Water-Soluble dicarboxylic acids, ketoacids and dicarbonyls in the atmospheric aerosols over the southern ocean and western pacific ocean

Water-soluble dicarboxylic acids (DCAs), ketoacids, and α-dicarbonyls in the marine aerosol samples collected over the Southern Ocean and western Pacific Ocean were determined. Oxalic acid was the most abundant species, followed by malonic acid and then succinic acid. It is suggested that aerosol concentrations of the organics over the Southern Ocean in this work represent their global background levels. Over the Southern Ocean, total concentrations of DCAs ranged from 2.9 to 7.2 ng m⁻³ (average: 4.5 ng m⁻³), ketoacids from 0.14 to 0.40 ng m⁻³ (av.: 0.28 ng m⁻³), and dicarbonyls from 0.06 to 0.29 ng m⁻³ (av.: 0.11 ng m⁻³). Over the western Pacific, total concentrations of DCAs ranged from 1.7 to 170 ng m⁻³ (av.: 60 ng m⁻³), ketoacids from 0.08 to 5.3 ng m⁻³ (av.: 1.8 ng m⁻³), and dicarbonyls from 0.03 to 4.6 ng m⁻³ (av.: 0.95 ng m⁻³). DCAs over the western Pacific have constituted a large fraction of organic aerosols with a mean DCAs-C/TC (total carbon) of 7.0% (range: 0.59–14%). Such a high value was in contrast to the low DCAs-C/TC (av.: 1.8%; range: 0.89–4.0%) for the Southern Ocean aerosols. Based on the relative abundances and latitudinal distributions of these organics, we propose that long-range atmospheric transport is more important over the western Pacific Ocean, in contrast, in situ photochemical production is more significant over the Southern Ocean although absolute concentrations of the organics are much lower.     

Determination of three-dimensional in situ stresses from anelastic strain recovery measurement of cores at great depth

In order to examine whether the anelastic strain recovery (ASR) method can be applied for determining the in situ stress in hard rocks at great depths, the anelastic strain recovery of oriented cores was measured in six independent directions. The core specimens were taken from four depths within the range of about 2400–4500 m MD at the METI Niitsu well in Japan; the rock materials were mudstone, dolerite, basalt and andesite. For all the rocks the expansional anelastic strains were obtained, the magnitude of the strains in various directions continuously measured for 1 or 2 weeks was of the order of 1000 × 10^− 6 in mudstone; in contrast, strains of the other cores did not exceed a few hundred microstrains. These strains were used for a three-dimensional analysis of the principal in situ stresses. At the third depth, the principal stress directions were considered to be affected by fractures pre-existing near the core, and showed the features of a very local stress state. With the exception of this data, the directions determined by the ASR method were in agreement with those determined using other in situ measurement methods. Based on two assumptions, i.e., (i) the rock stress in vertical direction is equal to density-related gravitational overburden stress, (ii) the ratio of anelastic strain recovery compliance of shear deformation mode and the compliance of volumetric deformation mode is equal to 2, the values of the three principal stresses were estimated. The values of the minimum principal stress in the plane perpendicular to the well axis determined in this study were in agreement with those determined based on extended leak-off tests (ELOT or XLOT) conducted at the same well. Therefore, it can be said that the ASR method is well suited for use in directly determining the directions of principal in situ stresses in three dimensions and in estimating the magnitude of the stresses in isotropic rocks at great depths, such as those encountered when drilling deep into a submarine seismogenic zone.     

Dynamic tensile cracking in slopes possibly induced by Rayleigh surface waves

The 1978 Miyagi-ken-oki earthquake generated crack openings in fill slopes in Sendai, Japan. Although the slopes were reinforced with steel pipe piles after this event, tensile cracking was induced again in the same slopes by the 2011 off the Pacific coast of Tohoku earthquake. This clearly indicates conventional countermeasures against dynamic slope failures, usually based on body wave interaction with slopes, are not always effective. Considering that similar open cracks in the top surfaces of slopes were also found in New Zealand and California, we may need to clarify the generation mechanism of such cracks with some new insights. Recently, it has been indicated that the effect of Rayleigh surface wave propagation on dynamic slope stability may become significant. In this contribution, therefore, by performing two-dimensional elastodynamic analyses of Rayleigh/body wave interaction with a geometrically simple model slope, we show Rayleigh waves may play a more dominant role than body waves in generating the open cracks, and emphasise the importance of taking into account the dynamic slope failures induced by Rayleigh waves. Surface waves may be produced also by nearby blasting, etc., and therefore, the results obtained here may be of crucial importance in comprehending the dynamic stability of slopes in general.     

Non-monotonic optimal damper placement via steepest direction search

An efficient and systematic procedure is proposed for finding the optimal damper positioning to minimize the dynamic compliance of a 3-D shear building model. The dynamic compliance is expressed in terms of the transfer function amplitudes of the local interstorey drifts evaluated at the undamped fundamental natural frequency. The dynamic compliance is minimized subject to a constraint on the sum of the damping coefficients of added dampers. Optimality criteria are derived and the optimal damper positioning is determined via an original steepest direction search algorithm. This algorithm enables one to find an optimal damper positioning sequentially for gradually increasing damper capacity levels. A non-monotonic design path with respect to the total damper capacity level often appears in the application of this algorithm. A new augmented algorithm via parameter switching is devised to find this non-monotonic design path. Copyright © 1999 John Wiley & Sons, Ltd.     

Standing stocks and production rates of phytoplankton and abundance of bacteria in the Seto Inland Sea, Japan

Standing stocks and production rates of phytoplankton and abundance of bacteria were investigated at 39 stations in the Seto Inland Sea, Japan during four crulses in October 1993, January, April and June 1994. Primary productivity was measured by the¹³C tracer method. Photosynthetic rate varied from 0.41 to 32.1 μgC/1/h with an average value of 4.67 μgC/l/h. Annual primary production was estimated to be 218 gC/m²/year. Annual primary production in this study was 1.8 times as high as the values which were previously reported at same area. The reason for the disagreement between our primary production value and previous values is not thought to be due to the difference of methods used for measuring primary production or the different Chl.a concentrations but to the method of estimating the primary production in the euphotic zone from thein vitro measurements. The distribution of bacterial cells in surface seawater was examined during the same cruises. Bacterial cell density ranged from 0.32 to 3.4×10⁶ cells/ml. The density was relatively high in the eutrophic regions of Hiroshima Bay and Osaka Bay In addition, a high density of bacteria was also observed in an area within Suo Nada where Chl.a was relatively low. The disparity between Chla and bacterial density in Suo Nada suggests that bacterial abundance can be controlled by the availability of substrates other than phytoplankton exudate.     

A quadratic element method for evaluating groundwater flow by the inversion of surface tilt with application to the Tono Area, Japan

By modifying a previous method with constant elements, we developed a quadratic element method for more accurately estimating groundwater flow by the inversion of tilt data. In this method: (1) a region of groundwater flow is divided into quadratic elements in which the change in groundwater volume per unit volume of rock (Δv) and the Skempton coefficient (B) vary in a quadratic manner with the coordinates, (2) the values of Δv are set to zero at the boundaries of the region of groundwater flow and (3) the sum of the squared second derivatives of Δv is adopted as a constraining condition that is weighted and added to the sum of the squared errors in tilt. First, analyses were performed for a flow model to determine the accuracy of this method for estimating groundwater flow and also to clarify the effect of the assumed size of a region of groundwater flow. These analyses showed that the quadratic element method proposed in this study gives a much better estimation of Δv than the constant element method and that a large region of groundwater flow should be assumed, rather than a small region, since the values of Δv at points outside of the actual region of groundwater flow are estimated to be nearly zero when a large region is assumed while these values are greatly overestimated when an excessively small region is assumed. Finally, the quadratic element method was applied to the site of the Mizunami Underground Research Laboratory in the Tono area, Japan. Inverse analyses were performed for tilt data measured by four tiltmeters with a resolution of 10⁻⁹ radians during the excavation of two shafts under the assumption that the rock mass is an isotropic and homogeneous half- space. The results showed that the method proposed in this study reproduced the tilt data very accurately. Thus, the distribution of Δv was estimated without sacrificing the reproducibility of the tilt data. The contour maps of B(1 + ν)Δv (ν: Poisson’s ratio) showed that the heterogeneous flow of groundwater occurred at the site and that groundwater volume decreased mainly in the area surrounded by two faults. The latter result is consistent with the finding obtained by previous investigations that these faults have low permeability in the direction perpendicular to the strike and may act as a flow barrier.     

Basin-scale distribution of NH<Subscript>4</Subscript><Superscript>+</Superscript> and NO<Subscript>2</Subscript><Superscript>−</Superscript> in the Pacific Ocean

We used more than 25,000 nutrient samples to elucidate for the first time basin-scale distributions and seasonal changes of surface ammonium (NH₄ ⁺) and nitrite (NO₂ ^?) concentrations in the Pacific Ocean. The highest NH₄ ⁺, NO₂ ^?, and nitrate (NO₃ ^?) concentrations were observed north of 40°N, in the coastal upwelling region off the coast of Mexico, and in the Tasman Sea. NH₄ ⁺ concentrations were elevated during May–October in the western subarctic North Pacific, May–December in the eastern subarctic North Pacific, and June–September in the subtropical South Pacific. NO₂ ^? concentrations were highest in winter in both hemispheres. The seasonal cycle of NH₄ ⁺ was synchronous with NO₂ ^?, NO₃ ^?, and satellite chlorophyll a concentrations in the western subtropical South Pacific, whereas it was synchronous with chlorophyll-a but out of phase with NO₂ ^? and NO₃ ^? in the subarctic regions.     

Escape from a Crisis in Fokker-Planck Models

Recent N-body simulations have shown that there is a serious discrepancy between the results of N-body simulations and the results of Fokker-Planck simulations for the evolution of globular and rich open clusters under the influence of the galactic tidal field. In some cases, the lifetime obtained from Fokker-Planck calculations is more than an order of magnitude smaller than those from N-body simulations. In this paper we show that the principal cause for this discrepancy is an over-simplified treatment of the tidal field used in previous Fokker-Planck simulations. We performed new Fokker-Planck calculations using a more appropriate implementation for the boundary condition of the tidal field. The implementation is only possible with anisotropic Fokker-Planck models, while all previous Fokker-Planck calculations rely on the assumption of isotropy. Our new Fokker-Planck results agree well with N-body results. Comparison of the two types of simulations gives a better understanding of the evolution of such clusters. This revised version was published online in July 2006 with corrections to the Cover Date.     

Modeling Local Tidal Constituents Using TOPEX/POSEIDON SSH for the Malaysian Marine Region

A new Local Ocean Tide Model, has been produced for the Exclusive Economic Zone (EEZ) of Malaysia, which incorporates some of the latest TOPEX/POSEIDON data for the years 1992 to 1998. Local tide gauge data are used as a comparison, along with another leading Global Ocean Tide Model, Ori96. The leading diurnal and semidiurnal constituents M₂, S₂, N₂, K₁, O₁, P₁ and Q₁ are reproduced using TOPEX/POSEIDON Sea Surface Heights (SSH) in a response analysis type least squares derivation following Munk and Cartwright (1966).