Controls on Methane Occurrences in Shallow Aquifers Overlying the Haynesville Shale Gas Field,East Texas

Understanding the source of dissolved methane in drinking‐water aquifers is critical for assessing potential contributions from hydraulic fracturing in shale plays. Shallow groundwater in the Texas portion of the Haynesville Shale area (13,000 km²) was sampled (70 samples) for methane and other dissolved light alkanes. Most samples were derived from the fresh water bearing Wilcox formations and show little methane except in a localized cluster of 12 water wells (17% of total) in a approximately 30 × 30 km² area in Southern Panola County with dissolved methane concentrations less than 10 mg/L. This zone of elevated methane is spatially associated with the termination of an active fault system affecting the entire sedimentary section, including the Haynesville Shale at a depth more than 3.5 km, and with shallow lignite seams of Lower Wilcox age at a depth of 100 to 230 m. The lignite spatial extension overlaps with the cluster. Gas wetness and methane isotope compositions suggest a mixed microbial and thermogenic origin with contribution from lignite beds and from deep thermogenic reservoirs that produce condensate in most of the cluster area. The pathway for methane from the lignite and deeper reservoirs is then provided by the fault system.     

Microsomal estrogen metabolism in channel catfish

Our goal was to study the involvement of cytochrome P450 genes in estrogen metabolism and the extent to which the potentially carcinogenic 4-hydroxyestradiol metabolite is formed by channel catfish (Ictalurus punctatus; CC). Estradiol metabolism and ethoxyresorufin-O-deethylase (EROD) activity were assessed in several tissues from fish collected from three variably contaminated sites in the Mississippi River Delta, from laboratory control fish, and from fish exposed to 20 mg/kg benzo(a)pyrene (BaP) i.p. for 4 days. Liver EROD activity was induced by BaP, but Delta fish EROD activities were not statistically higher than activities in control fish. Gill microsomal EROD activity was also induced by BaP, but activities were 8- to 77-fold lower than those from liver. The predominant estrogen metabolites formed by CC liver, gill and gonad microsomes were 2-hydroxyestradiol and estrone as detected by GC/MS. Liver and gill 2-hydroxyestradiol formation was induced in BaP-dosed fish. The trends in hydroxyestradiol formation in field collected fish were more variable. In all fish liver microsomes there was more 2- compared to 4-hydroxyestradiol formed. However, BaP-treatment increased the 4:2 hydroxyestradiol ratio from 0.04 in control fish to 0.2 in BaP-exposed fish, suggesting that BaP induces the formation of the potentially genotoxic estrogen metabolite. No detectable 4-hydroxyestradiol was produced by gill and gonad microsomes. These results will ultimately help in determining which fish P450 genes are susceptible to environmental contamination and may be involved in estrogen genotoxicity.     

Regional groundwater flow modeling of the Geba basin,northern Ethiopia

Hydrogeology Journal - The Geba basin is one of the most food-insecure areas of the Tigray regional state in northern Ethiopia due to recurrent drought resulting from erratic distribution of...     

Hydrogen and oxygen in brine shrimp chitin reflect environmental water and dietary isotopic composition

Hydrogen and oxygen isotope ratios of the common structural biopolymer chitin are a potential recorder of ecological and environmental information, but our understanding of the mechanisms of incorporation of H and O from environmental substrates into chitin is limited. We report the results of a set of experiments in which the isotopic compositions of environmental water and diet were varied independently in order to assess the contribution of these variables to the H and O isotopic composition of Artemia franciscana chitin. Hydrogen isotope ratios of chitin were strongly linearly correlated with both food and water, with approximately 26% of the hydrogen signal reflecting food and approximately 38% reflecting water. Oxygen isotopes were also strongly correlated with the isotopic composition of water and food, but whereas 69% of oxygen in chitin exchanged with environmental water, only 10% was derived from food. We propose that these observations reflect the position-specific, partial exchange of H and O atoms with brine shrimp body water during the processes of digestion and chitin biosynthesis. Comparison of culture experiments with a set of natural samples collected from the Great Salt Lake, UT in 2006 shows that, with some exceptions, oxygen isotope compositions of chitin track those of water, whereas hydrogen isotopes vary inversely with those of lake water. The different behavior of the two isotopic systems can be explained in terms of a dietary shift from allochthonous particulate matter with relatively higher δ²H values in the early spring to autochthonous particulate matter with significantly lower δ²H values in the late summer to autumn. These results suggest oxygen in chitin may be a valuable proxy for the oxygen isotopic composition of environmental water, whereas hydrogen isotope values from the same molecule may reveal ecological and biogeochemical changes within lakes.     

Finding the repeat times of the GPS constellation

Single-epoch estimates of position using GPS are improved by removing multipath signals, which repeat when the GPS constellation does. We present two programs for finding this repeat time, one using the orbital period and the other the topocentric positions of the satellites. Both methods show that the repeat time is variable across the constellation, at the few-second level for most satellites, but with a few showing much different values. The repeat time for topocentric positions, which we term the aspect repeat time, averages 247 s less than a day, with fluctuations through the day that may be as much as 2.5 s at high latitudes.     

Comparison of lipid character of sediments from the Great Lakes and the Northwestern Atlantic

Geolipid compositions of surficial sediments from Lake Michigan, Lake Huron, and from three locations in the Northwestern Atlantic were determined to compare source inputs and alteration processes in different sedimentary environments. Fatty acids, sterols, fatty alcohols, and alkanes were examined in both unbound and bound extracts of these samples. Significant amounts of long chain fatty acids, alcohols, and hydrocarbons are present in the deep ocean station, yet this location contains a proportionally larger amount of short chain geolipids than do marine stations closer to shore. Larger proportions of long chain lipids present in the Lake Michigan, Lake Huron, and Gulf of Maine samples relative to the open ocean samples reflect larger inputs of land-derived lipids to sediments closer to terrigenous sources. Marine samples contain a more complex mixture of sterols than is found in lake sediments, suggesting that sterol inputs and alteration processes in the marine environment are more complex than in lacustrine settings. Ratios of 16:1/16:0 and 18:1/18:0 fatty acids decrease with increasing distance from land, which suggests that fatty acid degradation before and during deposition becomes more extensive in the open deeper ocean stations.     

A 40 ka record of temperature and permafrost conditions in northwestern Europe from noble gases in the Ledo‐Paniselian Aquifer (Belgium)

The Ledo‐Paniselian Aquifer in Belgium offers unique opportunities to study periglacial groundwater recharge during the Last Glacial Maximum (LGM), as it was located close to the southern boundary of the ice sheets at that time. Groundwater residence times determined by ¹⁴C and ⁴He reveal a sequence of Holocene and Pleistocene groundwaters and a gap between about 14 and 21 ka, indicating permafrost conditions which inhibited groundwater recharge. In this paper, a dataset of noble gas measurements is used to study the climatic evolution of the region. The derived recharge temperatures indicate that soil temperatures in the periods just before and after the recharge gap were only slightly above freezing, supporting the hypothesis that permafrost caused the recharge gap. The inferred glacial cooling of 9.5°C is the largest found so far by the noble gas method. Yet, compared to other palaeoclimate reconstructions for the region, recharge temperatures deduced from noble gases for the cold periods tend to be rather high. Most likely, this is due to soil temperatures being several degrees higher than air temperatures during periods with extended snow cover. Thus the noble‐gas‐derived glacial cooling of 9.5°C is only a lower limit of the maximum cooling during the LGM. Some samples younger than the recharge gap are affected by degassing, possibly related to gas production during recharge in part of the recharge area, especially during times of melting permafrost. The findings of this study, such as the occurrence of a recharge gap and degassing related to permafrost and its melting, are significant for groundwater dynamics and geochemistry in periglacial areas. Copyright © 2010 John Wiley & Sons, Ltd.