Atmospheric and Coupled Model Intercomparison in Terms of Amplitude—Phase Characteristics of Surface Air Temperature Annual Cycle

1. Introduction In spite of the progress achieved in global climatemodelling during the last few decades, the models stillshow considerable errors even for the surface air tem-perature ?eld (Covey et al., 2000; IPCC, 2001; Lam-bert and Boer, 2001). As i…     

Luminescence dating of the top of a deep water core from the NESTOR site near the Hellenic Trench,east Mediterranean Sea

In the present study, the uppermost 3 cm of muddy, seabed sediment was collected from a deep-sea sediment core, drilled from a water depth of 4 km, near the deepest site of the Mediterranean Sea, outside Pylos, Greece. The core was divided into 7 layer samples, each 3–4 mm thick, in order to get an independent age assessment for each one using luminescence dating; from polymineral coarse grains in the range 30–60 μm. Between 11 and 22 aliquots were measured for each sample using the optically stimulated luminescence, single-aliquot regenerative-dose analysis. The estimated mean equivalent dose values had an uncertainty less than 3% and resulted in optical ages ranging from 3.5 to approximately 5 ka, with uncertainties lying between 5.5 and 7.4%. Multiple-aliquot, thermoluminescence-based, additive-dose, total bleaching approach provided equivalent doses with typical errors of 10–15% and ages in the range of 3.6 and 9.4 ka, with uncertainties up to 17%. Single-aliquot optical ages are shown to be relatively successful, due to their consistency with AMS ¹⁴C radiocarbon ages, obtained from Planktonic foraminifera from the same core. Luminescence dates for the topmost 1.5 cm indicate a substantial mix and post burial disturbance of the surface sediment. Below the topmost 1.5 cm, both luminescent approaches indicate ages which increase smoothly with depth. The concordant OSL and TL age estimates for the sample O5, in conjunction with specific luminescence properties and its major-element geochemical chemistry content, suggest that it was heated during the Santorini volcanic eruption. Deposition rates of 8.6–18.9 cm over 10 ka below the sample O5, provided by optical ages, exhibit an excellent level of agreement with the accumulation rate of 7–18 cm over 10 ka at the sea bottom, already reported for the site under study.     

Body tides on a 3-D elastic earth: Toward a tidal tomography

The deformational and gravitational response of the Earth to the tide generating potential has generally involved 1-D (i.e., depth varying) Earth models. Progressive improvement in observational constraints on body tides, generated from both ground and space-based surveys, suggests that an examination of the potential impact of lateral variations in Earth structure is warranted. We present a suite of predictions of the body tide response within the semi-diurnal, diurnal and long-period tidal bands computed using a finite-volume numerical code. The calculations adopt 3-D density and elastic structure taken from seismic inferences and, in a subset of the calculations, dynamic topography on the surface and internal interfaces. We find that perturbations in the radial displacement and surface gravity within the semi-diurnal band reach ~ 1 mm and 0.15 µgal, respectively. The perturbations in the diurnal band are comparable to these values, and within the long-period band they are a factor of 3–5 smaller. We also demonstrate that lateral variations in the elastic moduli, which have been ignored in recent work, contribute greater than 50% of the total perturbation. The level of perturbation associated with 3-D structure exceeds the current observational uncertainty obtainable using space-geodetic methods, and this suggests the possibility of performing tidal tomographic inversions of such data.     

Detrital blue amphiboles from the western Othrys Mountain and their relationship to the blueschist terrains of the Hellenides (Greece)

In contrast to blue amphiboles of the Ossa and Olympos tectonic windows in Thessaly, detrital blue amphiboles in Paleocene flysch deposits in the western Othrys Mountain (Pelagonian Zone s.l.) are chemically comparable with blue amphiboles from the Cyclades. For the detrital material, therefore, a source with "Cycladic" chemical affinities is assumed. The occurrence of these detrital minerals is in line with a Cretaceous onset of blueschist facies metamorphism in parts of the Hellenides, especially in the Cycladic belt. This was in response to Cretaceous subduction of the Pindos oceanic plate along the external margin of the Pelagonian micro-continent. Blueschist complexes were exhumed latest in the Paleocene when the terrigenous flysch sedimentation started in the Pelagonian and Pindos zones.     

The stress state of Venusian crust and variations of its thickness: Implication for tectonics and geodynamics

The data obtained for the heights of the relief and the external gravitational field of Venus for spherical harmonics with degree and order up to 18 allow one to start theoretical analysis of the crust-mantle boundary (Venusian Moho) and stress state of the planetary interior. We suppose that Venusian convection is confined by floating massive crust. Apparently the convection in the upper mantle of Venus is separated from that one in the lower mantle and its lateral scale must be essentially smaller than on Earth. So, the convection is reflected to a larger degree of the gravitational field of the planet than for Earth. The spherical harmonic expansion of the topography for Venus correlates with corresponding expansion of the non-equilibrium part of the gravitational potential for n = 3–18. At the same time the relief of Venus is significantly compensated. It is reasonable to suppose that the gravity field for these harmonics is due to crustal thickness variations and, probably, to variations of crustal density. Thus, in the proposed scheme the Moho's relief causes the partial isostatic compensation of the topography.All calculations are carried out for the series of realistic models of Venus taking into consideration an asthenosphere. The asthenosphere is modeled either by a weakened (shear modulus is reduced), or by a liquid inviscid layer. We also suppose that the asthenosphere extends from the base of crust to a depth of 418 km, and the density contrast across the Moho boundary is –0.4 g * cm^–3. If the actual density contrast across the Moho is less than the supposed one by some factor, then one must increase the amplitudes of the roots and inverse roots by the same factor. The results for the Moho's relief and stresses in the crust are presented for the case of the mean thickness of the crust of 50 km, which satisfies the probable upper (connected with phase transitions in waterless basalts) and lower (appearing in the framework of our interpretation) limits.On the whole, the crust-mantle boundary on Venus is evidently smooth, and the stress level in the crust is appreciably smaller than the crustal stresses on the Earth. The strong sensitivity of the stresses character to the parameters of the model of external layers of Venus together with geological data allow us to begin a preliminary investigation of the tectonical structure and geodynamics of the planet.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).     

The equation of state of Al,H-bearing SiO2 stishovite to 58 GPa

We have determined the P-V equation of state of Al-rich H-bearing SiO₂ stishovite by X-ray powder diffraction at pressures up to 58 GPa using synchrotron radiation. The sample contained 1.8 wt% Al₂O₃ and up to 500 ppm H₂O, and had a composition that would coexist with Mg-silicate perovskite in a subducted slab. By fitting a third-order Birch-Murnaghan equation of state to our compression data, we obtained a bulk modulus K _T0=298(7) GPa with K′=4.3(5). With K′ fixed to a value of 4, the bulk modulus K _T0=304(3) GPa. Our results indicate that Al³⁺ and H⁺ have a small effect on the elastic properties of stishovite. Compared with data obtained up to 43.8 GPa, peak intensities changed and we observed a decreased quality of fit to a tetragonal unit cell at pressures of 49 GPa and higher. These changes may be an indication that the rutile↔CaCl₂ transition occurs between these pressures. After laser annealing of the sample at 58.3(10) GPa and subsequent decompression to room conditions, the cell volume is the same as before compression, giving strong evidence that the composition of the recovered sample is also unchanged. This suggests that Al and H are retained in the sample under extreme P-T conditions and that stishovite can be an agent for transporting water to the deepest lower mantle.     

Phase relations in hydrous MORB at 18-28 GPa: implications for heterogeneity of the lower mantle

The phase relations in hydrous and anhydrous mid-ocean ridge basalt were determined at pressures of 18-28 GPa. Liquidus phase relations in hydrous and anhydrous MORB are different. Garnet is the liquidus phase at pressures below 21 GPa, Ca-Al (CAS) phase and stishovite are the liquidus phases at pressures of 22-27 GPa, and stishovite and Ca-perovskite are the liquidus phases above 27 GPa, whereas Ca-perovskite is a liquidus phase of anhydrous MORB at pressures above 23 GPa. Under subsolidus conditions, we have found that in the hydrous MORB system the stability fields of Al-bearing perovskite and Na-Al (NAL) phase might shift to lower pressure by about 1.5 GPa compared to the dry MORB system. This shift could be explained by oxidation of a garnet-bearing assemblage by hydrous fluid and formation of Fe³⁺-bearing aluminous perovskite at lower pressures relative to the anhydrous system and/or differences in water solubility of the phases existing in perovskite-bearing assemblages. Our data indicate that hydrous basaltic crust remains denser than peridotite along the geotherm of a subducting slab, i.e. there is no density crossover between peridotite and basalt. Therefore, in slabs going through the 660 km discontinuity, basalt would gravitationally sink into the lower mantle under relatively hydrous conditions. The delamination of former basaltic crust near the 660 km discontinuity might be possible under relatively dry conditions of subduction. There are no stable highly hydrous phases in MORB above 10 GPa even at lower temperatures corresponding to subducting slabs. Therefore, MORB cannot be an important carrier of water to the deep Earth interior. However, it can be constantly supplied by water-bearing fluid from the underlying peridotite part of the descending slab. Thus, it is plausible that water can control subduction of the oceanic crust into the lower mantle.     

Intradaily variability of water quality in a shallow tidal lagoon: Mechanisms and implications

Although surface water quality and its underlying processes vary over time scales ranging from seconds to decades, they have historically been studied at the lower (weekly to interannual) frequencies. The aim of this study was to investigate intradaily variability of three water quality parameters in a small freshwater tidal lagoon (Mildred Island, California). High frequency time series of specific conductivity, water temperature, and chlorophylla at two locations within the habitat were analyzed in conjunction with supporting hydrodynamic, meteorological, biological, and spatial mapping data. All three constituents exhibited large amplitude intradaily (e.g., semidiurnal tidal and diurnal) oscillations, and periodicity varied across constituents, space, and time. Like other tidal embayments, this habitat is influenced by several processes with distinct periodicities including physical controls, such as tides, solar radiation, and wind, and biological controls, such as photosynthesis, growth, and grazing. A scaling approach was developed to estimate individual process contributions to the observed variability. Scaling results were generally consistent with observations and together with detailed examination of time series and time derivatives, revealed specific mechanisms underlying the observed periodicities, including interactions between the tidal variability, heating, wind, and biology. The implications for monitoring were illustrated through subsampling of the data set. This exercise demonstrated how quantities needed by scientists and managers (e.g., mean or extreme concentrations) may be misrepresented by low frequency data and how short-duration high frequency measurements can aid in the design and interpretation of temporally coarser sampling programs. The dispersive export of chlorophylla from the habitat exhibited a fortnightly variability corresponding to the modulation of semidiurnal tidal currents with the diurnal cycle of phytoplankton variability, demonstrating how high frequency interactions can govern long-term trends. Process identification, as through the scaling analysis here, can help us anticipate changes in system behavior and adapt our own interactions with the system.     

The REMO Ocean Data Assimilation System into HYCOM （RODAS_H）： General Description and Preliminary Results

The first version of the Brazilian Oceano- graphic Modeling and Observation Network （REMO） ocean data assimilation system into the Hybrid Coordi- nate Ocean Model （HYCOM） （RODAS H） has recently been constructed for research and operational purposes. The system is based on a multivariate Ensemble Optimal Interpolation （EnOI） scheme and considers the high fre- quency variability of the model error co-variance matrix. The EnOl can assimilate sea surface temperature （SST）, satellite along-track and gridded sea level anomalies （SLA）, and vertical profiles of temperature （T） and salinity （S） from Argo. The first observing system experiment was carried out over the Atlantic Ocean （78°S-50°N, 100°W-20°E） with HYCOM forced with atmospheric reanalysis from 1 January to 30 June 2010. Five integra- tions were performed, including the control run without assimilation. In the other four, different observations were assimilated： SST only （A SST）; Argo T-S profiles only （AArgo）; along-track SLA only （A_SLA）; and all data employed in the previous runs （A_All）. The A_SST, A_Argo, and A_SLA runs were very effective in improv- ing the representation of the assimilated variables, but they had relatively little impact on the variables that were not assimilated. In particular, only the assimilation of S was able to reduce the deviation of S with respect to ob- servations. Overall, the A_All run produced a good analy- sis by reducing the deviation of SST, T, and S with respect to the control run by 39%, 18%, and 30%, respectively, and by increasing the correlation of SLA by 81%.