Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

Factors that contributed to recent eutrophication of two Slovenian mountain lakes

Increased eutrophication was recently observed in the 5th (5J) and 6th (6J) Triglav Lakes, two remote Slovenian mountain lakes. Sediment phosphorus (P) pools were analysed and potential external P sources affecting the lakes (atmospheric deposition, terrestrial export and nearby hut) evaluated, to assess the effects of internal and external changes on the lakes. A sequential extraction procedure was used to quantify five P fractions from the sediments: adsorbed (NH₄Cl–P), redox-sensitive (BD–P), aluminium- (NaOH–P) and calcium- (HCl–P) bound, and refractory organic (Res–P) P. Total phosphorus (TP) contents in surface sediment of 5J and 6J were 1430 and 641 µg P g^?1 dry weight sediment (dw), respectively. TP varied with depth in 5J sediments, but displayed no discernible pattern, whereas it decreased steadily downcore in 6J. Contents of all P forms were distinctly higher in 5J than 6J, but their rank order and relative abundances were similar in the two lakes. Res–P was the most abundant P fraction, followed by HCl–P. Together, the two P forms accounted for nearly 80 and 90% of TP in 5J and 6J sediments, respectively. BD–P and NaOH–P were less abundant, with each fraction accounting for 3 to 9% of TP, whereas NH₄Cl–P was least abundant. Atmospheric deposition and terrestrial export were substantial sources of P for the lakes. Delivery of the former was estimated to be at least 7.5 mg P m^?2 yr^?1 and the latter around 20 mg P m^?2 yr^?1. We concluded that P was not retained in the catchment effectively, likely because of only slightly acidic soil pH (5.9), relatively low aluminium content and high organic matter content (53%) in soils, resulting in higher vulnerability of the studied lakes to eutrophication. The mountain hut could also be a significant source of P for the lakes. Each year, it could potentially contribute ~12 kg of soluble P to the environment, but the true impact of the hut on lake trophic status remains unclear.     

Size-differential feeding in Pinna nobilis L. (Mollusca: Bivalvia): Exploitation of detritus,phytoplankton and zooplankton

The endangered fan shell Pinna nobilis is a large bivalve mollusc (<120 cm shell length) endemic to the Mediterranean that lives one-third buried in soft substrata, generally in shallow coastal waters. We hypothesised that P. nobilis of different sizes would ingest different food sources, because small fan shells will inhale material from closer to the substratum than do large fan shells. We studied stomach contents and faeces of 18 fan shells, 6 small (mean 23.0 cm length), 6 medium-sized (mean 41.5 cm length) and 6 large (mean 62.7 cm length) living in a small area of a low-energy coastal detritic bottom characterised by mud, sand and macroalgae at Mali Ston Bay, Croatia. We found that all P. nobilis ingested copious quantities of undetermined detritus (probably at least 95% of ingested material), phytoplankton, micro and mesozooplankton and pollen grains. Large P. nobilis stomach contents showed a preponderance of water column calanoid copepods, while small fan shells had higher numbers of bivalve larvae. All fan shells took in high numbers of harpacticoid copepods that are benthonic, feeding on microbial communities of detritus and benthic vegetation. There was also a significant selection of phytoplankton species, some apparently occurring between inhalation and ingestion. The stomach contents of small P. nobilis had a higher organic matter content than either medium-sized or large fan shells; this indicated that small fan shells ingested detritus of higher organic content than did larger P. nobilis. As the faeces of all P. nobilis had similar organic matter content, this also indicates higher assimilation efficiencies in small fan shells. The demonstration of differential dietary selectivity by different sized animals has implications for future trophic studies of this endangered species. This study also provides the first demonstration of predation on zooplankton by P. nobilis.     

Assessment of the natural and anthropogenic sources of chemical elements in alluvial soils from the Drava River using multivariate statistical methods

The objectives of this study are as follows: (a) an assessment of the geochemical background signature of the Drava Valley before the industrial revolution; (b) an evaluation of anthropogenic geochemical influences on the alluvial plains and river terraces in the valley; and (c) a determination of the spatial distribution of trace elements in the alluvial soils of the Drava River downstream of the Austrian–Slovenian border to the confluence of Mura and Drava Rivers.     

Characterization of atmospheric surfactants in the bulk precipitation by electrochemical tools

Characterization of atmospheric surfactants in bulk precipitations was carried out by adsorption study at the mercury electrode/solution interface using phase sensitive AC voltammetry. The structure and permeability of the adsorbed organic films at the mercury electrode was tested using the redox processes of lead and cadmium ions as electrochemical tools. The effects of organic matter from the bulk precipitations (rainwater and melted snow) were compared to those obtained for aqueous solutions of model substances: aromatic hydrocarbon (naphtalene), anionic surfactant (sodium dodecylbenzene sulfonate, NDBS), protein (albumine) and selected model substances suggested to be representative of water soluble organic compounds (WSOC) in atmospheric water (monocarboxylic, dicarboxylic, and polyacidic compounds and levoglucosan). It was found that substances like humic acid and 3-hydroxybutanoic acid may play an important role in atmospheric heterogeneous chemistry because of their surface active potential.     

Circumstellar dust and variability of carbon stars

A sample of 35 variable carbon stars has been considered. The stellar temperatures, radii, absolute luminosities, masses, and mass loss rates have been estimated. Then the spherical circumstellar dust shells around the analysed stars are discussed and the differences in the infrared properties between semi-regular, irregular, and long-period variables are indicated.     

On forecasting of cyclogenesis in the West Mediterranean and other areas bounded by mountain ranges by baroclinic model

Summary Changes occurring in the thermal structure of air masses in the Alps area and the West Mediterranean region, during cyclonic developments in the Gulf of Genoa, have been considered. The effect of the height and the form of the mountain ranges as well as that of the nonadiabatic processes, on the deformation of the thickness pattern, have been discussed. These factors have been further taken into consideration for a modification of the equations used inEstoque's method for the baroclinic model, and a new method has been developed for forecasting cyclogenesis in regions bounded by mountain ranges.

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Zusasmmenfassung Es werden die Änderungen der thermischen Struktur der Luftmassen im Alpengebiet und im westlichen Mittelmeerraum bei der Entwicklung von Zyklonen im Golf von Genua aufgezeigt und die Einflüsse von Höhe und Form der Gebirgszüge sowie von nichtadiabatischen Vorgängen auf die Deformation der relativen Topographie besprochen. Diese Faktoren werden auch zur Modifikation der in der Methode vonEstoque für ein baroklines Modell verwendeten Gleichungen in Betracht gezogen und damit wird eine neue Methode zur Vorhersage der Zyklogenese unter dem Einfluß von Gebirgszügen entwickelt.

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Résumé On expose dans ce mémoire à quelles modifications la structure thermique des masses d'air est soumise dans la région des Alpes et dans le bassin occidental de la Méditerranée lors du développement de dépressions sur le Golfe de Gênes. On y discute en outre l'influence de la hauteur et de la forme des chaînes de montagnes ainsi que celle des processus non-adiabatiques sur des déformations de la topographie relative. Tous ces éléments sont pris en considération pour leur adapter les équations utilisées dans le modèle baroclined'Estoque. Par là, on accède à une nouvelle méthode de prévision de la cyclogénèse, méthode qui tient compte de l'influence des chaînes de montagnes.

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With 5 Figures     

Comparison of three mathematical models for the estimation of 10-day drain discharge

Summary This paper presents an the evaluation of three mathematical models for the estimation of 10-day drain discharge using weather, pedological and phenological parameters. One model uses modified Palmer’s procedure for the calculation of water balance components and the second two use empirical multiple linear regression. The models have been applied to data of an amelioration experimental field in central Croatia (south-western part of the Pannonian Lowland), where a set of average 10-day air temperature and relative humidity data, average wind speed, cumulative precipitation and drain discharge amounts, insolation and soil moisture data and vegetation indices have been collected. The experiment has been performed during the period 1990–1992. The models have been tested by comparing estimated and observed 10-day drain discharge amounts. All models mainly give acceptable cumulative results although their accuracy depends on the season.     

Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia

In order to examine the extent of the As enrichment and the factors influencing this enrichment in the groundwater of Eastern Croatia, groundwater samples were collected from 56 production wells in two counties, Osijek-Baranja and Vukovar-Srijem, suspected to be more affected. Hydrochemical analyses were performed at all locations including in situ As speciation at 32 locations. Arsenic was detected in 46 out of 56 groundwater samples with total As concentrations up to 491 μg/L. Thirty-six of the studied wells yielded groundwater with total As concentrations that exceeded the WHO Maximum Contaminant Level for arsenic in drinking water of 10 μg/L. Only inorganic As species were detected with arsenite As(III) as the predominant form. The spatial distribution of As in the groundwater was significantly linked with geological, geomorphological and hydrogeological development of the alluvial basin of the Drava and Sava rivers. The most probable groundwater As sources are deeper sediments from the Middle and Upper Pleistocene. The results obtained suggest that biogeochemical processes controlling As concentration in the groundwater are complex and location-specific. Reductive dissolution of Fe oxides, desorption of As from Fe oxides and/or clay minerals as well as competition for the sorption sites with organic matter and phosphate could be the principal mechanisms that control As mobilization. The extent of those processes vary in the different parts of the Drava and Sava depressions and could be linked to different site related parameters, such as lithology, mineralogy, local hydrology and hydrogeology; thus different processes of As mobilization have been proposed for the different types of water in relation to groundwater evolution.