Composition and pressure dependence of lattice thermal conductivity of (Mg,Fe)O solid solutions

We measured the lattice thermal conductivities of Fe_0.98O wüstite and iron-rich (Mg,Fe)O magnesiowüstite using the pulsed light heating thermoreflectance technique with a diamond anvil cell up to 61 GPa at 300 K. We found that the thermal conductivity of wüstite does not show a monotonic increase as a function of pressure, contrary to that of MgO periclase. Rocksalt (B1) to rhombohedral B1 transition is likely to induce an abnormal pressure response in the conductivity of wüstite. Our results also show that magnesiowüstite has a lower conductivity than that of MgO and FeO endmembers due to a strong iron impurity effect, which is well reproduced by a model considering phonon-impurity scattering in a binary solid solution.     

A 27-kyr record of environmental change in central Asia inferred from the sediment record of Lake Hovsgol,northwest Mongolia

Geochemistry of a sediment core from Lake Hovsgol, northwest Mongolia provides a continuous, 27-kyr history of the response of the lake and the surrounding catchment to climate change. Principle component (PC) analysis of 19 major and trace elements, total inorganic carbon (TIC), and total organic carbon (TOC) in the bulk sediment samples revealed that the 21 chemical components can be grouped into four assemblages—group-1: Na, Mg, Ca, Sr, and TIC, hosted in carbonate minerals (calcite, dolomite, and magnesian calcite); group-2: Ni, Cu, and Zn, recognized as biophilic trace metals, and TOC; group-3: Al, K, Ti, V, Fe, Rb, Cs, Ba, and Pb, composed of rock-forming minerals; and group-4: Cr, Mn, and As, sensitive to the redox condition of the sediment. The four element assemblages originated from three relevant processes. Group-1 and group-2 components are authigenic products and comprise the end member on the PC-1 score, whose variation reflects changes in the water volume, i.e. the balance between precipitation and evaporation (P/E). Group-3 components from detrital materials of the catchment contribute to the PC-2 score, whose variability indicates erosion/weathering intensity in the drainage basin, which might be controlled by the amount of vegetation cover associated with moisture change. The group-4 components of redox-sensitive elements contribute to the PC-3 score and are not an end member because of their small amount. The first two PC scores suggest a sequential record of paleo-moisture evolution in central Asia. The P/E balance in the Lake Hovsgol region, inferred from the PC-1 score, gradually increased during the glacial/interglacial transition. This resembles climate change of the North Atlantic region on the glacial–interglacial scale, but does not reflect the abrupt climate shifts such as the warm Bølling-Allerød and the cold Younger Dryas of the North Atlantic on the millennial scale. A periodic variation of ~8.7 kyr was observed in the PC-2 score profile of detrital input to Lake Hovsgol over the last glacial and Holocene. The decrease in detrital input coincided with the copious supply of moisture from the Asian monsoon regime and the North Atlantic westerly winds to the Baikal drainage basin, which includes Lake Hovsgol. Our geochemical records from Lake Hovsgol demonstrate that the climate system of interior continental Asia was strongly influenced by change on both Milankovitch and sub-Milankovitch scales.     

Distribution and characteristics of landslides induced by the Iwate–Miyagi Nairiku Earthquake in 2008 in Tohoku District, Northeast Japan

The Iwate–Miyagi Nairiku Earthquake in 2008, whose seismic intensity was M. 7.2 in Japan Meteorological Agency (JMA) scale, induced innumerable landslides on the southern flank of Mt. Kurikoma volcano allocated along the Ou Backbone Range in Northeast Japan. Most landslides are detected in a hanging wall side of the seismic fault. Those landslides are classified into five types: deep-seated slide, debris slide, shallow debris slide, secondary shallow debris slide, and debris flow. Most common landslide types induced by the earthquake are shallow debris slides and subsequent debris flows. They are intensively distributed along steep gorges incising a volcanic skirt of Mt. Kurikoma, consisting of welded ignimbrite of the Pleistocene age. Debris flows are also distributed even along gentle river floors in the southern lower flank of the volcano. The area of densely distributed debris slides, shallow debris slides, and debris flows is concordant with that of severe seismic tremor. Thus, genetic processes of landslides induced by the Iwate–Miyagi Nairiku Earthquake in 2008 are attributed to multiple causative factors such as geology, topography, and seismic force.     

Petrology and magnetic properties of the Chiang Khan,Thailand, meteorite

Summary The Chiang Khan meteorite fell on 18th November, 1981 at Chiang Khan, Thailand. It consists of olivine, orthopyroxene, clinopyroxene, Fe-Ni metal, troilite, chromite, plagioclase, glass, and phosphate in order of abundance. Olivine forms barred or porphyritic chondrules, and its composition is uniform (average Fo_80.2), close to the average composition of olivine in equilibrated H chondrites. Orthopyroxene and clinopyroxene also have compositions similar to those in equilibrated H chondrites. Both well-defined chondrules and their broken fragments are present in the recrystallized matrix. Microcrystalline plagioclase and clinopyroxene often occur in the groundmass of chondrules, but clear interstitial plagioclase is absent. Chemical composition of chromite plots in the field of chromites in H chondrites. Chiang Khan meteorite is thus classified as an equilibrated H 5 type chondrite. The equilibrium temperatures estimated by using mineral pairs are as follows: Opx-Cpx 800–900°C; Ol-Chromite 510°C.Water content is 0.24 wt %, and the hydrogen isotopic composition (D) is –89.5In the thermal demagnetization experiment magnetization steadily decreased from 0 to 500°C, whereas the remanent magnetization obtained in the A.C. demagnetization experiment is very unstable, probably owing to the large grain size of the Fe-Ni metal.With 9 Figures     

Regional metamorphism and hydrothermal alteration related to Miocene submarine volcanism ('green tuff') in the Yurihara oil and gas field, northwest Honshu Island, Japan

Abstract Alteration of reservoir rocks in the Yurihara Oil and Gas Field, hereafter referred to as the ‘Yurihara field’, have been examined by using samples from six wells. These rocks are basalts in the lowermost part of the basin-fills (‘green tuff’ Formation). These basalts were produced in many eruptions in a submarine environment during the early to middle Miocene, and they underwent continuous intensive alteration genetically associated with Miocene submarine volcanism. The alteration of the basalts is of two types: low grade metamorphism and hydrothermal. The former belongs to the type of ocean floor metamorphism and comprises two subgroups: zeolite (zone I) and prehnite-pumpellyite (zones IIa: vein and amygdule occurrence, and IIb: replacing plagioclase). The latter is characterized by potassic metasomatism accompanied by adularia, quartz and calcite veins (zones IIIa: center and IIIb: margin of the metasomatism). This overprints the low grade metamorphic alteration. The central zone of hydrothermal alteration coincides with a major estimated fault, so that fluids probably assent along the fault. The basalts erupted during 16.5-15.5 Ma, determined by planktonic foraminifera assemblages of inter-bedded shales, then underwent successive low grade metamorphism. In time, the hydrothermal alteration that overprints low grade metamorphism occurred. Adularia veins of the altered rocks located in the hydrothermal alteration zones (zone IIIa and IIIb) have been dated as 9 Ma determined by the K-Ar method. This fact indicates that the activity of low grade metamorphism had already crossed the peak before hydrothermal alteration occurred at 9 Ma. The shape of isotherms of fluid inclusion homogenization temperatures (Th) and that of isolines of apparent salinity (Tm) almost coincide with each other, and these also coincide with the distribution of hydrothermal alteration (zones IIIa and IIIb). This indicates that the fluid inclusions formed at the same time as ascending fluids produced the potassic metasomatism. The maximum Th of the fluid inclusions is 222°C and Tm indicates trapped fluids of up to 3.3 wt% equivalent NaCl (i.e. almost the same as seawater). A Th versus Tm plot indicates mixing occurred between hydrothermal fluids and formation water that has low salinity. Corrensite and chlorite form veins, and the temperatures of their formation, estimated by the extent of aluminium substitution into the tetrahedral site of chlorite, ranges between 165 and 245°C in the centre of the hydrothermal alteration zone (zone IIIa). This is consistent with the result of Th analyses. The deposition temperature of chlorite associated with prehnite in veins ranges between 190 and 215°C in zones IIa and IIb.     

Anomalous behavior of cristobalite in helium under high pressure

We have investigated the high-pressure behavior of cristobalite in helium by powder X-ray diffraction. Cristobalite transformed to a new phase at about 8 GPa. This phase is supposed to have a molar volume of about 30 % larger than cristobalite, suggesting the dissolution of helium atoms in its interstitial voids. On further compression, the new phase transformed to a different phase which showed an X-ray diffraction pattern similar to cristobalite X-I at about 21 GPa. On the other hand, when the new phase was decompressed, it transformed to another new phase at about 7 GPa, which is also supposed to have a molar volume of about 25 % larger than cristobalite. On further decompression, the second new phase transformed to cristobalite II at about 2 GPa. In contrast to cristobalite, quartz did not show anomalous behavior in helium. The behavior of cristobalite in helium was also consistent with that in other mediums up to about 8 GPa, where the volume of cristobalite became close to that of quartz. These results suggest that dissolution of helium may be controlled not only by the density (amount of voids) but also by the network structure of SiO₄ tetrahedra (topology of voids).     

Morphological classification of nearby galaxies based on asymmetry and luminosity concentration

We investigate the behaviour of the asymmetry parameter A as a morphological parameter using a 'volume-limited' sample of 349 galaxies  (distance ≤25 Mpc,  M_V ≤−18.5 mag)  and a larger magnitude-limited sample of 707 nearby galaxies. We confirm the correlation of A with morphological type. The late-type galaxies (Sdm, Sm and Im) have larger A than early-type galaxies, and they tend to have larger A than spiral galaxies. We investigate the usefulness of the A versus concentration index C _in diagram as a tool for the regular–irregular and early–late classification. The diagram is not very useful to the regular versus late-type irregular classification, as inferred previously, but it is found to be useful to the early–late classification.     

Late Cretaceous uplift history of the Cretaceous volcanic arc in Southwest Japan: Provenance analysis of the Yuasa–Aridagawa basin based on U–Pb zircon ages

The Ryoke Metamorphic complex has undergone low‐P/T metamorphism and was intruded by granitic magmas around 100 Ma. Subsequently, the belt was uplifted and exposed by the time deposition of the Izumi Group began. The tectonic history of uplift, such as the timing and processes, are poorly known despite being important for understanding the spatiotemporal evolution of the Ryoke Metamorphic Belt. U–Pb zircon ages from sedimentary rocks in the forearc and backarc basins are useful for constraining uplift and magmatism in the provenance. U–Pb dating of detrital zircons from 12 samples (four sandstones and eight granitic clasts) in the Yuasa–Aridagawa basin, a Cretaceous forearc basin in the Chichibu Belt of Southwest Japan, gave mostly ages of 60–110 Ma. Granitic clasts contained in conglomerate suggest that granitic intrusions predate the formation of Coniacian and Maastrichtian conglomerate. Emplacement ages of granitic bodies originated from granitic clasts in Coniacian conglomerate are (110.2 ±1.3) Ma, (106.1 ±1.8) Ma, (101.8+5.8–3.8) Ma, and (95.3 ±1.4) Ma; for granitic clasts in Maastrichtian conglomerate, (89.6 ±1.8) Ma, (87.3+2.4–1.8) Ma, (85.7 ±1.2) Ma, and (82.7 ±1.2) Ma. The results suggest that detrital zircons in the sandstones were mainly derived from volcanic eruptions contemporaneous with depositional age, and plutonic rocks of the Ryoke Metamorphic Belt. Zircon ages of the granitic clast samples also indicate that uplift in the provenance began after Albian and occurred at least during the Coniacian to Maastrichtian. Our results, together with the difference of provenance between backarc and forearc basins suggest that the southern marginal zone of the Ryoke Metamorphic Belt was uplifted and supplied a large amount of clastic materials to the forearc basins during the Late Cretaceous.     

Welded tuffs and related pyroclastic deposits in northeastern Japan

Welded tuffs and related pyroclastic deposits are distributed at many localities in northeastern Japan, especially around the volcanoes of the Nasu volcanic zone running from north to south, but they are absent from the region along the Japan Sea. Their geological age varies from the Miocene to the Holocene, those of the Pleistocene being predominant in amount. Petrographically they cover rather a wide range from andesite to rhyolite, among which dacite is most common. The welded tuffs are always compact and hard, with well-developed columnar jointing, carrying parallel-layered obsidian lenticules; and various stages are observed from loose pyroclastic deposits to lava-like welded tuffs. Petrological, petrochemical, and physical properties of these deposits are studied in some detail. From these data some genetic consideration is given for the mechanism of welding, and also for the relation between the nature of parental magma and the formation of such pyroclastic deposits.