‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.     

Understanding the hydrological system dynamics of a glaciated alpine catchment in the Himalayan region using the J2000 hydrological model

This paper provides the results of hydrological modelling in a mesoscale glaciated alpine catchment of the Himalayan region. In the context of global climate change, the hydrological regime of an alpine mountain is likely to be affected, which might produce serious implications for downstream water availability. The main objective of this study was to understand the hydrological system dynamics of a glaciated catchment, the Dudh Kosi River basin, in Nepal, using the J2000 hydrological model and thereby understand how the rise in air temperature will affect the hydrological processes. The model is able to reproduce the overall hydrological dynamics quite well with an efficiency result of Nash–Sutcliffe (0.85), logarithm Nash–Sutcliffe (0.93) and coefficient of determination (0.85) for the study period. The average contribution from glacier areas to total streamflow is estimated to be 17%, and snowmelt (other than from glacier areas) accounts for another 17%. This indicates the significance of the snow and glacier runoff in the Himalayan region. The hypothetical rise in temperature scenarios at a rate of +2 and +4 °C indicated that the snowmelt process might be largely affected. An increase in snowmelt volume is noted during the premonsoon period, whereas the contribution during the monsoon season is significantly decreased. This occurs mainly because the rise in temperature will shift the snowline up to areas of higher altitude and thereby reduce the snow storage capacity of the basin. This indicates that the region is particularly vulnerable to global climate change and the associated risk of decreasing water availability to downstream areas. Under the assumed warming scenarios, it is likely that in the future, the river might shift from a ‘melt‐dominated river’ to a ‘rain‐dominated river’. The J2000 model should be considered a promising tool to better understand the hydrological dynamics in alpine mountain catchments of the Himalayan region. This understanding will be quite useful for further analysis of ‘what‐if scenarios’ in the context of global climate and land‐use changes and ultimately for sustainable Integrated Water Resources Management in the Himalayan region. Copyright © 2012 John Wiley & Sons, Ltd.     

Mesocosm experiments identifying hotspots of groundwater upwelling in a water column by fibre optic distributed temperature sensing

Lacustrine groundwater discharge (LGD) can substantially impact ecosystem characteristics and functions. Fibre optic distributed temperature sensing (FO‐DTS) has been successfully used to locate groundwater discharge into lakes and rivers at the sediment–water interface, but locating groundwater discharge would be easier if it could be detected from the more accessible water surface. So far, it is not clear if how and under which conditions the LGD signal propagates through the water column to the water surface–atmosphere interface, and what perturbations and signal losses occur along this pathway. In the present study, LGD was simulated in a mesocosm experiment. Under winter conditions, water with temperatures of 14 to 16 °C was discharged at the bottom of a 10 × 2.8‐m mesocosm. Water within this mesocosm ranged from 4.0 to 7.4 °C. Four layers (20, 40, 60, and 80 cm above the sediment) of the 82 cm deep mesocosm were equipped with FO‐DTS for tracing thermal patterns in the mesocosm. Aims are (a) to test whether the positive buoyancy of relatively warm groundwater imported by LGD into shallow water bodies allows detection of LGD at the lake's water surface–atmosphere interface by FO‐DTS, (b) to analyse the propagation of the temperature signal from the sediment‐water interface through the water column, and (c) to learn more about detectability of the signal under different discharge rates and weather conditions. The experiments supported the benchmarking of scale dependencies and robustness of FO‐DTS applications for measuring upwelling into aquatic environments and revealed that weather conditions can have important impacts on the detection of upwelling at water surface–atmosphere interfaces at larger scales.     

Proglacial groundwater storage dynamics under climate change and glacier retreat

Proglacial aquifers are an important water store in glacierised mountain catchments that supplement meltwater-fed river flows and support freshwater ecosystems. Climate change and glacier retreat will perturb water storage in these aquifers, yet the climate-glacier-groundwater response cascade has rarely been studied and remains poorly understood. This study implements an integrated modelling approach that combines distributed glacio-hydrological and groundwater models with climate change projections to evaluate the evolution of groundwater storage dynamics and surface-groundwater exchanges in a temperate, glacierised catchment in Iceland. Focused infiltration along the meltwater-fed Virkisá River channel is found to be an important source of groundwater recharge and is projected to provide 14%–20% of total groundwater recharge by the 2080s. The simulations highlight a mechanism by which glacier retreat could inhibit river recharge in the future due to the loss of diurnal melt cycling in the runoff hydrograph. However, the evolution of proglacial groundwater level dynamics show considerable resilience to changes in river recharge and, instead, are driven by changes in the magnitude and seasonal timing of diffuse recharge from year-round rainfall. The majority of scenarios simulate an overall reduction in groundwater levels with a maximum 30-day average groundwater level reduction of 1 m. The simulations replicate observational studies of baseflow to the river, where up to 15% of the 30-day average river flow comes from groundwater outside of the melt season. This is forecast to reduce to 3%–8% by the 2080s due to increased contributions from rainfall and meltwater runoff. During the melt season, groundwater will continue to contribute 1%–3% of river flow despite significant reductions in meltwater runoff inputs. Therefore it is concluded that, in the proglacial region, groundwater will continue to provide only limited buffering of river flows as the glacier retreats.     

Modeling core-scale permeability anisotropy in highly bioturbated “tight oil” reservoir rocks

A high-resolution simulation model of a heterogeneous low-permeability rock sample is used to investigate the effects of physical and biogenic sedimentary structures on scaling and anisotropy of absolute permeability at the core scale. Several simulation sub-samples with random locations and volumes were also selected for evaluation of the effects of scale and lithological composition on the calculated permeability. Vertical and horizontal permeability values (from whole core simulation) are in good agreement with routine core analysis (RCA) measurements from offsetting cores. Despite relatively good reservoir quality associated with geobodies of biogenic and relic bedding structures, results from the full diameter core simulation demonstrate that their limited volumetric abundance and restricted connectivity prevent these features from controlling fluid flow in these rocks. In fact, permeability seems to be dominated by the tighter encasing matrix, which exhibits average permeability values very close to those reported from RCA. Geometric averaging offers a better representation for the upscaling of horizontal permeability datasets; whereas, both geometric and harmonic averaging work similarly well for the vertical measurements. The methodology used in this work is particularly applicable to the detailed characterization of reservoir rocks with a high degree of heterogeneity caused by biological reworking and diagenesis.     

Chemical composition of spinel from Uralian-Alaskan-type Mafic–Ultramafic complexes and its petrogenetic significance

Uralian-Alaskan-type mafic–ultramafic complexes are recognized as a distinct class of intrusions regarding lithologic assemblage, mineral chemistry and petrogenetic setting. In the present study, we discuss new data on the distribution of major elements in minerals of the spinel group in rocks from Uralian-Alaskan-type complexes in the Ural Mountains, Russia. Cr-rich spinel (Cr₂O₃ = 20–53 wt%) in dunite with interstitial clinopyroxene and in wehrlite cumulates indicate that it reacted with interstitial liquid resulting in the progressive substitution of Al₂O₂ and Cr₂O₃ by Fe₂O₃ and TiO₂. A distinct change in the spinel chemistry in dunite (Cr₂O₃ = 47–53 wt%), towards Al₂O₃- and Cr₂O₃-poor but Fe₂O₃-rich compositions monitors the onset of clinopyroxene fractionation in wehrlite (Cr₂O₃ = 15–35 wt%, Al₂O₃ = 1–8 wt%, Fe₂O₃ = 25–55 wt%). In more fractionated mafic rocks, the calculated initial composition of exsolved spinel traces the sustained crystallization of clinopyroxene by decreasing Cr₂O₃ and increasing FeO, Fe₂O₃ and fO₂. Finally, the initiation of feldspar crystallization buffers the Al₂O₃ content in most of the spinels in mafic rocks at very low Cr₂O₃ contents (<5 wt%). The fractionation path all along and the reaction with interstitial liquid are accompanied by increasing Fe₂O₃ contents in the spinel. This likely is caused by a significant increase in the oxygen fugacity, which suggests closed system fractionation processes. Spinel with Cr₂O₃ < 27 wt% is exsolved into a Fe₂O₃-rich and an Al₂O₃-rich phase forming a variety of textures. Remarkably, exsolved spinel in different lithologies from complexes 200 km apart follows one distinct solvus line defining a temperature of ca. 600°C. This indicates that the parental magmas were emplaced and eventually cooled at similar levels in the lithosphere, likely near the crust–mantle boundary. Eventually, these 600°C hot bodies were rapidly transported into colder regions of the upper crust during a regional tectonic event, probably during the major active phase of the Main Uralian Fault.     

Zur Dynamotheorie stellarer und planetarer Magnetfelder I. Berechnung sonnenähnlicher Wechselfeldgeneratoren

Non-reflectionsymmetric turbulent motions in an electrically conducting fluid provide for an average electromotoric force α parallel to the average magnetic field . This effect – furthermore called α-effect – can lead to a self-excited built-up of magnetic fields by dynamo action. Since by actions of Coriolis forces turbulent motions in rotating systems generally are non-reflectionsymmetric, the explanation of stellar and planetary magnetic fields becomes possible. – In this first part spherical alternating field dynamos are calculated on conditions similar to those at the sun; α-effect and differential rotation provide for dynamo action. – The basic equations, which form a system of partial differential equations, are treated by a separation method; in this way our problem is transformed into a two-parametric eigenvalue problem for an infinite system of ordinary differential equations. The two eigenvalues determine the frequency and the amount of the induction actions necessary for the field maintenance. The solution of this problem was made by an electronic computer. – The results give evidence for the possibility of magnetohydrodynamic alternating field dynamos. Furthermore the magnitude of the calculated eigenvalues and the similarities between the calculated field and the observed solar magnetic field are showing that the sun realizes a dynamo of this kind.     

On different time scales of suspended matter dynamics in the Weser estuary

Long-term observations in the Weser estuary (Germany) between 1983 and 1997 provide insight into the response of the estuarine turbidity maximum (ETM) under a wide range of conditions. In this estuary the turbidity zone is closely tied to the mixing zone, and the positions of the ETM and the mixing zone vary with runoff. The intratidal suspended particulate matter (SPM) concentrations vary due to deposition during slack water periods, subsequent resubsequent and depletion of temporarily-formed and spatially-limited deposits during the following ebb or flood, and subsequent transport by tidal currents. The corresponding time history of SPM concentrations is remarkably constant over the years. Spring tide SPM concentrations can be twice the neap tide concentrations or even larger. A hysteresis in SPM levels between the falling and rising spring-neap cycle is attributed to enhanced resuspension by the stronger spring tidal currents. There is evidence that the ETM is pushed up-estuary during times of higher mean water levels due to storms. During river floods the ETM is flushed towards the outer estuary. If river floods and their decreasing parts occur during times of relatively high mean water levels, the ETM seems to be maintained in the outer estuary. If river floods and their decreasing parts occur during times of relatively low mean water levels, the ETM seems to loose inventory and may need up to half a year of non-event conditions to gain its former magnitude. During this time seasonal effects may be involved. Analyses of storm events and river floods have revealed that the conditions in the seaward boundary region play an equally important role for the SPM dynamics as those arising from the river.     

Climate change and human activities: a case study in Xinjiang, China

We examined both long-term climate variability and anthropogenic contributions to current climate change for Xinjiang province of northwest China. Xinjiang encompasses several mountain ranges and inter-mountain basins and is comprised of a northern semiarid region and a more arid southern region. Climate over the last three centuries was reconstructed from tree rings and temperature series were calculated for the past 50 years using weather station data. Three major conclusions from these analyses are: (1) Although temperature varied considerably in Xinjiang over the last 200 years, it was non-directional until the last 50 years when a substantial warming trend occurred; (2) The semiarid North Xinjiang was representative of the northern hemisphere climate, while the more arid South Xinjiang resembled the southern hemisphere climate, meanwhile, (3) The entire Xinjiang province captured the global-scale climate signal. We also compared human contributions to global change between North and South Xinjiang, including land cover/land use, population, and greenhouse gas production. For both regions, urban areas acted as heat islands; and large areas of grassland and forest were converted to barren land, especially in North Xinjiang. Additionally, North Xinjiang also showed larger increase in population and greenhouse gas emissions mainly associated with animal production than those in South Xinjiang. Although Xinjiang province is a geographically coupled mountain–basin system, the two regions have distinct climate patterns and anthropogenic activities related to land cover conversion and greenhouse gas production.