Magnetic particles in atmospheric particulate matter collected at sites with different level of air pollution

Magnetic measurements of deposited atmospehric dust can serve as an additional parameter in assessing environmental pollution. This method is based on the assumption that atmospherically deposited particles contain significant portion of ferrimagnetic iron oxides of anthropogenic origin, which can be easily detected. Aim of this paper is to identify clearly magnetic fraction of daily samples of particulate matter less than 10 μm (PM10), routinely used for air quality assessment and monitoring. We used combination of thermomagnetic analyses and other physical and chemical methods, including scanning electron microscopy (SEM) and Mössbauer spectroscopy. Our results show that daily samples of PM10, collected at sites with different degree of atmospheric pollution, contain magnetite of spherical shape, which is presumably of industrial origin. Thus, magnetic methods can be applied directly to the same substances, which are used routinely in air quality assessment and monitoring.     

Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.     

Residual drift demands in moment‐resisting steel frames subjected to narrow‐band earthquake ground motions

This paper presents the main results of the evaluation of residual inter‐story drift demands in typical moment‐resisting steel buildings designed accordingly to the Mexican design practice when subjected to narrow‐band earthquake ground motions. Analytical 2D‐framed models representative of the study‐case buildings were subjected to a set of 30 narrow‐band earthquake ground motions recorded on stations placed in soft‐soil sites of Mexico City, where most significant structural damage was found in buildings as a consequence of the 1985 Michoacan earthquake, and scaled to reach several levels of intensity to perform incremental dynamic analyses. Thus, results were statistically processed to obtain hazard curves of peak (maximum) and residual drift demands for each frame model. It is shown that the study‐case frames might exhibit maximum residual inter‐story drift demands in excess of 0.5%, which is perceptible for building's occupants and could cause human discomfort, for a mean annual rate of exceedance associated to peak inter‐story drift demands of about 3%, which is the limiting drift to avoid collapse prescribed in the 2004 Mexico City Seismic Design Provisions. The influence of a member's post‐yield stiffness ratio and material overstrength in the evaluation of maximum residual inter‐story drift demands is also discussed. Finally, this study introduces response transformation factors, T_p, that allow establishing residual drift limits compatible with the same mean annual rate of exceedance of peak inter‐story drift limits for future seismic design/evaluation criteria that take into account both drift demands for assessing a building's seismic performance. Copyright © 2013 John Wiley & Sons, Ltd.     

Runoff and sediment yield from land under various uses in a Mediterranean mountain area: long‐term results from an experimental station

In this study we analyzed runoff and sediment yield from land under various traditional and current land uses in Mediterranean mountain areas, using long‐term data from an experimental station in the Aísa Valley, Central Spanish Pyrenees. Monitoring at this station has provided 20 years of data that can help explain the hydrological and geomorphological changes that have been observed at larger spatial scales, and also the changes that have occurred to some of the most characteristic landscapes of the Mediterranean middle mountains. In spite of the problems associated with the use of small experimental plots, the results obtained are consistent with other studies in the Mediterranean region, and confirm the strong influence of land use changes on runoff generation and sediment yield. The results indicate that: (i) cereal cultivation on steep slopes (both alternating cereal cultivation and fallow on sloping fields and shifting agriculture on the steepest slopes) represents a major problem for soil conservation. This explains the occurrence throughout the Mediterranean mountains of many degraded hillslopes, which show evidence of sheet wash erosion, rilling, gullying and shallow landsliding; (ii) farmland abandonment has led to a marked reduction in runoff and sediment yield as a consequence of rapid plant recolonization, particularly by dense shrubs; (iii) the natural transformation of abandoned fields into grazing meadows has reduced runoff and sediment yield. Land use trends in the Mediterranean mountains are mainly characterized by generalized farmland abandonment and a decrease in livestock pressure. From a hydrological and geomorphological point of view the main consequences have been a reduction in overland flow from the hillslopes, and a reduction in sediment sources, with differences up to one order of magnitude in sediment yield from dense shrub cover and grazing meadow areas compared with areas under shifting agriculture. Copyright © 2012 John Wiley & Sons, Ltd.     

Reconstruction of a flash flood with large wood transport and its influence on hazard patterns in an ungauged mountain basin

The reconstruction of past flash floods in ungauged basins leads to a high level of uncertainty, which increases if other processes are involved such as the transport of large wood material. An important flash flood occurred in 1997 in Venero Claro (Central Spain), causing significant economic losses. The wood material clogged bridge sections, raising the water level upstream. The aim of this study was to reconstruct this event, analysing the influence of woody debris transport on the flood hazard pattern. Because the reach in question was affected by backwater effects due to bridge clogging, using only high water mark or palaeostage indicators may overestimate discharges, and so other methods are required to estimate peak flows. Therefore, the peak discharge was estimated (123 ± 18 m³ s^–1) using indirect methods, but one‐dimensional hydraulic simulation was also used to validate these indirect estimates through an iterative process (127 ± 33 m³ s^–1) and reconstruct the bridge obstruction to obtain the blockage ratio during the 1997 event (~48%) and the bridge clogging curves. Rainfall–Runoff modelling with stochastic simulation of different rainfall field configurations also helped to confirm that a peak discharge greater than 150 m³ s^–1 is very unlikely to occur and that the estimated discharge range is consistent with the estimated rainfall amount (233 ± 27 mm). It was observed that the backwater effect due to the obstruction (water level ~7 m) made the 1997 flood (~35‐year return period) equivalent to the 50‐year flood. This allowed the equivalent return period to be defined as the recurrence interval of an event of specified magnitude, which, where large woody debris is present, is equivalent in water depth and extent of flooded area to a more extreme event of greater magnitude. These results highlight the need to include obstruction phenomena in flood hazard analysis. Copyright © 2012 John Wiley & Sons, Ltd.     

Accuracy assessment of the Mexican National Forest Inventory map: A study in four ecogeographical areas

The accuracy of the Mexican National Forest Inventory (NFI) map is derived in four distinct ecogeographical areas, using an assessment design tailored for the project. A main achievement of the design was to integrate the high diversity of classes encompassed at the most detailed subcommunity level of the classification scheme within a cost‐controlled statistically sound assessment. A hybrid double sampling strategy was applied to the 2.5 million‐ha study area. A total of 5955 reference sites were verified against their NFI map label. The availability of detailed quasi‐synchronous reference data for the 2000 Landsat‐derived NFI and the high diversity of mapped classes allowed a careful thematic analysis on the selected regions, relevant for national extrapolation. Global accuracy estimates of 64–78 per cent were registered among the four ecogeographical areas (two with mainly temperate climate and the other two with mainly tropical climate), with the lower accuracy levels found in areas more densely covered with forests. According to the estimates, the NFI map tends to underestimate the presence of temperate forest (especially oak) and overestimate the presence of tropical forest in the areas investigated. The analysis of confusions reveals difficulties in unambiguously interpreting or labelling forests with secondary vegetation, herbaceous and/or shrub‐like vegetation as well as distinguishing between aquatic vegetation types. The design proved useful from the perspective of accuracy assessments of regional maps in biodiverse regions.     

Bioremediation perspective of historically contaminated sediment with polycyclic aromatic hydrocarbons

The purpose of the current study is to compare the influence of different aerobic conditions(biostimulation(BS),bioaugmentation(BA),and a combination of biostimulation and bioaugmentation(BB))on polycyclic aromatic hydrocarbons(PAH)degradation and compare the degraded amount with single step XAD-4 extraction as a new tool for bioavailability assessment for chronically contaminated sediment samples obtained from territory of Autonomous Province Vojvodina of Serbia(S1,S2,and S3).A great number of papers dealing with biodegradation of PAHs in spiked sediment or soil have been published,but to the authors’knowledge,a limited number of papers studied aged,historically polluted sediment and a sum of chosen U.S.Environmental Protection Agency(USEPA)PAHs.A significant reduction(up to67%)in PAH concentration was observed,while the percentage of reduction varied depending on the sediment sample and treatment used.BS treatment successfully stimulated growth of indigenous bacteria.Further,PAH-degrading strain Sphingomonas paucimobilis F8 inoculated in BA and BB treatment survived for up to 7 weeks after it was suppressed by unfavorable conditions or native microbes.Degraded amounts generally showed good correlation with results obtained from XAD-4 extraction.Results obtained in the current study represent a good start for standardizing a XAD-4 extraction technique as a simplified,easier,and lower cost method for bioavailability assessment.     

Groundwater behaviour in Madeira, volcanic island (Portugal)

Madeira Island is a hot-spot originating from a mantle plume. K-Ar age determinations indicate that the emerged part of the island was generated during Post-Miocene times 6000–7000 years B.P. Groundwater occurs in perched-water bodies, spring discharge from them is high, about 3,650 l/s; in dike-impounded water and basal groundwater. Basal groundwater is exploited by tunnels (1,100 l/s) and wells (1,100 l/s). Hydraulic gradients range from 10^–4 to 10^–2 and transmissivity ranges from 1.16×10^–2 to 2.89×10^–1 m²/s, indicating the heterogeneity of the volcanic aquifers. Water mineralisation is variable, and electrical conductivity ranges from 50 to 3,300 S/cm. There is a difference between groundwater discharging from perched-water bodies (43–201 S/cm) and from basal groundwater (109–3,300 S/cm). Groundwater average pH is 7.37, with waters acid to slightly alkaline (6.13–8.4), and generally cold. Nevertheless, a few samples associated with fault zones can be classified as thermal waters.

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Resumen La Isla de Madeira tuvo origen en un punto caliente proveniente de una pluma del manto. Las dataciones K – Ar, indican que la parte emergida de la isla se formó durante en Post—Mioceno, hace unos 6000–7000 años. El agua subterránea se encuentra en acuíferos colgados, cuya descarga a través de manantiales es alta, alrededor de 3650 l/s; también como agua retenida en diques o bien como agua subterránea propiamente dicha. Esta última es explotada por túneles (1100 l/s) y pozos (1100 l/s). Los gradientes hidráulicos varían desde 10–4 hasta 10–2 y la transmisividad varía desde 1.16×10^–2 hasta 2.89×10^–1 m²/s, indicando la heterogeneidad de los acuíferos volcánicos. La mineralización de agua es variable y la conductividad eléctrica varía desde 50 mS/cm hasta 3300 mS/cm. Hay una diferencia entre el agua subterránea proveniente de acuíferos colgados (43–201 mS/cm) y aquella del acuífero principal (109–3300 mS/cm). El pH promedio para el agua subterránea es 7.37; con variación desde ácida hasta ligeramente alcalina (6.13–8.4), y es generalmente fría. Sin embargo unos pocos ejemplos asociados con zonas de falla, pueden ser clasificados como agua termal.

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Résumé Lîle de Madeira est un point chaud, provenant dun panache mantélique. Les datations par la méthode de K-Ar indiquent que la part émergée de lîle a été générée pendant le Post Miocène, il y a 6000–7000 ans. Les eaux souterraines sont cantonnées dans des aquifères perchées qui se déchargent par des sources à grands débits, avec des valeurs dapproximativement de 3500 l/s, ainsi que dans les dikes. Une importante quantité des eaux souterraine se trouve sur la forme deau de fonds, formant une nappe basale, qui est exploitée par des tunnels (1100 l/s) et par des puits (1100 l/s). Les gradients hydrauliques ont des valeurs dans lintervalle de 10^–2 à 10^–4, tandis que les transmissivités se rangent entre 1.16×10^–2 m²/s et 2.81×10^–1 m²/s, ce quindique la hétérogénéité de laquifère volcanique. La minéralisation des eaux est aussi variable avec des conductivités électriques qui se rangent ente 50 mS/cm et 3300 mS/cm. Il y a une différence entre la conductivité des eaux provenant des aquifères perchées (30–201 mS/cm) par rapport à la conductivité les eaux de la nappe basale (109–3300 mS/cm). Le pH moyen est de 7.37 avec des valeurs de 6.13 pour les eaux acides et de 8.4 pour les eaux à faible alcalinité. En général il sagit des eaux froides, mais quelques échantillons provenant des zones faillées peuvent être classifiés comme des eaux thermales.