Variability in the annual cycle of vertical particulate organic carbon export on Arctic shelves: Contrasting the Laptev Sea,Northern Baffin Bay and the Beaufort Sea

The ongoing regression of sea ice cover is expected to significantly affect the fate of organic carbon over the Arctic continental shelves. Long-term moored sediment traps were deployed in 2005–2006 in the Beaufort Sea, Northern Baffin Bay and the Laptev Sea to compare the annual variability of POC fluxes and to evaluate the factors regulating the annual cycle of carbon export over these continental shelves. Annual POC fluxes at 200 m ranged from 1.6 to 5.9 g C m⁻² yr⁻¹ with the highest export in Northern Baffin Bay and the lowest export over the Mackenzie Shelf in the Beaufort Sea. Each annual cycle exhibited an increase in POC export a few weeks before, during, or immediately following sea ice melt, but showed different patterns over the remainder of the cycle. Enhanced primary production, discharge of the Lena River, and resuspension events contributed to periods of elevated POC export over the Laptev Sea slope. High POC fluxes in Northern Baffin Bay reflected periods of elevated primary production in the North Water polynya. In the Beaufort Sea sediment resuspension contributed to most of the large export events. Our results suggest that the outer shelf of the Laptev Sea will likely sustain the largest increase in POC export in the next few years due to the large reduction in ice cover and the possible increase in the Lena River discharge. The large differences in forcing among the regions investigated reinforce the importance of monitoring POC fluxes in the different oceanographic regimes that characterize the Arctic shelves to assess the response of the Arctic Ocean carbon cycle to interannual variability and climate change.     

The GREGOR Fabry‐Pérot Interferometer

The GREGOR Fabry‐Pérot Interferometer (GFPI) is one of three first‐light instruments of the German 1.5‐meter GREGOR solar telescope at the Observatorio del Teide, Tenerife, Spain. The GFPI uses two tunable etalons in collimated mounting. Thanks to its large‐format, high‐cadence CCD detectors with sophisticated computer hard‐ and software it is capable of scanning spectral lines with a cadence that is sufficient to capture the dynamic evolution of the solar atmosphere. The field‐of‐view (FOV) of 50″×38″is well suited for quiet Sun and sunspot observations. However, in the vector spectropolarimetric mode the FOV reduces to 25″×38″. The spectral coverage in the spectroscopic mode extends from 530–860 nm with a theoretical spectral resolution of R ≈250 000, whereas in the vector spectropolarimetric mode the wavelength range is at present limited to 580–660 nm. The combination of fast narrow‐band imaging and post‐factum image restoration has the potential for discovery science concerning the dynamic Sun and its magnetic field at spatial scales down to ∼50 km on the solar surface (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Sedimentary Environment Influences Ecosystem Response to Nutrient Enrichment

As coastal catchment land use intensifies, estuaries receive increased nutrient and sediment loads, resulting in habitats that are dominated by muddy organic-rich sediments. Increased mud (i.e. silt-clay (particles <?63 μm)) content has been associated with negative effects on soft sediment biodiversity and ecosystem functioning, but the simultaneous impact of nutrient enrichment on ecosystem response is unclear. Nutrient recycling and denitrification in estuarine soft sediments represent important ecosystem functions regenerating nutrients for primary producers and regulating the ability to remove excess terrestrially derived nitrogen. To test the effect of sedimentary environment on ecosystem resilience to nutrient perturbation, we experimentally enriched sediments with slow release fertiliser across an intertidal sedimentary gradient (0–24% mud content). The enrichment successfully elevated pore water ammonium concentrations (median 36?×?control) to levels representative of enriched estuaries. Findings show that the sedimentary environment can influence ecosystem function response to nutrient stress. In particular, denitrification enzyme activity was suppressed by nutrient enrichment, but the effect was greater as sediment mud content increased. Furthermore, compared with sandy sediments, sediments with high mud content may restrict nutrient processing (release, uptake or transformation of organic nutrients by the benthos) facilitating ecosystem shifts toward eutrophication. These results show the value of investigating the impacts of stressors in different environmental settings and demonstrate that land use practices that increase the proportion of muddy habitats in estuaries may reduce denitrification which in turn may reduce ecosystem resilience to eutrophication.     

Uranium and microcracks in a 1,000-meter core,Redstone, New Hampshire

The spatial distribution and mineralogical association of uranium in 30 samples of a 1,000 meter core from the Redstone (NH) Quarry were examined with fission track techniques, backscattered electron imaging, and energy dispersive X-ray spectrometry with the following results for the Conway and Mount Osceola granites: (1) Uranium occurs in microcracks sealed with siderite and/or with Ca+ RE fluorocarbonate minerals; the uranium contents of siderite and the RE fluorocarbonates are 1 to 30 ppm and 500–1,500 ppm, respectively. (2) Siderite and to a lesser extent RE fluorocarbonate minerals occur as replacement minerals of amphibole and biotite; the RE fluorocarbonates are the main alteration minerals of allanite. (3) The degree of alteration and the extent of uranium redistribution are greater in samples with major uraniferous microcracks. (4) The contents of Ca and Mn are approximately constant for siderite in sealed cracks throughout the Conway and Mount Osceola granites for the entire section penetrated by the corehole, approximately 700 meters. — From these observations, we conclude that an extensive set of fractures throughout a significant volume of the Mount Osceola and Conway granties were the conduits through which hydrothermal fluids containing CO₂, uranium, and REs circulated. Microcracks facilitated fluid-rock interactions resulting in alteration and uranium redistribution. Certain primary uraniferous accessory minerals, i.e., allanite and ilmenorutile may have been the source for at least part of the uranium and REs that now occur in secondary minerals in these granites.     

Experimental studies of groundwater pipe flow network characteristics in gravelly soil slopes

Piping flow networks have often been identified in hydrogeological field studies of gravelly soil slopes in the southern part of China. The present experimental studies have shown that under long-term groundwater seepage, piping flow networks gradually develop in the slope. Factors affecting the development of flow pipe seepage network included the grain size distribution, the degree of soil compaction, and soil depth. Piping seepage networks favorably form if the content of the gravel was high, the soil cohesion was low, the degree of the soil compaction was low, or the soil depth was shallow. Due to the enhanced permeability associated with the presence of flow pipe seepage network in gravelly soil slopes, groundwater can be effectively drained away. This can beneficially prevent the rise of groundwater level in the slope during raining seasons, hence reducing pore water pressure along the potential failure surface and increasing slope stability. Once the flow pipe seepage network was disturbed or damaged, the water level in the upper portion of the slope experienced a great rise, hence reducing the slope stability. Therefore, slope toe excavation and excessive loading at the slope crest should be avoided for slopes with well-developed flow pipe seepage network in order to preserve it.     

Tracking the sources and fate of nitrate pollution by combining hydrochemical and isotopic data with a statistical approach

This study contributes to identifying and spatializing the different types of nitrate sources by combining hydrogeochemical and isotopic data with principal component analysis (PCA) and t-distributed stochastic neighbor embedding (t-SNE) multicriteria statistical methods. The methodology is applied to the strategic Mons Basin chalk aquifer (Belgium). The results are based on a whole dataset containing 72 water samples with analyses of the hydrogeochemical parameters (temperature, pH, electrical conductivity (EC), redox potential, dissolved O₂), alkalinity, total organic carbon (TOC), silica (SiO₂), major and minor ions (NO₃^–, NH⁴⁺, Ca²⁺, dissolved Fe and Mn, K⁺, Mg²⁺, Na⁺, Sr²⁺, Cl^–, F^–, SO₄^–_, B) and multiple stable isotope ratios (δ¹¹B, δ¹⁵N–NO₃^–, δ¹⁸O–NO₃^–). Compared to classical PCA, the recently developed t-SNE method, which considers nonlinear relationships between variables and preserves local-scale similarities in a low-dimensional space, showed much better performance in discriminating different groups of samples and related zones in the aquifer. t-SNE results combined with isotope ratios highlighted four zones in the aquifer (grouped as A–D) and the presence of denitrification fronts. Group A presents a manure signature (δ¹⁵N–NO₃^– – mean (μ) +12.78‰, standard deviation (σ) 6.48‰; δ¹¹B – μ 29.96‰, σ 6.91‰). Group B exhibits both manure and inorganic fertilizer signatures (δ¹⁵N–NO₃^– – μ 6.27‰, σ 2.55‰; δ¹¹B – μ 15.86‰, σ 9.69‰). Group C shows a contamination by sewage (δ¹⁵N–NO₃^– – μ 12.67‰, σ 5.60‰; δ¹¹B – μ 9.97‰, σ 7.08‰). Group D presents a mixed signature (δ¹⁵N–NO₃^– – μ 9.25‰, σ 2.94‰; δ¹¹B – μ 20.00‰, σ 6.70‰).

     

Fingered flow: The creator of sand columns in dune and beach sands

Sand columns, sand cones, sand mushrooms and other striking sand forms are frequently observed in the Dutch and German beach and dune sands. This paper aims to clarify the mechanism of sand column formation. Recently it has become evident that homogeneous beach and dune sands often become irregularly wetted by infiltrating rainwater. In otherwise dry sandy soils, wet preferential flow paths (‘fingers’) may develop. At two test sites the volumetric soil moisture content varied between 0·2 and 12·0 per cent. The wet fingers represent the premature state of sand columns. When the dry sand in between these fingers is blown away by the wind, the more resistant wet sand of the fingers will remain in its place and appear as sand columns at the surface. As a result of wind and erosive sand drifts, striking sand forms may be formed.