Heavy metals in Changjiang estuarine and offshore sediments: responding to human activities

The Changjiang (Yangtze) estuarine and offshore sediments were analyzed for total heavy metals concentrations and chemical fractions.Distributions of heavy metals show typical banded diffusion pattern,with high concentrations near the river mouth and following a decreasing trend in the offshore direction.According to chemical fractions,Fe/Mn oxide fraction is the major non-residual fraction in the Changjiang estuarine and offshore sediments.Higher percentage of non-residual fraction of Pb implies that,the industrial contaminations transported via the atmosphere and river input,may affect the non-residual fraction of heavy metals.Over past fifteen years,the concentration of Pb normalizing to Al presents significant increasing trend,corresponding to the effect of human activities.By comparison of heavy metals fractions in 2003 to 2006,it has been realized that increasing water and sediment may cause a higher percentage non-residual fraction of Cu in the southern part of offshore muddy sediments.     

Cretaceous reactivation and intensified erosion in the Archean–Proterozoic Limpopo Belt,demonstrated by apatite fission track thermochronology

Cratons are generally assumed to be regions of long-lasting tectonic stability. In particular the study of the Phanerozoic exhumation history of cratons has been largely hampered by the scarcity of suitable stratigraphic controls onshore. This fact is even more pronounced in terranes lacking Mesozoic or younger penetrative structural fabrics and metamorphic overprinting. Our study in the Limpopo belt shows that modern apatite fission track thermochronology provides a hitherto unavailable perspective in the study of these rocks, and has profound implications for the crustal evolution of the Zimbabwe Craton.Apatite fission track data from 35 samples taken along two transects, in the southern edge of the Zimbabwe Craton and in the Central Zone of the Limpopo Belt, suggest that extensive regions experienced kilometer-scale exhumation in two discrete events, as recently as the Cretaceous. The first occurred at around 130 Ma, and the second at around 90 Ma. Basin subsidence and sedimentation loads on the Mozambique margin support the timing of these events and provide strong indications of the source and pathways for the eroded material. Further, the results indicate that young and old “surfaces” (in a geomorphological sense) may be structurally juxtaposed in regions of high elevation in Zimbabwe. This is contrary to early ideas of surface chronologies based on summit accordances or invoking pediplanation.     

Geochemistry of xenolithic eclogites from West Africa, part 2: origins of the high MgO eclogites

Oxygen isotope, mineral trace element, and measured and reconstructed whole-rock compositions are reported for the high MgO eclogite xenolith suite (16 to 20 wt% MgO in the whole rock) from the Koidu Kimberlite complex, Sierra Leone. In contrast to the previously published data for low MgO eclogites (6 to 13 wt% MgO) from this area, high MgO eclogites equilibrated at higher temperatures (1080 to 1130°C vs. 890 to 930°C) have only mantlelike δ¹⁸O and show variable degrees of light rare earth element (REE) enrichment. Analyses of multiple mineral generations suggest that the heterogeneous REE patterns of the high MgO eclogites reflect variable degrees of metasomatic overprinting. High MgO and Al₂O₃ contents of the eclogites suggest a cumulate origin, either as high-pressure (2 to 3 GPa) garnet-pyroxene cumulates or low-pressure (<1 GPa) plagioclase-pyroxene-olivine cumulates. Trace element modeling suggests a low-P origin for eclogites with flat heavy REE patterns and a high-P origin for eclogites with fractionated heavy REE. Flat heavy REE patterns, the presence of Sr anomalies, and low to moderate transition element contents in the low-P group are consistent with a low-pressure origin as metamorphosed olivine gabbros and troctolites. These metagabbroic high MgO eclogites either could represent the basal section of subducted oceanic crust or foundered mafic lower continental crust. In the former case, the metagabbroic high MgO eclogites may be genetically related to the Koidu low MgO suite. Crystal fractionation trends suggest that the metapyroxenitic high MgO eclogites formed at lower pressures than their current estimated equilibrium pressures (>4 GPa).     

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 2: comparison to other records

A new Greenland Ice Core Chronology (GICC05) based on multi-parameter counting of annual layers has been obtained for the last 42 ka. Here we compare the glacial part of the new time scale, which is based entirely on records from the NorthGRIP ice core, to existing time scales and reference horizons covering the same period. These include the GRIP and NorthGRIP modelled time scales, the Meese-Sowers GISP2 counted time scale, the Shackleton–Fairbanks GRIP time scale (SFCP04) based on ¹⁴C calibration of a marine core, the Hulu Cave record, three volcanic reference horizons, and the Laschamp geomagnetic excursion event occurring around Greenland Interstadial 10. GICC05 is generally in good long-term agreement with the existing Greenland ice core chronologies and with the Hulu Cave record, but on shorter time scales there are significant discrepancies. Around the Last Glacial Maximum there is a more than 1 ka age difference between GICC05 and SFCP04 and a more than 0.5 ka discrepancy in the same direction between GICC05 and the age of a recently identified tephra layer in the NorthGRIP ice core. Both SFCP04 and the tephra age are based on ¹⁴C-dated marine cores and fixed marine reservoir ages. For the Laschamp event, GICC05 agrees with a recent independent dating within the uncertainties.     

Molecular characterization of dissolved organic matter in pore water of continental shelf sediments

Dissolved organic matter (DOM) in sediment pore water is a complex molecular mixture reflecting various sources and biogeochemical processes. In order to constrain those sources and processes, molecular variations of pore water DOM in surface sediments from the NW Iberian shelf were analyzed by ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) and compared to river and marine water column DOM. Weighted average molecular element ratios of oxygen to carbon ((O/C)_wa) and hydrogen to carbon ((H/C)_wa) provided general information about DOM sources. DOM in local rivers was more oxygenated ((O/C)_wa 0.52) and contained less hydrogen ((H/C)_wa 1.15) than marine pore water DOM (mean (O/C)_wa 0.50, mean (H/C)_wa 1.26). The relative abundance of specific compound groups, such as highly oxygenated aromatic compounds or nitrogen-bearing compounds with low H/C ratios, correspond to a high concentration of lignin phenols (160 μg/g sediment dry weight) and a high TOC/TN ratio (13.3) in the sedimentary organic matter and were therefore assigned to terrestrial sources. The lower degree of unsaturation and a higher relative abundance of nitrogen-bearing compounds in the pore water DOM reflected microbial activity within the sediment. One sampling site on the shelf with a high sediment accumulation, and a humic-rich river sample showed a wide range of sulfur compounds in the DOM, accompanied by a higher abundance of lipid biomarkers for sulfate-reducing bacteria, probably indicating early diagenetic sulfurization of organic matter.     

Metamorphic reactions between fluid inclusions and mineral hosts. I. Progress of the reaction calcite+quartz=wollastonite+CO2 in natural wollastonite-hosted fluid inclusions

 At the Bufa del Diente contact-metamorphic aureole, brine infiltration through metachert layers embedded in limestones produced thick wollastonite rims, according to Cc+Qz=Wo+CO₂. Fluid inclusions trapped in recrystallized quartz hosts include: (1) high salinity four phase inclusions [Th(V-L)=460–573° C; Td(salts)=350–400° C; (Na+K)_Cleq=64–73 wt%; X _{CO 2}≤0.02]; (2) low density vapour-rich CO₂-bearing inclusions [Th(L-V)≈500±100° C; X _{CO 2}=0.22–0.44; X _NaCl≤0.01], corresponding to densities of 0.27± 0.05 gcm⁻³. Petrographical observations, phase compositions and densities show that the two fluids were simultaneously trapped in the solvus of the H₂O-CO₂-salts system at 500–600° C and 700±200 bars. The low density fluid was generated during brine infiltration at the solvus via the wollastonite producing reaction. Identical fluid types were also trapped as inclusion populations in wollastonite hosts 3 cm adjacent to quartz crystals. At room temperature, both fluid types additionally contain one quartz and one calcite crystal, generated by the back-reaction Wo+CO₂=Cc+Qz of the host with the CO₂-proportion of the fluid during retrogression. All of the CO₂ was removed from the fluid. On heating in the microstage, the reaction progress of the prograde reaction was estimated via volume loss of the calcites. In vapour-rich fluids, 50% progress is reached at 490–530° C; 80% at 520–560° C; and 100% at 540–590° C, the latter representing the trapping temperatures of the original fluid at the two fluid solvus. The progress is volume controlled. With knowledge of compositions and densities from unmodified inclusions in quartz and using the equation of state of Duan et al. (1995) for H₂O-CO₂-NaCl, along with f _{CO 2}-values extracted from it, the reaction progress curve was recalculated in the P-T-X-space. The calculated progress curve passes through the two fluid solvus up to 380° C/210 bars, continues in the one fluid field and meets the solvus again at trapping conditions. The P-T slope is steep, most of the reaction occurs above 450° C and there is high correspondence between calculated and measured reaction progress. We emphasize that with the exception of quartz, back-reactions between inclusion fluids and mineral hosts is a common process. For almost any prograde metamorphic mineral that was formed by a devolatilization reaction and that trapped the equilibrium fluid or any peak metamorphic fluid as an inclusion, a fluid-host back-reaction exists which must occur somewhere along the retrograde path. Such retrograde reactions may cause drastic changes in density and composition of the fluid. In most cases, however, evidence of the evolving mineral assemblages is not given for they might form submicroscopical layers at the inclusion walls. Received: 15 March 1995 / Accepted: 1 June 1995     

西藏更新世冰川作用与冰期的开始——一个自循环假说

十次考察任务期间,我们获得了西藏及其周围山地冰川最大规模的新资料。在喜马拉雅山和喀喇昆仑山南侧低至890m和980m的海拔高度上发现冰碛物。在青藏高原北坡的祁连山,冰碛物发现于2300m的海拔高度。在喀喇昆仑山、Aghil和昆仑山北坡,冰碛物也低达1900m。对冰漂砾的放射性分析表明,青藏高原南部和中部古冰体厚度至     

Über den Einfluß fluktuierender Windfelder auf ein stetig geschichtetes Meer

Zusammenfassung Am geschichteten Meer werden die erzwungenen Schwingungen theoretisch untersucht, die ein an der Oberfl?che angreifender Wind hervorruft. Grunds?tzlich entsteht an der Oberfl?che eine Grenzschicht mit gro?er Horizontalgeschwindigkeit. Für den Fall, da? ihre Ausdehnung klein gegenüber der inneren Region ist, werden die erzwungenen Schwingungen (Abschnitt 2) analytisch berechnet. Interne Wellen oberhalb der Tr?gheitsperiode sind klein und auf sehr kleine Wellenzahlen beschr?nkt. Die physikalische Erl?uterung sowie die Tatsache, da? einige spezielle Windfelder keine internen Wellen anregen k?nnen, bringt Abschnitt 3, die numerische L?sung für beliebige Frequenzen und Wellenzahlen Abschnitt 4. Interne Wellen unterhalb der Tr?gheitsperiode werden haupts?chlich durch die Divergenz des Windfeldes hervorgerufen, solche oberhalb der Tr?gheitsperiode durch die Rotation des Windfeldes, und es ergeben sich unterschiedliche funktionale Zusammenh?nge zwischen Wind und internen Wellen. Die hier vorgelegten Ergebnisse k?nnen nur mit Hilfe einer tangential an der Oberfl?che angreifenden Kraft erhalten werden und weisen wesentliche Unterschiede gegenüber ?hnlichen Ergebnissen auf, die für den Windeinflu? eine Volumenkraft annehmen.

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On the influence of fluctuating winds on a continuously stratified ocean

Summary The model of a stratified ocean is used for a theoretical study of the forced oscillations caused by the wind acting upon the surface. A boundary layer with high horizontal velocity is principally generated at the surface. If it is narrow as compared with the inner region, the forced oscillations (section 2) are computed analytically. Internal waves above the inertia period are small and confined to very small wave numbers. The physical explanation and the fact that special wind fields cannot generate internal waves, are given in section 3; the numerical solution for arbitrary frequences and wave numbers is treated in section 4. Internal waves below the inertia period are mainly caused by the divergence of the wind field; those above the inertia period by the rotation of the wind field; and different functional connections between the wind and the internal waves are the results. The results presented here can be obtained only by means of a force acting tangentially upon the surface. They differ essentially from similar results based upon the assumption of a volume force for the wind effect.

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Influence de champs de vent fluctuants sur une mer contin?ment stratifiée

Résumé On étudie et on calcule analytiquement (paragraphe 2) pour une mer stratifiée, les oscillations provoquées par un vent s'attaquant à la surface. En principe, il se forme à la surface une couche-limite à grande vitesse horizontale. Les ondes internes au-dessus de la période d'inertie sont petites et se limitent à de très petits nombres d'ondes. Le paragraphe 3 donne l'explication physique et signale le fait que quelques champs de vent spéciaux ne peuvent pas provoquer d'ondes internes; le paragraphe 4 apporte une solution numérique pour des fréquences et des caractéristiques numériques d'ondes quelconques. Les ondes internes au-dessous de la période d'inertie sont dues principalement à la divergence du champ de vent, celles au-dessus de la période d'inertie, à la rotation de ce champ; et on trouve des rapports fonctionnels distincts entre le vent et les ondes internes. Les résultats exposés ici ne peuvent être obtenus qu'à l'aide d'une force attaquant tangentiellement la surface, ils diffèrent notablement des résultats correspondants obtenus en admettant que l'influence du vent s'exerce sous forme d'une force non tangentielle.

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Mit der — hier gekürzt — vorliegenden Arbeit promovierte der Verfasser bei der Mathematisch-Naturwissenschaftlichen Fakult?t der Christian-Albrechts-Universit?t Kiel.     

4D velocity of Strombolian eruptions and man-made explosions derived from multiple Doppler radar instruments

We used a novel system of three continuous wave Doppler radars to successfully record the directivity of i) Strombolian explosions from the active lava lake of Erebus volcano, Antarctica, ii) eruptions at Stromboli volcano, Italy, and iii) a man-made explosion in a quarry.     

On the ice age glaciation of the Tibetan highlands and its transformation into a 3-D model

We present an interdisciplinary study on data and modeling intercomparison, concerning the possible existence of a Tibetan ice sheet and its climatological implications during the ice age. In the ice sheet model the fields of ice flow and temperature are calculated, and a highly parameterized formulation of the yearly snow balance is used, defining the forcing at the surface of the ice sheet. The data set used, supplies the height of the equilibrium line of the glaciers (=ELA) and documents the maximum extension of the glaciated areas. With prescribed snow accumulation above the ELA and melting below, the model is integrated for 10 000 model years and the model glaciation is then compared with the data.The main results are: Provided the height of the glacial equilibrium line has been reconstructed correctly, a Tibetan ice sheet can be bult up within 10 000 model years, using moderate rates of precipitation (maximum snow fall: 100 mm/year). Comparison of data and model glaciation suggests an increase of precipitation from the NW to the E of Tibet and from the S to the NE, which reflects the presently observed pattern of the monsoon circulation.