Factors affecting the distribution of potentially toxic elements in surface soils around an industrialized area of northwestern Greece

In order to investigate the factors influencing the distribution of 32 potentially toxic elements in the Ptolemais–Kozani basin, northwestern Greece, 38 soil samples were collected and analyzed. Concentrations of Al, Ca, Fe, K, Mg, Mn, Na, P, Ti, Ba, Co, Cr, Cu, La, Li, Ni, Pb, Sc, Sr, V, Y, and Zn were determined by ICP-AES and concentrations of As, Bi, Cd, Cs, Mo, Rb, Sb, Th, Tl, and U by ICP-MS. Bivariate analysis, principal component analysis, and geostatistical analysis were employed to investigate the factors influencing the distribution of the elements determined in the study area. The results indicate that the distribution of the majority of elements determined, especially for Cr, Ni, and associated elements, is greatly influenced by the geology and geomorphology of the study area. Principal component analysis has yielded four factors that explain over 77% of the total variance in the data. These factors are as follows: lithophilic elements that are associated with Al silicates minerals of K (factor I: 29.4%), ultramafic rocks (factor II: 20.5%), elements that are coprecipitated with Fe and Mn oxides (factor III: 18.0%), and anthropogenic activities (factor IV: 9.3%). The anthropogenic activities that influence the distribution of several potentially toxic elements (i.e., Cd, Cu, Pb, Zn) are agricultural practices and the deposition of fly ash in the vicinity of the local power stations.     

A critical state interpretation for the cyclic liquefaction resistance of silty sands

Contrary to many laboratory investigations, common empirical correlations from in situ tests consider that the increase in the percentage of fines leads to an increase of the cyclic liquefaction resistance of sands. This paper draws upon the integrated Critical State Soil Mechanics framework in order to study this seemingly not univocal effect. Firstly the effect of fines on the Critical State Line (CSL) is studied through a statistical analysis of a large data set of published monotonic triaxial tests. The results show that increasing the content of non-plastic fines practically leads to a clockwise rotation of the CSL in (e–ln p) space. The implication of this effect on cyclic liquefaction resistance is subsequently evaluated with the aid of a properly calibrated critical state elasto-plastic constitutive model, as well as a large number of published experimental results and in situ empirical correlations. Both sets of data show clearly that a fines content, less than about 30% by weight, may prove beneficial at relatively small effective stresses (p₀<50–70 kPa), such as the in situ stresses prevailing in most liquefaction case studies, and detrimental at larger confining stresses, i.e. the stresses usually considered in laboratory tests. To the extent of these findings, a correction factor is proposed for the practical evaluation of liquefaction resistance in terms of the fines content and the mean effective confining stress.     

Contribution of geophysical methods to karst-system exploration: an overview

The karst environment is one of the most challenging in terms of groundwater, engineering and environmental issues. Geophysical methods can provide useful subsurface information in karst regions concerning, for instance, hazard estimation or groundwater exploration and vulnerability assessment. However, a karst area remains a very difficult environment for any geophysical exploration; selection of the best-suited geophysical method is not always straightforward, due to the highly variable and unpredictable target characteristics. The state of the art is presented, in terms of the contributions made by geophysical methods to karst-system exploration, based on extensive analysis of the published scientific results. This report is an overview and should be used as a preliminary methodological approach, rather than a guideline.     

<Emphasis Type="Italic">M</Emphasis><Subscript>W</Subscript>9 Tohoku earthquake in 2011 in Japan: precursors uncovered by natural time analysis

This paper reviews the precursory phenomena of the 2011 M _W9 Tohoku earthquake in Japan that emerge solely when we analyze the seismicity data in a new time domain termed natural time. If we do not consider this analysis, important precursory changes cannot be identified and hence are missed. Natural time analysis has the privilege that enables the introduction of an order parameter of seismicity. In this frame, we find that the fluctuations of this parameter exhibit an unprecedented characteristic change, i.e., an evident minimum, approximately two months before Tohoku earthquake, which strikingly is almost simultaneous with unique anomalous geomagnetic field variations recorded mainly on the z component. This is consistent with our finding that such a characteristic change in seismicity appears when a seismic electric signal (SES) activity of the VAN method (from the initials of Varotsos, Alexopoulos, Nomicos) initiates, and provides a direct confirmation of the physical interconnection between SES and seismicity.     

Identifying the occurrence time of an impending mainshock:a very recent case

The procedure by means of which the occurrence time of an impending mainshock can be identified by analyzing in natural time the seismicity in the candidate area subsequent to the recording of a precursory seismic electric signals(SES) activity is reviewed. Here, we report the application of this procedure to an MW5.4 mainshock that occurred in Greece on 17 November 2014. This mainshock(which is pretty rare since it is the strongest in that area for more than half a century) was preceded by an SES activity recorded on 27 July 2014, and the results of the natural time analysis reveal that the system approached the critical point(mainshock occurrence) early in the morning on 15 November 2014.     

Elimination of Zinc from Roof Runoff through Geotextile and Clinoptilolite Filters

Direct infiltration of roof runoff into the ground may pose a potential risk of soil and groundwater contamination. The performance of two different barrier materials for the retention of zinc from roof runoff of an eleven year old zinc roof was examined in a field study. As barrier materials geotextile and clinoptilolite were applied. Automatic samplers were used to take samples both at the inlet and at the outlet of the retention facility. Samples of twenty rain events were examined. Zinc was detected in the roof runoff in concentrations of up to 25 mg/L, and lead which originates from the tin‐solder was present in concentrations of up to 84 μg/L. Under most circumstances, a first flush could be observed for the analysed substances. No retention of heavy metals was observed, where only geotextile was used as a barrier material. The clinoptilolite filter was able to adsorb up to 97 % of zinc from the roof runoff.     

The fine and coarse particulate matter at four major Mediterranean cities: local and regional sources

Particulate air pollution is associated with adverse health effects to the population exposed. The aim of this paper is the identification of local and regional sources, affecting PM₁₀ and PM_2.5 levels in four large cities of southern Europe, namely: Lisbon, Madrid, Marseille, and Rome. Air pollution data from seven sampling sites of the European Union network were used. These stations were selected due to their ability of monitoring PM_2.5 concentrations and providing reliable series of data. Each station’s background was also taken into account. Pearson correlation coefficients and primal component analysis components were extracted separately for cold and warm periods in order to define the relationships among particle matters (PM_s) and gaseous pollutants (CO, NO₂, SO₂, and O₃) and evaluate the contributions of local sources. Possible seasonal variations of PM_2.5/PM₁₀ ratio daily values were also used as markers of PM sources, influencing particulate size distribution. Particle emissions were primarily attributed to traffic and secondarily to natural sources. Minimum daily values of PM_2.5/PM₁₀ ratio were observed during warm periods, particularly at suburban stations with rural background, due to dust resuspension and also due to the increase of biogenic coarse PM (pollen, dust, etc.). Hybrid Single-Particle Lagrangian Integrated Trajectory Model trajectory model was used in order to compute the 4-day backward trajectories of the air masses that affected the four cities which are under study during days with recorded PM₁₀ exceedances, within a 5-year period (2003–2007), at 300, 750, and 1,500 m above ground level (AGL). The trajectories were then divided to clusters with a K-means analysis. In all four cities, the influence of slow-moving air masses was associated with a large fraction of PM₁₀ exceedances and with high average and maximum daily mean PM₁₀ concentrations, principally at the 300 m AGL analysis. As far the issue of the increased PM₁₀ concentrations, the results were weaker in Marseille and particularly in Rome, probably due to their greater distance from Northwest Africa, in comparison to Madrid and Lisbon. Dust intrusions from the Sahara desert and transportation of Mediterranean/Atlantic sea spray, were characterized as primary regional sources of exogenous PM₁₀ in all four cities. Continental trajectories from the industrialized northern Italy affected PM₁₀ levels particularly in Marseille and Rome, due to their more eastern geographical position.     

Damage sequence and safety margin assessment of expansion joints by shake table testing

The performance of nonstructural components has attracted attention, and previous large earthquakes have resulted in widespread damage to expansion joints. In contrast to the main structural components, for which ductility beyond the design tolerance is ensured, the safety margin of nonstructural components classified as the product of mechanical engineering, such as expansion joints, is uncertain. This paper investigates the damage sequence and safety margin of expansion joints through shake table testing. The expansion joints were installed to connect 2 rigid steel frames with short and long natural periods. Four commonly used types, high-performance and standard-performance floor and wall expansion joints, were tested. Seven damage patterns of the 4 expansion joints were observed, and most of the damage patterns were considered displacement dependent. The damage mechanisms and relative displacements at the moment of damage were identified by using strain gauges attached near collision and damage locations. The high-performance expansion joints showed only minor damage beyond the design motion range, whereas the standard-performance expansion joints exhibited minor damage below the design motion range and failure at the design motion range or slightly beyond. For each damage state, repair information was obtained through a questionnaire to an expansion joint manufacturer, and the sum of the initial cost and repair cost for high-performance and standard-performance expansion joints was compared. The results will be useful for the selection of expansion joints in the design process.