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51.
The density ρ of Caspian Sea waters was measured as a function of temperature (273.15–343.15) K at conductivity salinities of 7.8 and 11.3 using the Anton-Paar Densitometer. Measurements were also made on one of the samples (S = 11.38) diluted with water as a function of temperature (T = 273.15–338.15 K) and salinity (2.5–11.3). These latter results have been used to develop an equation of state for the Caspian Sea (σ = ±0.007 kg m−3)
where ρ0 is the density of water and the parameters A, B and C are given by
Measurements of the density of artificial Caspian Sea water at 298.15 K agree to ± 0.012 kg m−3 with the real samples. These results indicate that the composition of Caspian Sea waters must be close to earlier measurements of the major components. Model calculations based on this composition yield densities that agree with the measured values to ± 0.012 kg m−3. The new density measurements are higher than earlier measurements. This may be related to a higher concentration of dissolved organic carbon found in the present samples (500 μM) which is much higher than the values in ocean waters (~65 μM).  相似文献   
52.
We present a record of peatland development in relation to climate changes and human activities from the Palomaa mire, a remote site in northern Finland. We used fine‐resolution and continuous sampling to analyse several proxies including pollen (for vegetation on and around the mire), testate amoebae (TA; for mire‐wetness changes), oxygen and carbon isotopes from Sphagnum cellulose (δ18O and δ13C; for humidity and temperature changes), peat‐accumulation rates and peat‐colour changes. In spite of an excellent accumulation model (30 14C dates and estimated standard deviation of sample ages <1 year in the most recent part), the potential to determine cause–effect (or lead–lag) relationships between environmental changes and biotic responses is limited by proxy‐specific incorporation processes below the actively growing Sphagnum surface. Nevertheless, what emerges is that mire development was closely related to water‐table changes rather than to summer temperature and that water‐table decreases were associated with increasing peat‐accumulation rates and more abundant mire vegetation. A rapid fen‐to‐bog transition occurred within a few years around AD 1960 when the water table decreased beyond the historical minimum, supporting the notion that mires can rapidly shift into bogs in response to allogenic factors. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
53.
A total stress model applicable to clays under undrained conditions is presented. The model involves three strength parameters: the undrained shear strengths in triaxial compression, triaxial extension, and simple shear. The amount of physical anisotropy implied by the model is a function of the relative magnitude of these three strengths assuming a Mises-type plastic potential. Elastoplastic deformation characteristics below failure are accounted for by a hardening law requiring two additional parameters that can be related to the axial strains halfway to failure in triaxial compression and extension. Finally, elasticity is accounted for by Hooke law. The result is a relatively simple model whose parameters can all be inferred directly from a combination of in situ and standard undrained laboratory tests. The model is applied to a problem involving the horizontal loading of a monopile foundation for which full scale tests have been previously conducted. The model shows good agreement with the measured data.  相似文献   
54.
Coarse-scale data assimilation (DA) with large ensemble size is proposed as a robust alternative to standard DA with localization for reservoir history matching problems. With coarse-scale DA, the unknown property function associated with each ensemble member is upscaled to a grid significantly coarser than the original reservoir simulator grid. The grid coarsening is automatic, ensemble-specific and non-uniform. The selection of regions where the grid can be coarsened without introducing too large modelling errors is performed using a second-generation wavelet transform allowing for seamless handling of non-dyadic grids and inactive grid cells. An inexpensive local-local upscaling is performed on each ensemble member. A DA algorithm that restarts from initial time is utilized, which avoids the need for downscaling. Since the DA computational cost roughly equals the number of ensemble members times the cost of a single forward simulation, coarse-scale DA allows for a significant increase in the number of ensemble members at the same computational cost as standard DA with localization. Fixing the computational cost for both approaches, the quality of coarse-scale DA is compared to that of standard DA with localization (using state-of-the-art localization techniques) on examples spanning a large degree of variability. It is found that coarse-scale DA is more robust with respect to variation in example type than each of the localization techniques considered with standard DA. Although the paper is concerned with two spatial dimensions, coarse-scale DA is easily extendible to three spatial dimensions, where it is expected that its advantage with respect to standard DA with localization will increase.  相似文献   
55.
We explore the possibility of building a continuous glacier reconstruction by analyzing the integrated sedimentary response of a large (440 km2) glacierized catchment in western Norway, as recorded in the downstream lake Nerfloen (N61°56’, E6°52’). A multi-proxy numerical analysis demonstrates that it is possible to distinguish a glacier component in the ~ 8000-yr-long record, based on distinct changes in grain size, geochemistry, and magnetic composition. Principal Component Analysis (PCA) reveals a strong common signal in the 15 investigated sedimentary parameters, with the first principal component explaining 77% of the total variability. This signal is interpreted to reflect glacier activity in the upstream catchment, an interpretation that is independently tested through a mineral magnetic provenance analysis of catchment samples. Minimum glacier input is indicated between 6700–5700 cal yr BP, probably reflecting a situation when most glaciers in the catchment had melted away, whereas the highest glacier activity is observed around 600 and 200 cal yr BP. During the local Neoglacial interval (~ 4200 cal yr BP until present), five individual periods of significantly reduced glacier extent are identified at ~ 3400, 3000–2700, 2100–2000, 1700–1500, and ~ 900 cal yr BP.  相似文献   
56.
57.
The point of departure for this article is the contemporary tendency towards localisation of politics in the context of neo-liberal globalisation. Mediated through institutional reforms, political discourses and localised struggles, this localisation of politics produce new and transformed local political spaces. The purpose of the article is to examine the capacity of popular movements to use and transform such political spaces within the South African housing sector. This analysis is done through a combination of conceptual examination of political space and actor capacity and a concrete case study of the political strategies and capacities of The South African Homeless People’s Federation. The article argues that the Federation has utilised political relations at different scales to mobilise resources such as land and subsidies for housing for its members. It has also influenced the formulation of housing policies through its discourses and practical experiences with people-driven housing processes. In consequence the Federation’s ability to function as a civil/political movement has granted them a certain capacity to participate in the complicated process of turning de jure rights to adequate shelter into de facto rights for the urban poor as citizens of a democratic South Africa.  相似文献   
58.
We present an experimental investigation on the dissolution of uniaxially stressed crystals of NaClO3 in contact with brine. The crystals are immersed in a saturated fluid, stressed vertically by a piston and monitored constantly in situ with a CCD camera. The experiments are temperature-controlled and uniaxial shortening of the sample is measured with a high-resolution capacitance analyzer. Once the crystal is stressed it develops dissolution grooves on its free surface. The grooves are oriented with their long axis perpendicular to the direction of compressive stress and the initial distance between the parallel grooves is in accordance with the Asaro-Tiller-Grinfeld instability. We observe a novel, transient evolution of this roughness: The grooves on the crystal surface migrate upwards (against gravity), grow in size and the inter-groove distance increases linearly with time. During the coarsening of the pattern this switches from a one-dimensional geometry of parallel grooves to a two-dimensional geometry with horizontal and vertical grooves. At the end of the experiment one large groove travels across the crystal and the surface becomes smooth again. Uniaxial shortening of the crystal by pressure solution creep decays exponentially with time and shows no long term creep within the range of the resolution of the capacitance analyzer (accuracy of 100nm over a period of 14 days). This indicates that, while active, the fast transient processes on the free surface increase the solution concentration and thereby significantly slow down or stop pressure solution at the top of the crystal. This novel feedback mechanism can explain earlier results of cyclic pressure solution creep and demands development of a more complex theory of pressure-solution creep including processes that act on free surfaces.  相似文献   
59.
The objective is to capture the 3D spatial variation in the failure mode occurring in accretionary wedges and their analog experiments in the laboratory from the sole knowledge of the material strength and the structure geometry. The proposed methodology relies on the maximum strength theorem which is inherited from the kinematic approach of the classical limit analysis. It selects the optimum virtual velocity field which minimizes the tectonic force. These velocity fields are constructed by interpolation thanks to the spatial discretization conducted with ten-noded tetrahedra in 3D and six-noded triangles in 2D. The resulting, discrete optimization problem is first presented emphasizing the dual formalism found most appropriate in the presence of nonlinear strength criteria, such as the Drucker–Prager criterion used in all reported examples. The numerical scheme is first applied to a perfectly triangular 2D wedge. It is known that failure occurs to the back for topographic slope smaller than and to the front for slope larger than a critical slope, defining subcritical and supercritical slope stability conditions, respectively. The failure mode is characterized by the activation of a ramp, its conjugate back thrust, and the partial or complete activation of the décollement. It is shown that the critical slope is captured precisely by the proposed numerical scheme, the ramp, and the back thrust corresponding to regions of localized virtual strain. The influence of the back-wall friction on this critical slope is explored. It is found that the failure mechanism reduces to a thrust rooting at the base of the back wall and the absence of back thrust, for small enough values of the friction angle. This influence is well explained by the Mohr construction and further validated with experimental results with sand, considered as an analog material. 3D applications of the same methodology are presented in a companion paper.  相似文献   
60.
The effect of wind waves on water level and currents during two storms in the North Sea is investigated using a high-resolution Nucleus for European Modelling of the Ocean (NEMO) model forced with fluxes and fields from a high-resolution wave model. The additional terms accounting for wave-current interaction that are considered in this study are the Stokes-Coriolis force, the sea-state-dependent energy and momentum fluxes. The individual and collective role of these processes is quantified and the results are compared with a control run without wave effects as well as against current and water-level measurements from coastal stations. We find a better agreement with observations when the circulation model is forced by sea-state-dependent fluxes, especially in extreme events. The two extreme events, the storm Christian (25–27 October 2013), and about a month later, the storm Xaver (5–7 December 2013), induce different wave and surge conditions over the North Sea. Including the wave effects in the circulation model for the storm Xaver raises the modelled surge by more than 40 cm compared with the control run in the German Bight area. For the storm Christian, a difference of 20–30 cm in the surge level between the wave-forced and the stand-alone ocean model is found over the whole southern part of the North Sea. Moreover, the modelled vertical velocity profile fits the observations very well when the wave forcing is accounted for. The contribution of wave-induced forcing has been quantified indicating that this represents an important mechanism for improving water-level and current predictions.  相似文献   
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