Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

Ultimate bearing capacity of energy piles in dry and saturated sand

Acta Geotechnica - The influence of thermal loads on the ultimate bearing capacity of energy piles is examined. Five laboratory model tests were carried out to investigate piles equipped with...     

基于星载GPS的HY-2卫星高精度精密定轨模拟研究(英文)

HY-2卫星是我国第一颗测高卫星,其径向定轨精度要求厘米量级,搭载了星载GPS接收机。目前HY-2还处于测试阶段,没有公布观测数据。为了确定基于星载GPS的HY-2精密定轨流程及其定轨精度,本文模拟了HY-2卫星星载GPS观测数据,结果表明HY-2星载GPS天线每个历元至少观测7颗GPS卫星。给出了基于星载GPS的精密定轨流程,分别采用简化动力学方法和动态几何法进行了精密定轨实验。对于相位1mm和3mm随机误差的相位观测数据,简化动力学法和动态几何法定轨都能够实现厘米量级的径向精密定轨,几何法定轨精度略低于简化动力定轨。地球重力场模型是影响HY-2卫星精密定轨的重要因素,本文对不同阶次的重力场模型EIGEN2、EGM96、TEG4和GEMT3进行了简化动力学定轨实验,高于50阶次的重力场模型都能够实现厘米级径向精密定轨,主要原因在于大量的高精度星载GPS观测数据和重力场模型精度的提高。     

Evaluation of earthquake signal characteristics for early warning

This paper evaluates different characteristics for earthquake early warning.The scaling relationships between magnitude,epicenter distance and calculated parameters are derived from earthquake event data from USGS.The standard STA/LTA method is modified by adding two new parameters to eliminate the effects of the spike-type noise and small pulsetype noise ahead of the onset of the P-wave.After the detection of the P-wave,the algorithm extracts 12 kinds of parameters from the first 3 seconds of the P-wave.Then stepwise regression analysis of these parameters is performed to estimate the epicentral distance and magnitude.Six different parameters are selected to estimate the epicentral distance,and the median error for all 419 estimates is 16.5 km.Four parameters are optimally combined to estimate the magnitude,and the mean error for all events is 0.0 magnitude units,with a standard deviation of 0.5.Finally,based on the estimation results,additional work is proposed to improve the accuracy of the results.     

Prevalence and diversity of norovirus genogroups I and II in Hong Kong marine waters and detection by real-time PCR

Marine waters from six sites around Hong Kong with varying levels of sewage pollution were examined for noroviruses (NoVs) by PCR cloning and sequencing of a highly-variable N-terminal region of the VP1 capsid gene, at the ORF1-ORF2 junction of NoV. Phylogenetic analysis of genogroups GI- and GII-specific PCR clones obtained from different marine sites indicated that human NoV GI.1 and GII.4 strains are the most prevalent genotypes circulating in Hong Kong waters. GI- and GII-specific TaqMan-based real-time PCR assays targeting the ORF1-ORF2 junction of NoVs were used to quantify NoV particles in marine water samples in parallel with total Escherichia coli counts which were enumerated on TBX medium. No correlation of any significance between NoV and E. coli counts was observed which highlighted the inadequacy in using E. coli as a fecal indicator to predict the level of NoVs in marine waters to protect public health.     

Reduction of future disaster damages by learning from disaster experiences

This paper examines the effect of a country’s own past disaster experiences and nearby countries’ past experiences on subsequent disaster damage. We use global disaster data from 1990 to 2010, which include disaster-related death tolls for both natural and technological disasters that are further divided into sub-categories. Overall, we find evidence of a reduction effect of past disaster damage on future disaster damage. More detailed analyses show that an adaptation effect seems to be present for certain combinations of disaster types and levels of economic development. The results show that a country’s own experiences reduce future damage for natural disasters but that the marginal effect is larger for lower-income countries. On the other hand, for technological disasters, a robust impact of experiences was found only in higher-income countries. In terms of the disaster experiences of nearby countries, the adaptation effect was found only for natural disasters, and the marginal impact was relatively higher for higher-income countries.     

车排子凸起与沙湾凹陷过渡带的构造模型

车排子凸起位于准噶尔盆地扎伊尔山前,是夹持在南部四棵树凹陷和东部沙湾凹陷之间的三角构造带。然而对这个三角构造带是原地掩伏构造,山前推覆构造,还是走滑构造控制形成的认识存在争议。目前对于车排子凸起与沙湾凹陷过渡带的构造变形特征以及变形机制的认识尚不清楚。而过渡带是研究该区构造变形与演化的良好区域,精细研究该区域构造几何学与运动学对于揭示其构造变形机制以及认识盆山之间的关系具有积极作用,并对于该区油气勘探具有重要意义。本文以研究区的连片三维地震资料为基础,运用不整合面识别、轴面分析及平衡剖面等方法,对车排子凸起与沙湾凹陷过渡带进行精细的构造解析、建模与构造复原。研究表明,过渡带发育下二叠统（P₁j-P₁f）,中二叠统（P₂x-P₂w）,上二叠统（P₃w）,三叠系（T）,侏罗系（J）,白垩系（K）与古近系-第四系（E-Q）7个构造变形层序。发育佳木河组底部及石炭系内部滑脱层。深部（前二叠系）构造楔发育于整个过渡带,其个数和几何学形态的变化直接影响了上覆背斜形态。构造楔在早二叠世开始楔入,挤压作用持续至三叠纪末期。晚三叠世发育生长地层,显示了P-T构造层褶皱变形的时间,随后三叠纪末期,过渡带受到来自西北缘造山带方向的逆冲推覆构造的叠加作用,表现在后缘发育一系列叠瓦构造,推覆距离约为8 km,南部逆冲断层上盘二叠系-三叠系被剥蚀完全,北部残余少量下二叠统佳木河组。     

青海某地软玉的宝石学特征

青海软玉产于花岗岩与大理岩的内接触带。与和田玉、花莲玉相比，化学成分表现高ＣａＯ，低Ａｌ２Ｏ３、ＴＦｅ、Ｎａ２Ｏ等特点；矿物成分以透闪石为主，含少量白云石、滑石等，颜色多呈白色、淡绿色，赤有灰白、暗绿等色，油脂光泽，半透明至不透明，平均比重２．９４，平均硬度５．９５×１０８ｋｇ／ｍ２，折射率１．６２３～１．６２２。块度大、裂纹少，具良好的加工工艺性能。     

Preparation of iron phosphate from sludge sourced from the electrocoagulation treatment of source-separated urine

In order to prepare iron phosphate by waste sludge, we report a method for effective utilization of the sludge obtained from the electrocoagulation treatment of source-separated urine. The sludge was dissolved with hydrochloric acid and pretreated with H₂O₂ and Na₃PO₄; finally, NaOH was added to precipitate iron phosphate from the solution. Thermal treatment of the precipitate at 750 °C in air yielded crystalline quartz-like anhydrous FePO₄. The precipitate was characterized by a number of thermal techniques such as thermogravimetry/differential thermal analysis, scanning electron microscopy, and X-ray powder diffraction.