Identifying Groundwater Potential in Crystalline Basement Rocks Using Remote Sensing and Electromagnetic Sounding Techniques in Central Western Mozambique

Exploring for groundwater in crystalline rocks in semiarid areas is a challenge because of their complex hydrogeology and low potential yields. An integrated approach was applied in central western Mozambique, in an area covered by Precambrian crystalline basement rocks. The approach combined a digital elevation model (DEM), remote sensing, and a ground-based geophysical survey. The aim was to identify groundwater zones with high potential and to identify geological structures controlling that potential. Lineaments were extracted from the DEM that had been enhanced using an adaptive-tilt, multi-directional, shading technique and a non-filtering technique to characterize the regional fracture system. The shallowness and amount of stored groundwater in the fracture zones was assessed using vegetation indices derived from Landsat 8 OLI images. Then, 14 transient electromagnetic (TEM) survey profiles were taken in different geological settings across continuous lineaments that were considered to be aligned along inferred faults. In the central lineament zones, the TEM soundings gave resistivity values of less than 300 Ωm at a depth of 20–80 m. The values varied with location. Conversely, values greater than 400 Ωm were observed at the sites away from the central zones. This contrast is probably caused by the differences in permeability and degree of weathering along the fractured zones. These differences could be key factors in determining groundwater occurrence. By integrating five water-related factors (lineament density, slope, geology, vegetation index, and proximity to lineaments), high groundwater potential zones were located in the vicinity of the lineaments. In these zones, vegetation remains active regardless of the season.     

Tidal effect on dynamics of pore water nitrate in intertidal sediment of a eutrophic Estuary

To evaluate the effect of the tidal cycle on the pore water nitrate dynamics in intertidal sediment, concentrations of inorganic nitrogen in water and sediment were monitored during tidal cycles in the mud flat of Tama Estuary, Japan. During submergence, nitrate concentration was highest in the overlying water and decreased monotonically with increasing depth in the sediment, suggesting that the primary source of nitrate in the sediment was nitrate transported from the overlying water. Pore water nitrate decreased remarkably during the initial 3–4 hours after the onset of exposure. Thereafter, it was constant or slightly increased until tidal flooding.In situ accumulation of nitrate at the end of exposure, however, did not exceed the nitrate concentrations in the overlying water. The inhibition of nitrate reduction and the stimulation of nitrification would explain the change of nitrate concentration, both consistent with the input of oxygen into the sediment following a 10 mm drop of the water table. In Tama Estuary sediments, the effect of the tidal cycle on the removal of combined nitrogen is rather negative, because high nitrate concentrations in the overlying water canceled the positive effect of nitrate accumulation by nitrification during exposure, while tidal oxygen intrusion have an inhibitory effection sedimentary denitrification.     

Correction of atmospheric effect on ADEOS/OCTS ocean color data: Algorithm description and evaluation of its performance

This paper first describes the atmospheric correction algorithm for OCTS visible band data used at NASDA/EOC. Sharing a basic structure with Gordon and Wang’s Sea WiFS algorithm, it uses 10 candidate aerosol models including the “Asian dust model” introduced in consideration of the unique feature of aerosols over the east Asian waters. Based on the observations at 670 and 865 nm bands, the algorithm selects a pair of aerosol models that account best for the observed spectral reflectances, and synthesizes the aerosol reflectance used for the atmospheric correction. Two different schemes for determining the value of the parameter for the aerosol model selection are presented and their anticipated estimation error is analyzed in terms of retrieved water reflectance at 443 nm. The results of our numerical simulation show that the standard deviation of the estimation error of the “weighted average” scheme is mostly within the permissible level of ±0.002, reducing the error by 18% on average compared to the “simple average” scheme. The paper further discusses the expected error under the old CZCS-type atmospheric correction, which assumes constant aerosol optical properties throughout the given image. Although our algorithm has a better performance than the CZCS algorithm, further analysis shows that the error induced by the assumption taken in the algorithm that the water-leaving radiance at 670 nm band is negligibly small may be large in high pigment concentration waters, indicating the necessity for future improvements.     

Determination of Zirconium, Niobium, Hafnium and Tantalum at ng g-1 Levels in Geological Materials by Direct Nebulisation of Sample HF Solution into FI-ICP-MS

We have developed a rapid and accurate method to determine Zr, Nb, Hf and Ta (denoted as HFSE) in geological samples by inductively coupled plasma-mass spectrometry fitted with a flow injection system (FI-ICP-MS). The method involves sample decomposition by HF followed by HF dissolution of HFSE coprecipitated with insoluble M and Ca fluoride residues formed during the initial HF attack. This HF solution was directly nebulized into an ICP mass spectrometer. An external calibration curve method and an isotope dilution method (ID) were applied for the determination of Nb and Ta, and of Zr and Hf, respectively. Recovery yields of HFSE were > 96% for peridotite, basalt and andesite compositions, apart from Zr and Hf for peridotite (> 85%). No matrix effects for either signal intensities of HFSE or isotope ratios of Zr and Hf were observed in basalt, andesite and peridotite solutions down to a dilution factor of 100. Detection limits in silicate rocks were 40, 2, 1 and 0.1 ng g-1 for Zr, Nb, Hf and Ta, respectively. This technique required only 0.1 ml of sample solution, and thus is suitable for analysing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates. We also present newly determined data for the Zr, Nb, Hf and Ta concentrations in USGS silicate reference materials DTS-1, PCC-1, BCR-1, BHVO-1 and AGV-1, GSJ reference materials JB-1, -2, -3, JA-1, -2 and -3, and the Smithsonian reference Allende powder.     

Current Nature of the Kuroshio in the Vicinity of the Kii Peninsula

The Kuroshio flows very close to Cape Shionomisaki when it takes a straight path. The detailed observations of the Kuroshio were made both on board the R/V Seisui-maru of Mie University and on board the R/V Wakayama of the Wakayama Prefectural Fisheries Experimental Station on June 11–14, 1996. It was confirmed that the current zone of the Kuroshio touches the coast and bottom slope just off Cape Shionomiaki, and that the coastal water to the east of the cape was completely separated from that to the west. The relatively high sea level difference between Kushimoto and Uragami could be caused by this separation of the coastal waters when the Kuroshio takes a straight path. This flow is rather curious, as the geostrophic flow, which has a barotropic nature and touches the bottom, would be constrained to follow bottom contours due to the vorticity conservation law. The reason why the Kuroshio leaves the bottom slope to the east of Cape Shionomisaki is attributed to the high curvature of the bottom contours there: if the current were to follow the contours, the centrifugal term in the equation of motion would become large and comparablee to the Coriolis (or pressure gradient) term, and the geostrophic balance would be destroyed. This creates a current-shadow zone just to the east of the cape. As the reason why the current zone of the Kuroshio intrudes into the coastal region to the west of the cape, it is suggested that the Kii Bifurcation Current off the southwest coast of the Kii Peninsula, which is usually found when the Kuroshio takes the straight path, has the effect of drawing the Kuroshio water into the coastal region. The sea level difference between Kushimoto and Uragami is often used to monitor the flow pattern of the Kuroshio near the Kii Peninsula. It should be noted that Uragami is located in the current shadow zone, while Kushimoto lies in the region where the offshore Kuroshio water intrudes into the coastal region. The resulting large sea level difference indicates that the Kuroshio is flowing along the straight path.     

Seasonal dynamics influencing coastal primary production and phytoplankton communities along the southern Myanmar coast

Myanmar is tenth among the world’s fish-producing countries and third in ASEAN (Association of Southeast Asian Nations). To understand the mechanisms underlying the high production, oceanographic and phytoplankton surveys, including primary productivity measurements based on pulse amplitude modulation fluorometry, were conducted near an active fishing ground near Myeik City. Three surveys, one in each of the representative seasons and covering the characteristic coastal environments, showed well-defined seasonality in primary production and phytoplankton occurrence. End of the dry season was the most productive, with productivity of 2.59 ± 1.56 g C m^?2 day^?1 and high concentration of chlorophyll a (3.14 ± 2.64 µg L^?1). In this season, the phytoplankton population was dominated by high densities of the diatoms Bellerochea horologicalis and Chaetoceros curvisetus, whereas primary productivity was low at the onset of the dry season, 1.36 ± 0.77 g C m^?2 day^?1. However, this low primary production might be compensated by activation of microbial food chains originating from high dissolved organic carbon. The rainy season exhibited the lowest production, 6.6% of the end of the dry season, due to the extensive discharge of turbid water from the rivers which lowered euphotic layer depth and resulted in an unusually high diffuse attenuation coefficient of 2.30 ± 1.03 m^?1. This incident of turbid water may be related to soil erosion from deforestation and mangrove deterioration. This research reveals the seasonal trend in Myanmar’s coastal productivity and its relationship to the tropical monsoon climate as well as emphasizing the importance of tropical coastal environments to the sustainability of the fisheries.     

Long-term change and variation of salinity in the western North Pacific subtropical gyre revealed by 50-year long observations along 137°E

The 137°E repeat hydrographic section for 50 winters during 1967–2016 has been analyzed to examine interannual to interdecadal variations and long-term changes of salinity and temperature in the surface and intermediate layers of the western North Pacific, with a particular focus on freshening in the subtropical gyre. Rapid freshening on both isobars and isopycnals began in the mid-1990s and persisted for the last 20 years in the upper main thermocline/halocline in the western subtropical gyre. In addition, significant decadal variability of salinity existed in the subtropical mode water (STMW), as previously reported for the shallower layers. An analysis of the 144°E repeat hydrographic section during 1984–2013 supplemented by Argo profiling float data in 2014 and 2015 revealed that the freshening trend and decadal variability observed at 137°E originated in the winter mixed layer in the Kuroshio Extension (KE) region and was transmitted southwestward to 137°E 1–2 years later in association with the subduction and advection of STMW. The mechanism of these changes and variations in the source region was further investigated. In addition to the surface freshwater flux in the KE region pointed out by previous studies, the decadal KE variability in association with the Pacific Decadal Oscillation likely contributes to the decadal salinity variability through water exchange between the subtropics and the subarctic across the KE. Interdecadal change in both the surface freshwater flux and the KE state, however, failed to explain the rapid freshening for the last 20 years.     

Decadal seesaw of the Central and Subtropical Mode Water formation associated with the Kuroshio Extension variability

Available Argo profiling float data from 2002 to 2011 were analyzed to examine the effect of the Kuroshio Extension (KE) current system variability on the formation of the Central Mode Water. Just north of the upstream portion of the KE at 140–152°E, formation of a lighter variety of the Central Mode Water in winter was active during the unstable period of the upstream KE in 2006–2009 and was reduced when the upstream KE was in the stable period of 2002–2005 and 2010–2011. This decadal formation variability is out of phase with that of the Subtropical Mode Water just south of the KE.     

SAR- and gravity change-based characterization of the distribution pattern of pyroclastic flow deposits at Mt. Merapi during the past 10 years

Mt. Merapi, Indonesia, is one of the most active and dangerous volcanoes in the Torrid Zone. This volcano has erupted frequently and has produced pyroclastic flows following the collapse of the summit lava dome. We used Synthetic Aperture Radar (SAR) data acquired by JERS-1 and RADARSAT-1 satellites from April 1996 to July 2006 to clarify the distribution patterns of the pyroclastic flow deposits. The extent of the deposits, termed P-zones, was accurately extracted by ratio operation and low-level feature extraction from SAR intensity images. These images highlighted temporal changes of the distribution area, perimeter, flow distance, included angle, and collapse direction. To validate the image-processing results, reflectance spectra of the rock samples collected after the eruption in June 2006 were measured in a laboratory. The reflectance spectra of all samples showed similar characteristics to the reference spectra, which were derived from atmospheric correction of Hyperion sensor image data covering the lava dome at the summit. Therefore, P-zones were confirmed to be the pyroclastic flow deposits originating from destruction of the lava dome at the summit. The image-processing results clarified that the extent of the distribution areas, perimeter, flow distances, and included angle of the P-zones were variable among the eruptions, while the collapse direction had a constant pattern. The collapse pattern followed a clockwise change from the south toward the west. By comparing the ratio maps of Bouguer gravity anomaly data in two periods, the change was interpreted to originate from the inclination of the conduit and the formation of shallow and deep magma reservoirs.     

Holocene paleolimnological changes in Lake Skallen Oike in the Syowa Station area of Antarctica inferred from organic components in a sediment core (Sk4C-02)

Antarctic climate changes influence environmental changes at both regional and local scales. Here we report Holocene paleolimnological changes in lake sediment core Sk4C-02 (length 378.0 cm) from Lake Skallen Oike in the Soya Kaigan region of East Antarctica inferred from analyses of sedimentary facies, a range of organic components, isotope ratios of organic carbon and nitrogen, and carbon-14 dating by Tandetron accelerator mass spectrometry. The sediment core was composed of clayish mud (378.0–152.5 cm) overlain by organic sediments (152.5 cm-surface). The age of the surface and the core bottom were 150 (AD1950-1640) and ca. 7,030 ± 73 calibrated years before present (cal BP), respectively, and the mean sedimentation rate was estimated to be 0.55 mm/year. Multi-proxy analyses revealed that the principal environmental change in the core is a transition from marine to lacustrine environments which occurred at a depth of 152.5 cm (ca. 3,590 cal BP). This was caused by relative sea level change brought about by ongoing retreat of glaciers during the mid-Holocene warming of Antarctica, and ongoing isostatic uplift which outpaced changes in global (eustatic) sea level. The mean isostatic uplift rate was calculated to be 2.8 mm/year. The coastal marine period (378.0–152.5 cm, ca. 7,030–3,590 cal BP) was characterized by low biological production with the predominance of diatoms. During the transition period from marine to freshwater conditions (152.5-approximately 135 cm, ca. 3,590–3,290 cal BP) the lake was stratified with marine water overlain by freshwater, with a chemocline and an anoxic (sulfidic) layer in the bottom of the photic zone. Green sulfur bacteria and Cryptophyta were the major photosynthetic organisms. The Cryptophyta appeared to be tolerant of the moderate salinity and stratified water conditions. The lacustrine period (approximately 135 cm-surface, ca. 3,290 cal BP-present) was characterized by high biological production by green algae (e.g. Comarium clepsydra and Oedegonium spp.) with some contributions from cyanobacteria and diatoms. Biological production during this period was 8.7 times higher than during the coastal marine period.