Assessment of urban heat island effect for different land use–land cover from micrometeorological measurements and remote sensing data for megacity Delhi

Urban heat island intensities (UHI) have been assessed based on in situ measurements and satellite-derived observations for the megacity Delhi during a selected period in March 2010. A network of micrometeorological observational stations was set up across the city. Site selection for stations was based on dominant land use–land cover (LULC) classification. Observed UHI intensities could be classified into high, medium and low categories which overall correlated well with the LULC categories viz. dense built-up, medium dense built-up and green/open areas, respectively. Dense urban areas and highly commercial areas were observed to have highest UHI with maximum hourly magnitude peaking up to 10.7 °C and average daily maximum UHI reaching 8.3 °C. UHI obtained in the study was also compared with satellite-derived land surface temperatures (LST). UHI based on in situ ambient temperatures and satellite-derived land surface temperatures show reasonable comparison during nighttime in terms of UHI magnitude and hotspots. However, the relation was found to be poor during daytime. Further, MODIS-derived LSTs showed overestimation during daytime and underestimation during nighttime when compared with in situ skin temperature measurements. Impact of LULC was also reflected in the difference between ambient temperature and skin temperature at the observation stations as built-up canopies reported largest gradient between air and skin temperature. Also, a comparison of intra-city spatial temperature variations based UHI vis-à-vis a reference rural site temperature-based UHI indicated that UHI can be computed with respect to the station measuring lowest temperature within the urban area in the absence of a reference station in the rural area close to the study area. Comparison with maximum and average UHI of other cities of the world revealed that UHI in Delhi is comparable to other major cities of the world such as London, Tokyo and Beijing and calls for mitigation action plans.     

Pre-onset land surface processes and ��internal�� interannual variabilities of the Indian summer monsoon

It is proposed that, land?Catmosphere interaction around the time of monsoon onset could modulate the first episode of climatological intraseasonal oscillation (CISO) and may generate significant ??internal?? interannual variation in the Indian summer monsoon rainfall. The regional climate model RegCM3 is used over Indian monsoon domain for 27?years of control simulation. In order to prove the hypothesis, another two sets of experiment are performed using two different boundary conditions (El Ni?o year and non-ENSO year). In each of these experiments, a single year of boundary conditions are used repeatedly year after year to generate ??internal?? interannual monsoon variability. Simulation of monsoon climate in the control model run is found to be in reasonably good agreement with observation. However, large rainfall bias is seen over Arabian Sea and Bay of Bengal. The interannual monsoon rainfall variability are of the same order in two experiments, which suggest that the external influences may not be important on the generation of ??internal?? monsoon rainfall variability. It is shown that, a dry (wet) pre-onset land-surface condition increases (decreases) rainfall in June which in turn leads to an anomalous increase (decrease) in seasonal (JJAS) rainfall. The phase and amplitude of CISO are modulated during May?CJune and beyond that the modulation of CISO is quite negligible. Though the pre-onset rainfall is unpredictable, significant modulation of the post-onset monsoon rainfall by it can be exploited to improve predictive skill within the monsoon season.     

Geology and tectonic implications of tourmaline bearing leucogranite of Bastipadu,Kurnool, Andhra Pradesh,India

Tourmaline bearing leucogranite occurs as a pluton with pegmatitic veins intruding the Archaean granodiorite in the Bastipadu area, Kurnool district of Andhra Pradesh. We present field and petrographic relations, mineral chemistry and geochemical data for the leucogranite. It is essentially a two-mica granite, composed of quartz, perthite, microcline, albite, tourmaline and muscovite along with minor biotite and titanite. The euhedral tourmalines are regularly distributed in the rock. The geochemical studies show that the leucogranite is calc-alkaline, peraluminous to metaluminous which formed in a syn-collisional to volcanic arc-related setting. It displays strong ‘S’ type signatures with high K/Na ratios, moderately fractionated light rare earth elements, relatively flat heavy rare earth elements with \(\hbox {[Ce/Yb]}_\mathrm{N} \le 27.8\) and a strong negative Eu anomaly. The geochemical characteristics indicate that the leucogranite melt might have been generated from partial melting of metasediments. Electron probe microanalyser data show the presence of alkali group tourmaline in leucogranite represented by schorl and dravite. Tourmaline compositions plot in the Li-poor granitoids and associated pegmatites and aplites and metapelites/metasammites fields. Partial melting of boron-enriched source rocks is linked with the development of tourmalines in the leucogranite.     

The Chemical Nature of Phosphorus in Subtropical Lake Sediments

The phosphorus (P) composition of sediment profiles in three subtropical lakes of contrasting trophic state in Florida, USA, was determined by sequential fractionation and solution ³¹P NMR spectroscopy. Sediment from Lake Annie, an oligo-mesotrophic sinkhole with moderately acidic sediment (pH 5.4; loss on ignition 58 %), contained higher total P concentrations than sediment from eutrophic Lake Okeechobee (pH 7.7, loss on ignition 36 %) and hyper-eutrophic Lake Apopka (pH 7.5, loss on ignition 69 %). The chemical nature of sediment P varied markedly among the three lakes, suggesting the predominance of different diagenetic processes. Lake Okeechobee sediment was dominated by inorganic P, indicating the dominance of abiotic reactions; Lake Annie sediment contained abundant organic P throughout the sediment profile, indicating the importance of organic P stabilization at acidic pH; Lake Apopka contained almost half of its sediment P in microbial biomass, indicating the importance of biotic processes in regulating P dynamics. Solution ³¹P NMR spectroscopy of NaOH–EDTA extracts revealed that organic P occurred mainly as phosphomonoesters in all lakes. However, sediment from Lake Apopka also contained abundant phosphodiesters and was the only lake to contain detectable concentrations of polyphosphate, perhaps due to a combination of alternating redox conditions and high concentrations of inorganic phosphate and organic carbon. Organic P concentrations determined by sequential fractionation and solution ³¹P NMR spectroscopy were similar for all lakes when microbial P was included in values for sequential fractionation. We conclude that the chemical nature of sediment P varies markedly depending on trophic state and can provide important information on the dominant processes controlling P cycling in subtropical lakes.     

Geology of Pulikonda and Dancherla alkaline complexes,Andhra Pradesh

Geological studies on saturated to oversaturated and subsolvus aegirine-riebeckite syenite bodies of the Pulikonda alkaline complex and Dancherla alkaline complex were carried out. The REE distribution of the Dancherla syenite shows a high fractionation between LREE and HREE. The absence of Eu anomaly suggests source from garnet peridotite. The Pulikonda syenite shows moderate fractionation between LREE and HREE as reflected by enrichment of HREE and moderate enrichment of LREE. The negative Eu anomaly indicates role of plagioclase fractionation.Three distinct co-eval primary magmas i.e. mafic syenite-, felsic syenite- and alkali basalt magmas — all derived from low-degrees of partial melting of mantle differentiates and enriched metasomatised lower crust played a major role in the genesis and emplacement of the syenites into overlying crust along deep seated regional scale trans-lithospheric strike-slip faults and shear zones following immediately after late-Archaean calc-alkaline arc magmatism at different time-space episodes i.e. initially at craton margin and later on into the thickened interior of the Eastern Dharwar craton. The ductile sheared and folded Pulikonda alkaline complex was evolved dominantly from the magmas derived from partial melting of lower crust and minor juvenile magmas from mantle. Differentiation and fractionation by liquid immiscibility of mafic magma and commingling-mixing of intermediate and felsic magmas followed by fractionational crystallisation under extensional tectonics during waning stages of calc-alkaline arc magmatism nearer to the craton margin were attributed as the main processes for the genesis of Pulikonda syenite complex. Commingling and limited mixing of independent mantle derived mafic and felsic syenitic magmas and accompanying fractionation resulting into soda rich and potash rich syenite variants was tentatively deduced mechanism for the origin of Dancherla, Danduvaripalle, Reddypalle syenites and other bodies belonging to Dancherla alkaline complex at the craton interior. The Peddavaduguru syenite was formed by differentiation of alkali mafic magma (gabbro to diorite) and it’s simultaneous mingling with fractionated felsic syenitic magma under incipient rift. Vannedoddi and Yeguvapalli syenites were derived due to desilicification and accompanying alkali feldspar mestasomatism of younger potash rich granites along Guntakal-Gooty fault and along Singanamala shear zone respectively.     

Trace-element heterogeneity in rutile linked to dislocation structures: Implications for Zr-in-rutile geothermometry

The trace-element composition of rutile is commonly used to constrain P–T–t conditions for a wide range of metamorphic systems. However, recent studies have demonstrated the redistribution of trace elements in rutile via high-diffusivity pathways and dislocation-impurity associations related to the formation and evolution of microstructures. Here, we investigate trace-element migration in low-angle boundaries formed by dislocation creep in rutile within an omphacite vein of the Lago di Cignana unit (Western Alps, Italy). Zr-in-rutile thermometry and inclusions of quartz in rutile and of coesite in omphacite constrain the conditions of rutile deformation to around the prograde boundary from high pressure to ultra-high pressure (~2.7 GPa) at temperatures of 500–565°C. Crystal-plastic deformation of a large rutile grain results in low-angle boundaries that generate a total misorientation of ~25°. Dislocations constituting one of these low-angle boundaries are enriched in common and uncommon trace elements, including Fe and Ca, providing evidence for the diffusion and trapping of trace elements along the dislocation cores. The role of dislocation microstructures as fast-diffusion pathways must be evaluated when applying high-resolution analytical procedures as compositional disturbances might lead to erroneous interpretations for Ca and Fe. In contrast, our results indicate a trapping mechanism for Zr.