A hydrochemical approach to estimate mountain front recharge in an aquifer system in Tamilnadu,India

Mountain-front recharge (MFR) is a process of recharging an aquifer by infiltration of surface flow from streams and adjacent basins in a mountain block and along a mountain front (MF). This is the first attempt in India to estimate MFR along the foothills of Courtallam using hydrogeochemistry and geostatistical tools. The estimation of MFR has been carried out by collecting groundwater samples along the foothills of Courtallam. Collected water samples were analyzed for major cations and anions using standard procedures. Hydrogeochemical facies show the existence of four water types in this region. Calcium-rich water derived from gneissic rock terrain indicates significant recharge from higher elevation. Log pCO₂ and ionic strength of the samples were also calculated to identify the geochemical process. Majority of the collected samples have sodium-rich water and weak ionic strength, which indicate foothill recharge and low residence time. Silicate and carbonate weathering have an equal interplay along the foothills with a relatively large fraction of Mg from the MF. The spatial diagrams of three factors show that the southern part of the study area is dominated by both weathering and anthropogenic processes, whereas the northern part is dominated by both leaching and weathering processes. Thus, the dominant weathering process represented by the second factor indicates the large recharge process along the foothills.     

The GEF/UNDP/IMO Malacca Straits Demonstration Project: Sources of Pollution

The Straits of Malacca is subjected to a great variety of environmental stresses due to its strategic location as a major international shipping lane and the concentration of agriculture, industry and urbanisation which predominate on the west coast of Peninsular Malaysia. This paper gives an overview of the study conducted in the Malacca Straits as part of the GEF/UNDP/IMO Regional Programme on the Prevention and Management of Marine Pollution in the East Asian Seas, in particular pertaining to the identification of land and sea-based sources of pollution in Malaysia which contributes to the pollution load in the Straits, as well as the assessment of the relative contribution of each source.     

Performance of image classification on hyperspectral imagery for lithological mapping

SVM and SAM classifiers for the lithological mapping using Hyperion data in parts of Gadag schist belt of western Dharwar craton, Karnataka, India were used. The main objective of the present study is to assess and compare the potential use of Hyperion data set for lithological mapping. Accuracy assessment of the derived thematic maps was based on the analysis of the confusion matrix statistics computed for each classification map. For consistency, the same set of validation points were used in evaluating the accuracy of the lithological thematic maps produced. On the basis of the accuracy assessment results, it appears that SVM generally outperformed the SAM classifier in both OA accuracy and individual classes’ accuracies. OA accuracy and Kc for SVM is 96.93% and 0.9655, whereas for SAM it is 74.02% and 0.7085 respectively. SVM classification is the best in describing the spatial distribution and the cover density of each lithology, as was also indicated from the statistics of the individual class results. The individual class accuracy were also analyzed for the SVM and the result show that PA ranges from 87% to 100% and UA ranges from 91% to 100%, whereas for SAM ranges from 15% to 95%, and from 31% to 100% respectively. The SVM method could effectively classify and improve on the existing geological map for the Gadag schist belt (GSB) using hyperspectral data. The results could be validated through field visits. Therefore, it is concluded that hyperspectral remote sensing data can be efficiently used to improve existing maps, especially in areas where same rock types show variable degree of alteration over smaller spatial scales.     

Advanced oxidation of catechol in reverse osmosis concentrate generated in leather wastewater by Cu–graphite electrode

Reverse osmosis (RO) concentrate generated from tannery was treated by advanced electrochemical oxidation using graphite electrodes. Catechol was selected as model organic pollutant in the RO concentrate. The influence of applied current density, catechol concentration, pH, temperature and inner electrode space of electrodes was investigated in electrochemical oxidation system. The optimized conditions were found to be current density (j), 100 mA/cm²; electrolysis time (t _eco), 60 min; pH, 7.0; and temperature, 25 °C at an inner electrode space, 2 cm. The average mass transport coefficient for the removal of catechol as COD was found to be 3.0 × 10^?5 m/s at optimum conditions. Faradic efficiency and specific energy consumption were also calculated for the applied current density. Further, the treatment of catechol was confirmed through Fourier transform infrared spectroscopy. Theoretical evaluation of current density suggested that the removal of catechol was controlled when supplied at above limiting applied current densities and mass transport controlled at lower of limiting current densities.     

Devaluation of female work participation with urbanization: a case of peri-urban Ahmedabad

GeoJournal - Urban expansion of the Indian metropolitan cities has reached the rural peripheries. There have been social, economic, and environmental consequences of this process of...     

Weathering and landslide occurrences in parts of Western Ghats,Kerala

The climatic condition of Western Ghats has influenced the process of weathering and landslides in this mountainous tract along the southwest coast of India. During the monsoon period, landslides are a common in the Western Ghats, and its intensity depends upon the thickness of the loose unconsolidated soil formed by the process of weathering. Debris landslides with a combination of saprock, saprolite and soil, indicate the role of weathering in landslide occurrences. This paper reports on how the weathering in the windward slope of Western Ghats influences the occurrence of landslides and the factors which accelerate the weathering process. Rock and soil samples were collected from the weathering profile of hornblende gniess and granite gneiss. The chemical analysis and the calculated Chemical Index of Alteration (CIA) indicate the significant weathering and its possible influence on landslide occurrences in the study area. Mainly, the CIA value of lateritic soil and forest loam indicated the extent of high chemical weathering in this region. Rainfall is the dominant parameter influencing the chemical weathering process. In addition, deforestation, land use practices and soil erosion are some of the other important factors accelerating the weathering process and landslide occurrences in the region. The locations of the previous landslides superimposed on geology and soil show that most of the landslide occurrences are associated with the highly weathered zone, particularly lateritic soil and the ‘severe’ (rock outcrop) erodability zone.     

Sorption of Cesium on Clay Colloids: Kinetic and Thermodynamic Studies

Sorption of radionuclides onto stable colloids can significantly enhance their transport in groundwater. Batch adsorption studies were performed to evaluate the influence of various experimental parameters like initial pH, contact time, temperature and concentration of Na⁺ and Ca²⁺ ions on the sorption of Cs on clay. The sorption process is dependent on pH of the solution with distribution coefficient (K _d) found to increase with increase in pH. The kinetic experiments were carried out at different temperatures, and the results have shown that the sorption process fits well into a pseudo-second-order mechanism with apparent activation energy of 45.7?kJ/mol. The rate constant was found to decrease with increase in temperature. The thermodynamic parameters such as ?G ⁰, ?H ⁰ and ?S ⁰ were calculated. The negative value of ?H ⁰ indicates that the reaction is exothermic. The negative values obtained for ?G ⁰ indicated that the sorption of cesium on clay was spontaneous at all studied concentrations. The distribution coefficient was found to decrease with increasing concentration of Na⁺ and Ca²⁺ ions. The cesium sorption data were fitted to Freundlich, Langmuir, Temkin and Dubinin–Radushkevich (D–R) isotherms. The values of Langmuir separation factor (R _L) indicate a favorable Cs adsorption. The values of mean free energy of sorption (E) at various temperatures ranged from 10.5 to 11.1?kJ/mol, which indicates that the sorption process follows chemisorption.     

A composite fall-slippage model for cliff recession in the sedimentary coastal cliffs

A composite fall-slippage model is proposed in this study for the Tertiary sedimentary coastal cliffs of Varkala in the western coastal tract of Peninsular India which are retreating landwards due to the combination of several factors. The fall model in the present study accounts both spring seepage and wave action, resulting in undercutting and this fall affects only the topmost laterite and the just below sandstone in the cliff. Slippage in this area affects all the litho-units and hence the geologic characteristics of all the litho-units are considered for developing the slippage model. This mathematically derived model can be used in other cliffs exhibiting the same morphology as well as the one controlled by the same influencing factors. This model differs from other models in incorporating multi-lithounits as well as multi-notches. Varkala cliffs form a part of the aspiring geopark in the Global Geopark Network and hence a study on the cliff recession is a pressing requirement.