Calcium and Magnesium‐bearing Sabugalite from the Tono Uranium Deposit,Central Japan

Calcium and magnesium‐bearing sabugalite occurs as aggregations of yellowish platy crystals in veinlets or druses in conglomerate from the oxidized parts of the Tono uranium deposit, Central Japan. X‐ray powder diffractometry of this mineral has reflections consistent with previous powder diffraction data of sabugalite. It is included in the monoclinic system with space group C2/m and calculated cell parameters of a = 19.68Å, b = 9.89Å, c = 9.82Å α = γ = 90°, β‐96.93° and V = 1897.83ų. Chemical analysis yields a formula of (Ca_0.10 Mg_0.09)_Σ0.19Al_0.53(UO₂)_2.04((PO₄)_1.99(AsO₄)_0.01)_Σ2.00·11.22H₂O. EMPA mapping shows that the mineral is compositionally uniform with no micron‐scale layering. Charge of cations including Ca and Mg in the cation‐H₂O layer is 1.98 being identical to that of autunite group minerals. This suggests that the charge balance in the cation‐H₂O layer of the mineral could be made by the alkaline earth or alkaline elements rather than by hydrogen ions.     

Origin of the Moon — Capture by gas drag of the Earth's primordial atmosphere

We propose a new scenario of the lunar origin, which is a natural extension of planetary formation processes studied so far by us in Kyoto. According to these studies, the Earth grew up in a gaseous solar nebula and, consequently, the sphere of its gravitational influence (i.e., the Hill sphere of the Earth) was filled by a gas forming a dense primordial atmosphere of the Earth. In the later stages, this atmosphere as well as the solar nebula was dissipated gradually, owing to strong activities of the early-Sun in a T Tauri-stage.In the present and the subsequent papers, we study a series of dynamical processes where a lowenergy (i.e., slightly unbound) planetisimal is trapped within the terrestrial Hill sphere, under the above-mentioned circumstances that the gas density of the primordial atmosphere is gradually decreasing. It is clear that two conditions must be satisfied for the lunar origin: first, an unbound planetesimal entering the Hill sphere have to dissipate its kinetic energy and come into a bound orbit before it escapes from the Hill sphere and, second, the bound planetisimal never falls onto the surface of the Earth.In this paper we study the first condition by calculating the oribital motion of a planetesimal in the Hill sphere, which is affected both by solar gravity and by atmospheric gas drag. The results show that a low-energy planetisimal with the lunar mass or less can be trapped in the Hill sphere with a high probability, if it enters the Hill sphere at stages before the atmospheric density is decreased to about 1/50 of the initial value.In the subsequent paper, the second condition will be studied and it will be shown that a tidal force, among other forces, is very important for a trapped planetesimal to avoid collision with the Earth and stay eternally in the Hill sphere as a satellite.     

Heavy Sulfur-isotope Enrichment in Middle Miocene Onnagawa Mudstones in the Green Tuff Region, Northeastern Japan

Abstract. Sulfur isotope ratios are analyzed for a series of mudstones in a successive section in the Taiheizan area in the central Green Tuff region, northeast Japan. The δ³⁴S values for the Uyashinai Mudstone Member (Nishikurosawa stage), the Onnagawa Formation and the Funakawa Formation range from -45 to -14%, -20 to +4% and -30 to -10%, respectively. There is a marked positive shift in δ³⁴S values at the Nishikurosawa/Onnagawa boundary and an upward δ³⁴S-decreasing trend in the Onnagawa and Funakawa Formations. The present data provides evidence for environmental change in the form of stratification of the seawater, initiated at the Nishikurosawa/Onnagawa boundary and persisting during deposition of the Onnagawa Formation, followed by gradual oxygenation during deposition of the Funakawa Formation.     

Collapse mechanism of the Paleogene Sakurae cauldron, SW Japan

The Paleogene Sakurae cauldron of SW Japan is characterized by a nested structure with a polygonal outline (21×13 km²) including a circular collapsed part (5 km in diameter). Total thickness of the caldera infill amounts to 2,000 m. The lower member of the infill consists mainly of felsic crystal tuff and lesser intercalated andesitic lava flows, whereas the upper member is composed of high-grade ignimbrite capped with a large rhyolitic lava dome. These members represent the first and second stage eruptions, respectively. Faults bounding the cauldron rim comprise intersecting radial and concentric faults, producing the polygonal outline of this cauldron. The primary collapse of this cauldron thus occurred as a polygonal caldera basin where products of the first stage eruption accumulated. In contrast, the inner collapse part is defined by a ring fracture system. This sector subsided concurrently with accumulation of the high-grade ignimbrite of the second stage eruption. This inner circular collapse thus represents syn-eruptional subsidence concurrent with the climactic eruption. Magma drainage during the first stage probably induced outward-dipping ring fractures in the chamber roof. Opening of the ring fractures following subsidence of the central bell-jar block caused rapid evacuation of magma as voluminous pumice flows, even though magma pressure may have decreased to some degree.     

Geology, Wall-rock Alteration and Vein Paragenesis of the Bilimoia Gold Deposit, Kainantu Metallogenic Region, Papua New Guinea

The Bilimoia deposit (2.23 Mt, 24 g/t Au), located in the eastern Central Mobile Belt of mainland Papua New Guinea, is composed of fault‐hosted, NW–NNW‐trending Irumafimpa–Kora and Judd–Upper Kora Au‐quartz veins hosted by Middle–Late Triassic basement that was metamorphosed to medium‐grade greenschist facies between Middle–Late Triassic and Early–Middle Jurassic. Mineralizing fluids were introduced during crustal thickening, rapid uplift, change of plate motions from oblique to orthogonal compression, active faulting and S₃ and S₄ events in an S₁–S₄ deformation sequence. The Bilimoia deposit is spatially and temporally related to I‐type, early intermediate to felsic and late mafic intrusions emplaced in Late Miocene (9–7 Ma). Hydrothermal alteration and associated mineralization is divided into 10 main paragenetic stages: (1) chlorite–epidote‐selvaged quartz–calcite–specularite vein; (2) local quartz–illite–pyrite alteration; (3) quartz–sericite–mariposite–fuchsite–pyrite wall‐rock alteration that delimits the bounding shears; (4) finely banded, colloform‐, crustiform‐ and cockade‐textured and drusy quartz ± early wolframite ± late adularia; (5) hematite; (6) pyrite; (7) quartz ± amethyst‐base metal sulfides; (8) quartz–chalcopyrite–bornite–Sn and Cu sulfides–Au tellurides and Te ± Bi ± Ag ± Cu ± Pb phases; (9) Fe ± Mn carbonates; and (10) supergene overprint. Fluid inclusions in stage 4 are characterized by low salinity (0.9–5.4 wt% NaCl equivalent), aqueous–carbonic fluids with total homogenization temperatures ranging from 210 to 330°C. Some of the inclusions that homogenized between 285 and 330°C host coexisting liquid‐ and vapor‐rich (including carbonic) phases, suggesting phase separation. Fluid inclusions in quartz intergrown with wolframite have low salinity (0.9–1.2 wt% NaCl equivalent), aqueous–carbonic fluids at 240–260°C, defining the latter’s depositional conditions. The ore fluids were derived from oxidized magmatic source initially contaminated by reduced basement rocks. Wall‐rock alteration and involvement of circulating meteoric waters were dominant during the first three stages and early part of stage 4. Stage 5 hematite was deposited as a result of stage 4 phase separation or entrainment of oxygenated groundwater. Gold is associated with Te‐ and Bi‐bearing minerals and mostly precipitated as gold‐tellurides during stage 8. Gold deposition occurred below 350°C due to a change in the sulfidation and oxidation state of the fluids, depressurization and decreasing temperature and activities of sulfur and tellurium. Bisulfides are considered to be the main Au‐transporting complexes. The Bilimoia deposit has affinities that are similar to many gold systems termed epizonal orogenic and intrusion‐related. The current data allow us to classify the Bilimoia deposit as a fault‐controlled, metamorphic‐hosted, intrusion‐related mesothermal to low sulfidation epithermal quartz–Au–Te–Bi vein system.     

Mesoscale eddy effects on temporal variability of surface chlorophyll a in the Kuroshio Extension

We investigated the relationship between chlorophyll a (Chl-a) concentrations estimated from satellite observations and the activity of eddies in the Kuroshio Extension region. High (low) area-averaged Chl-a concentrations were frequently observed in the core of cyclonic (anticyclonic) eddies. Such relationships between Chl-a concentrations and eddy cores were not frequently observed in the southern part of the recirculation gyre, and advection of background meridional gradient of Chl-a by eddy-edge currents accounted for Chl-a spatial variability. Decadal-scale changes of Chl-a concentrations around the Kuroshio Extension were strongly affected by eddy activity and transport but not by large-scale near-surface isopycnal heaving. We also found that decadal changes of nutrient concentrations near the main stream could affect Chl-a concentrations in the southern part of the recirculation gyre via southward transport of eddies and mean flow.     

Evaluation of radiation-damage halos in quartz by cathodoluminescence as a geochronological tool

Detailed quantitative cathodoluminescence (CL) imaging analysis was carried out for radiation-damage halos observed by CL (CL halo) created in natural quartz by implantation of 4 MeV He⁺ ions. The band of CL halo was approximately 14 μm in width and was constant for any He⁺ ion dose. The width of the halo is consistent with the theoretical range of ⁴He ions in quartz. A quantitative response of CL intensity to He⁺ ion dose was obtained, leading to the application of CL halos to geodosimetrical use. The CL intensity increases exponentially in the luminescent band from the implantation surface to the inside, until it reaches a maximum at 14 μm depth, with a rapid decrease beyond this point. This result is as predicted by Bragg's law, although we find some differences between the CL intensity and the theoretical stopping power.     

He+ ion implantation and electron irradiation effects on cathodoluminescence of plagioclase

Cathodoluminescence (CL) spectra of unirradiated, He⁺ ion-implanted and electron-irradiated plagioclase minerals contain the following emission bands: (1) below 300 nm due to Pb²⁺, (2) at ~320 and ~350 nm to Ce³⁺, (3) at 380–420 nm to Eu²⁺, Ti⁴⁺ and/or Al–O^?–Al/Ti defects, (4) at 560–580 nm to Mn²⁺ and (5) at 720–760 nm to Fe³⁺. During the implantation of He⁺ ion, much of their energy may be dissipated by partial destruction and strain of the feldspar framework, resulting in quenching of CL. Deconvolution of CL spectra acquired from albite and oligoclase reveals an emission component at 1.86 eV (666 nm) assigned to a radiation-induced defect center associated with Na⁺ atoms. As its intensity increases with radiation dose, this emission component has potential for geodosimetry and geochronometry. Electron irradiation causes Na⁺ migration in plagioclase, and then a considerable reduction in intensity of emissions assigned to impurity centers, which is responsible for an alteration in the energy state or a decrease in luminescence efficiency following the change of activation energy. Emission intensity at 1.86 eV positively correlates with electron irradiation time for unimplanted and He⁺ ion-implanted albite and oligoclase, but negatively for the implanted albite above 1.07 × 10^?4 C/cm². It implies that radiation halo produced by α-particles should not be measured using CL spectroscopy to estimate β radiation dose on albite in the high radiation level.     

Effects of variability of sea ice transport through the Fram Strait on the intensity of the Atlantic deep circulation

Results from an ice-ocean coupled model are used to investigate the impact of long-term variability in sea ice transport at the Fram Strait on the intensity of the Atlantic deep circulation. An increase (or decrease) in sea ice transport through the Fram Strait leads to a stronger (or weaker) deep circulation in the Atlantic. Change in the sea ice transport is accompanied by a salinity anomaly in the surface layer of the Arctic Ocean. Such an anomaly could inversely affect the Atlantic circulation once it reaches deep water formation regions. If the Canadian Archipelago is closed, the anomaly is subsequently transported through the Fram Strait, and counters the initial changes in the Atlantic deep circulation. On the other hand, if the Canadian Archipelago is open, some of the anomaly is transported to the Canadian Archipelago, and the initial change in the Atlantic deep circulation persists. In the Arctic Ocean basin, the time scale and path of the salinity anomalys propagation depends on the large-scale flow at the surface of the Arctic Ocean. Our results suggest that the salinity anomaly transport and its propagation pathway out of the Arctic Ocean are important determinants of the role of sea ice transport variability through the Fram Strait in controlling the intensity of the Atlantic deep circulation.     

A new scheme of nonlinear energy transfer among wind waves: RIAM method-algorithm and performance-

A numerical scheme for calculating the nonlinear energy transfer among wind waves (RIAM method) was developed on the basis of the rigorous method of Masuda. Then the performance of the RIAM method was examined by applying it to various forms of wind-wave spectra and different situations of wind-wave evolution, in comparison mainly with the WAM method. The computational time of the Masuda method was reduced by a factor of 300 by the RIAM method, which is still 2000 times slower than the WAM method simply because the RIAM method processes thousands of resonance configurations whereas the WAM method does only one. The RIAM method proves to give accurate results even for spectra of narrow band widths or bimodal spectra, whereas the WAM method often calculates an unrealistic magnitude and pattern of nonlinear energy transfer functions. In the duration-limited evolution of wind-wave spectra, the RIAM method yields a unimodal directional distribution on the low-frequency side of the spectral peak, whereas the WAM method produces a spurious bimodal one there. At higher frequencies, however, both methods give a bimodal directional distribution with two oblique maxima. The RIAM method enhances the growth of the total energy and peak period of wind waves in comparison with the WAM method. Nevertheless, Toba's constant of his 3/2-power law approaches almost the same standard value of 0.06 in both methods. For spectra of a narrow band width or for those perturbed by a small hump or depression, the RIAM method tends to recover the monotonic smoother form of spectrum whereas the WAM method often yields unrealistic humps or depressions.