest, and the proportion of important species for mollusca was the highest. The structure of the macrobenthic community showed significant differences between sites, and greater divergence was observed between the third site (S03) and other stations. The ABC plots showed that the biomass curve lay below the abundance curve, and the W‐statistic value was negative. The result of the BOPA index showed that two stations had moderate ecological status in spring and that there were two heavily polluted sites and one moderately polluted site in summer. The BIO‐ENV analyses indicated that the grain‐size fractions together with trace metals (Hg, Pb, Zn, Cu, and Cr) could be considered as the major environmental variables influencing the macrobenthic patterns. The results together demonstrated that the macrobenthic communities in Laizhou Bay were negatively affected, perhaps by the tremendous impact of heavy metals in the sediments.     

数字磁变仪的设计与实现

本文介绍了石英光电磁变仪及其数字化采集，记录的设计和实现，并讨论了数字磁变仪系统在地磁台站的应用结果。     

Re-discussion on the Jiaochang Arcuate Structure, Sichuan Province, and the Seismogenic Structure for Diexi Earthquake in 19331

The Jiaocbang arcuate structure is one of the numerous arcuate structural belts in Sichuan. The present paper gives a further argument about the characteristics of that arcuate structure and the new activity of the Songpinggou fault and affirms that the Songpinggou fault is an active fault in the Holocene epoch. The Diexi M7.5 earthquake took place in 1933 on the west wing of that arcuate structure, near the apex of the arc. Many authors have given quite different opinions about the genetic structure of that earthquake. The authors have made on-the-spot investigations time and again over recent years. Besides this, the authors have also further studied the shape of intensity contour lines, the distribution characteristics of ground surface seismic hazards, the left-lateral dislocation of buildings along the Songpinggou fault, the NWtrending ground fissures that developed on the ground surface after earthquake, and so on. On this basis, it is still considered that the seismogenic fault of the 1933 Diexi M7.5 earthquake was the Songpinggou fault on the west wing of the Jiaochang arcuate structure.     

高低空急流在闽西北大暴雨过程中的作用及数值模拟

本文对2002年6月14~18日福建西北部地区的连续暴雨~大暴雨过程的诊断及模拟分析表明,在有利的环流背景条件下,高空急流的加强和动量下传,促使低空急流的建立和维持;低空急流的加强则提供了有利暴雨产生的高温高湿的大气条件;高低空急流的适宜配置,产生了动力场的耦合作用,为大暴雨的发生、发展提供了动力条件。     

南海海平面高度年循环的特征

根据 ＴＯＰＥＸ／ ＰＯＳＥＩＤＯＮ－ＥＲＳ高度计提供的海平面高度异常资料和并行海洋气候模式（ＰＯＣＭ）模拟海平面高度资料，分析了南海海平面高度年循环特征。结果表明：ｌ月，３月和５月海平面高度的异常值分别与７月，９月，１１月的异常值相反。ｌ月（７月），深水海区与吕宋海峡的海平面高度为负（正）异常，在大部分陆架区和南海的西和南部，海平面高度为正（负）异常。在３月（９月），除海平面高度异常的量级已减少，且较小的ＳＳＨ正异常（负异常）出现在南海的中部以外，海平面高度异常的分布型与 １月（７月）类似； ＳＳＨ的年循环的最大振幅出现在吕宋岛的西北海域；风的季节变化是南海ＳＳＨ季节变化的主要原因。     

吉林省敦化市乡村人群气候变化感知的偏差及群体分异研究

通过问卷调查,具体分析了吉林省敦化市乡村人群对气候变化趋势和极端冷暖年的感知偏差及人群分异.发现乡村人群对气候变化趋势的感知与科学事实比较符合,由于对变暖转折年代更敏感,因而对变暖的确认度在一些时段与科学事实在变化程度或幅度上存在比较大的偏差.乡村人群对极端冷暖年不如对趋势感知的准确度高.经验积累影响乡村人群对气候变化...     

二次特征值问题的最佳向后扰动分析

二次特征值问题 (QEP)的主要的求解方法之一是转化为广义特征值问题 (GEP) ,然后用求解广义特征值的方法 (比如 QZ方法 )求解。本文研究由此获得的计算解的范数意义下的最佳向后扰动分析 ,所得结果是 Tisseur最近所得结果的加强。     

几类特殊的矩阵多项式

本文讨论几类特殊的矩阵多项式,先介绍几个基本概念,然后证明。对这几类特殊的矩阵多项式,与之相应的L—值问题可转化为低次的代数多项式求根问题。最后,使用“投影尺度”建立了L—值的摄动定理。     

海洋中液-固界面作用的分形研究Ⅰ.SAXS法测量固体交换剂的分维

本文将分形作为一个新概念,应用到海洋化学的液-固界面作用的一系列的研究上。根据用SAXS法测定一些常见的粘土矿物(高岭石,蒙脱石)和水合氧化物(水锰矿、δ-MnO_2、氧化铁凝胶、针铁矿、无定形氧化铁)的分维结果,可将这些结果划分成三类:(1)小尺度模量下具有表面分形;大尺度模量下具有质量分形。(2)只有一种分维值的表面分形。(3)在小尺度模量下和大尺度模量下分别具有不同分维值的表面分形。