Distribution of arsenic and mercury in subtropical coastal beachrock,Gulf of Mannar,India

An assessment of coastal pollution was made on the basis of trace element concentrations (arsenic — As, mercury — Hg) in the Gulf of Mannar. The beachrock samples were collected along the coastal tracts between Rameswaram and Kanyakumari. The samples were dried and digested to determine the As and Hg using atomic absorption spectrophotometer (AAS-air-acetylene and nitrous oxide method). The As and Hg accumulation status of the beachrock was assessed using geo-accumulation index values (I _geo). The accumulation of As and Hg in the beachrock ranges from 2.75 to 20.72 μg g⁻¹ and from 0.06 to 0.31 μg g⁻¹, respectively. The As and Hg concentrations in the beachrocks are compared with crustal average values and average of other region sediments. The possible source of the contamination is from atmospheric deposition and anthropogenic activities.     

Geophysical and tracer studies to detect subsurface chromium contamination and suitable site for waste disposal in Ranipet,Vellore district,Tamil Nadu,India

A chemical factory near Ranipet town in Vellore district, in the state of Tamil Nadu, India produced chromium-based inorganic chemicals. The factory area in granite gnessic terrain receives an average annual rainfall of 1,000 mm. About 1.5 lakh tons of solid wastes rich in hexavalent chromium (Cr⁶⁺), spreading over an area of 14,000 m² (about 3.5 acres), having about 4 m thickness, is accumulated in an open yard within the factory premises. The soil and groundwater in and around the factory area are contaminated with Cr⁶⁺ leached from dump site. Cr⁶⁺ is carcinogenic in nature and when leached in water can lead to respiratory disorders. Resistivity surveys comprising vertical electrical sounding, multielectrode resistivity imaging, drilling of bore wells, chemical analysis of soil, formation and groundwater samples and bore hole tracer studies were carried out within the factory and adjoining areas to decipher subsurface geology, hydraulic behavior of dyke as natural barrier and lateral and vertical extent of pollution zone in and around the chromium dump site. The data obtained were integrated and interpreted for understanding the pollution migration and its impact on environment. Remedial measures are suggested for containing the contamination.     

Projected climate change impacts on spatial distribution of bioclimatic zones and ecoregions within the Kailash Sacred Landscape of China,India, Nepal

Rapidly accelerating climate change in the Himalaya is projected to have major implications for montane species, ecosystems, and mountain farming and pastoral systems. A geospatial modeling approach based on a global environmental stratification is used to explore potential impacts of projected climate change on the spatial distribution of bioclimatic strata and ecoregions within the transboundary Kailash Sacred Landscape (KSL) of China, India and Nepal. Twenty-eight strata, comprising seven bioclimatic zones, were aggregated to develop an ecoregional classification of 12 ecoregions (generally defined by their potential dominant vegetation type), based upon vegetation and landcover characteristics. Projected climate change impacts were modeled by reconstructing the stratification based upon an ensemble of 19 Earth System Models (CIMP5) across four Representative Concentration Pathways (RCP) emission scenarios (i.e. 63 impact simulations), and identifying the change in spatial distribution of bioclimatic zones and ecoregions. Large and substantial shifts in bioclimatic conditions can be expected throughout the KSL area by the year 2050, within all bioclimatic zones and ecoregions. Over 76 % of the total area may shift to a different stratum, 55 % to a different bioclimatic zone, and 36.6 % to a different ecoregion. Potential impacts include upward shift in mean elevation of bioclimatic zones (357 m) and ecoregions (371 m), decreases in area of the highest elevation zones and ecoregions, large expansion of the lower tropical and sub-tropical zones and ecoregions, and the disappearance of several strata representing unique bioclimatic conditions within the KSL, with potentially high levels of biotic perturbance by 2050, and a high likelihood of major consequences for biodiversity, ecosystems, ecosystem services, conservation efforts and sustainable development policies in the region.     

A site-specific study on the measurement of sorption coefficients for radionuclides

A study on the potential of geological media from the vicinity of the mining site in Tummalapalle region of Andhra Pradesh in India for retardation of radionuclide migration in groundwater was conducted. The studies included the measurement of sorption coefficients for six radionuclides, uranium, thorium, lead, bismuth, radium and polonium, between two groundwater simulants and two site-specific samples of geological media. Initial parametric studies involving chemical composition, pH, calcium carbonate and organic carbon contents of both geological media and ground water simulants were carried out. Significant differences in sorption coefficients were observed as a result of varying pH, calcium carbonate and presence of trace quantities of organic contents in simulant solutions. For example, uranium has a hundred fold lower distribution coefficient in the case of simulant solution having higher carbonate content. Similarly, in the case of the geological media having higher calcium carbonate and organic carbon contents, higher distribution coefficients were obtained for all radionuclides. Among the six radionuclides studied thorium showed the largest and radium the smallest distribution coefficient values for the soil samples assessed. The site-specific sorption coefficients will be used for contaminant transport study.     

Appraisal of land use/land cover of mangrove forest ecosystem using support vector machine

Human activities in many parts of the world have greatly changed the natural land cover. This study has been conducted on Pichavaram forest, south east coast of India, famous for its unique mangrove bio-diversity. The main objectives of this study were focused on monitoring land cover changes particularly for the mangrove forest in the Pichavaram area using multi-temporal Landsat images captured in the 1991, 2000, and 2009. The land use/land cover (LULC) estimation was done by a unique hybrid classification approach consisting of unsupervised and support vector machine (SVM)-based supervised classification. Once the vegetation and non-vegetation classes were separated, training site-based classification technology i.e., SVM-based supervised classification technique was used. The agricultural area, forest/plantation, degraded mangrove and mangrove forest layers were separated from the vegetation layer. Mud flat, sand/beach, swamp, sea water/sea, aquaculture pond, and fallow land were separated from non-vegetation layer. Water logged areas were delineated from the area initially considered under swamp and sea water-drowned areas. In this study, the object-based post-classification comparison method was employed for detecting changes. In order to evaluate the performance, an accuracy assessment was carried out using the randomly stratified sampling method, assuring distribution in a rational pattern so that a specific number of observations were assigned to each category on the classified image. The Kappa accuracy of SVM classified image was highest (94.53 %) for the 2000 image and about 94.14 and 89.45 % for the 2009 and 1991 images, respectively. The results indicated that the increased anthropogenic activities in Pichavaram have caused an irreversible loss of forest vegetation. These findings can be used both as a strategic planning tool to address the broad-scale mangrove ecosystem conservation projects and also as a tactical guide to help managers in designing effective restoration measures.     

Hydrogeological processes controlling the release of arsenic in parts of 24 Parganas district,West Bengal

A study was conducted to understand the hydrogeological processes dominating in the North 24 Parganas and South 24 Parganas based on representative 39 groundwater samples collected from selected area. The abundance of major ions was in the order of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺ > Fe²⁺ for cations and HCO₃ ^? > PO₄ ^3? > Cl^? > SO₄ ^2? > NO₃ ^? for anions. Piper trilinear diagram was plotted to understand the hydrochemical facies. Most of the samples are of Ca-HCO₃ type. Based on conventional graphical plots for (Ca + Mg) vs. (SO₄ + HCO₃) and (Na + K) vs. Cl, it is interpreted that silicate weathering and ion exchange are the dominant processes within the study area. Previous studies have reported quartz, feldspar, illite, and chlorite clay minerals as the major mineral components obtained by the XRD analysis of sediments. Mineralogical investigations by SEM and EDX of aquifer materials have shown the occurrence of arsenic as coating on mineral grains in the silty clay as well as in the sandy layers. Excessive withdrawal of groundwater for irrigation and drinking purposes is responsible for fluctuation of the water table in the West Bengal. Aeration beneath the ground surface caused by fluctuation of the water table may lead to the formation of carbonic acid. Carbonic acid is responsible for the weathering of silicate minerals, and due to the formation of clay as a product of weathering, ion exchange also dominates in the area. These hydrogeological processes may be responsible for the release of arsenic into the groundwater of the study area, which is a part of North 24 Parganas and South 24 Parganas.     

Impact of Doppler weather radar data on thunderstorm simulation during STORM pilot phase—2009

This study assesses the impact of Doppler weather radar (DWR) data (reflectivity and radial wind) assimilation on the simulation of severe thunderstorms (STS) events over the Indian monsoon region. Two different events that occurred during the Severe Thunderstorms Observations and Regional Modeling (STORM) pilot phase in 2009 were simulated. Numerical experiments—3DV (assimilation of DWR observations) and CNTL (without data assimilation)—were conducted using the three-dimensional variational data assimilation technique with the Advanced Research Weather Research and Forecasting model (WRF-ARW). The results show that consistent with prior studies the 3DV experiment, initialized by assimilation of DWR observations, performed better than the CNTL experiment over the Indian region. The enhanced performance was a result of improved representation and simulation of wind and moisture fields in the boundary layer at the initial time in the model. Assimilating DWR data caused higher moisture incursion and increased instability, which led to stronger convective activity in the simulations. Overall, the dynamic and thermodynamic features of the two thunderstorms were consistently better simulated after ingesting DWR data, as compared to the CNTL simulation. In the 3DV experiment, higher instability was observed in the analyses of thermodynamic indices and equivalent potential temperature (θ _e) fields. Maximum convergence during the mature stage was also noted, consistent with maximum vertical velocities in the assimilation experiment (3DV). In addition, simulated hydrometeor (water vapor mixing ratio, cloud water mixing ratio, and rain water mixing ratio) structures improved with the 3DV experiment, compared to that of CNTL. From the higher equitable threat scores, it is evident that the assimilation of DWR data enhanced the skill in rainfall prediction associated with the STS over the Indian monsoon region. These results add to the body of evidence now which provide consistent and notable improvements in the mesoscale model results over the Indian monsoon region after assimilating DWR fields.     

Exact bianchi type-II,VIII, and IX cosmological models with matter and electromagnetic fields in Lyra's manifold

Spatially-homogeneous and anisotropic Bianchi type-II, VIII, and IX stiff-fluid cosmological models in the presence of source-free electromagnetic fields are obtained in Lyra's manifold. Some properties of the models are also discussed.     

Bianchi type-II,VIII, and IX cosmologies with conformally-invariant scalar field and electromagnetic fields

In the expansive nondecelerative universe creation of matter happens as a result of a fundamental relationship and mutual compatibility of the field and matter.     

Hall effects on oscillatory MHD boundary-layer flow under variable suction

The effects of Hall current on the oscillatory hydromagnetic boundary-layer flow under variable suction, past an infinite porous flat plate in the presence of a transverse magnetic field is discussed. The expressions for velocity and skin-friction are obtained and their variations for small and large frequency of oscillations are extensively discussed.