Influence of surface and vegetation characteristics on C-band radar measurements for soil moisture content

Soil moisture estimation using microwave remote sensing faces challenges of the segregation of influences mainly from roughness and vegetation. Under static surface conditions, it was found that Radarsat C-band SAR shows reasonably good correlation and sensitivity with changing soil moisture. Dynamic surface and vegetation conditions are supposed to result in a substantial reduction in radar sensitivity to soil moisture. A C-band scatterometer system (5.2 GHz) with a multi-polarization and multi-angular configuration was used 12 times to sense the soil moisture over a tall vegetated grass field. A score of vegetation and soil parameters were recorded on every occasion of the experiment. Three radar backscattering models Viz., Integral Equation Model (IEM), an empirical model and a volume scattering model, have been used to predict the backscattering phenomena. The volume scattering model, using the Distorted Born Approximation, is found to predict the backscattering phenomena reasonably well. But the surface scattering models are expectedly found to be inadequate for the purpose. The temporal variation of soil moisture does show good empirical relationship with the observed radar backscattering. But as the vegetation biomass increases, the radar shows higher sensitivity to the vegetation parameters compared to surface characteristics. A sensitivity analysis of the volume scattering model for all the parameters also reveals that the radar is more sensitive to plant parameters under high biomass conditions, particularly vegetation water content, but the sensitivity to surface characteristics, particularly to soil moisture, is also appreciable.     

Oxygen and Carbon Isotope Study of Calcite and Dolomite in the Disseminated Au-Ag Telluride Bulawan Deposit, Negros Island, Philippines

Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ¹⁸O and δ¹³C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ¹⁸O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ¹³C values range from ‐6.1 to ‐1.0%. The δ¹⁸O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ¹³C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ¹⁸O and δ¹³C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ¹⁸O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ¹⁸O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and ¹⁸O‐enriched fluids which reacted with ¹⁸O‐ and ¹³C‐rich wallrocks such as limestone.     

Assessment of the Uncertainties in the NO2 and O3 Measurements by Visible Spectrometers

The column amounts of nitrogen dioxide (NO2) and ozone (O3) were measured using a visible spectrometer based on the twilight zenith-sky technique at two observatories located at similar latitudes in the northern part of Japan separated by a distance of 150 km. The measurements began in April 1991 at the Moshiri Observatory (44.4°N, 142.3°E) and in April 1994 at the Rikubetsu Observatory (43.5°N, 143.8°E). Since weather conditions and the possible influence from tropospheric pollution were not always identical at these two observatories, the overall accuracy of the measurements was studied comparing these data sets. The first year data obtained at a solar zenith angle of 90 degrees indicated that the NO2 slant column values at sunrise and sunset agreed within 0.36 and 0.54 × 1016 cm-2, respectively, corresponding to 5 % (June) and to 12 % (December) of the columns. The O3 values agreed within 0.76 × 1019 cm-2, corresponding to 4 % (March) 6 % (August) of the columns, although a part of the difference was systematic. The O3 column amounts were also compared to those obtained by the Dobson spectrometer at Sapporo (43.5°N, 143.8°E), whose latitude is similar to these observatories. When an air mass factor of 17.5 was used, the two-year Moshiri vertical column values agreed with the Dobson direct sun values to within 15 Dobson Units, or 3 6 % of the column. The difference between the two values was found to be due partly to the change in the air mass factor caused by seasonal and day-to-day changes in the shape of the O3 vertical profiles. These results confirm the reliability of the NO2 and O3 measurements by visible spectrometers at these sites for the Network for the Detection of Stratospheric Change (NDSC).     

藏北高原D110点不同季节土壤温度的日变化特征

利用１９９８年ＧＡＭＥ－Ｔｉｂｅｔ加强观测期间取得的一个年周期的土壤温度资料,对藏北高原Ｄ１１０点土壤温度日变化特征的月际变化进行了分析。结果表明,在夏半年（５－９）月土壤温度存在明显的日变化,且基本上按正弦曲线变化,但相位随深度的增加而滞后;冬半年土壤温度尽管也存在日变化,但变幅较小。     

Climato-limnological signals during the past 260 000 years in physical properties of bottom sediments from Lake Baikal

The St.16 core obtained from the Academician Ridge of Lake Baikal in eastern Siberia may span about 260 000 years, and some physical properties of the core samples are closely related to aquatic paleoproductivity and climatic change. The median of grain size, grain density, and water content fluctuate synchronously. They also are connected with change in the abundance of biogenic silica (diatoms). The physical parameters indicate that there were high aquatic productivity periods around interglacial periods (MIS 5 and 7; 70 000-125 000 yr B.P. and 180 000-250 000 yr B.P.). Comparatively large clastics were transported from outside of the lake through various routes (ice rafting, etc.) in addition to fluvial routes during the glacials or 'stadials. There are ca. 20 000 yr, 40 000 yr and 100 000 yr periods in the variations of physical properties. These are related to the three Milankovitch parameters of solar insolation.     

Age model, physical properties and paleoceanographic implications of the middle Pleistocene core sediments in the Choshi area, central Japan

Abstract   A continuous, well-preserved core was obtained from the Choshi area, on the Pacific side of Japan, to investigate paleoceanographic and paleoclimatic changes around the northwestern Pacific region during the middle Pleistocene. Siliciclastic sequences in the core are divided into five formations – the Obama, Yokone, Kurahashi and Toyosato Formations in the Inubo Group and the Katori Formation, in ascending order. Examination of calcareous nannofossils and magnetic polarities detected four datums in the core sediments of the Inubo Group: the top of Reticulofenestra asanoi , the base of Helicosphaera inversa , the top of Pseudoemiliania lacunosa and the Brunhes–Matuyama boundary. Fourteen marine isotope stages (MIS24–MIS11) were identified in the δ¹⁸O and δ¹³C records based on detected datums and the graphic correlation with the standard stack oxygen isotope curve. Magnetic susceptibility and gamma-ray attenuation porosity evaluator density were also measured and low values characterize the glacial intervals. Biogenic sedimentation by primary production may be larger during the glacial periods because of invasions of nutrient-rich northern surface-waters related to the southward shift of the Kuroshio front in the Choshi area.     

Geology, Mineralogy, and Formation Environment of the Disseminated Gold-Silver Telluride Bulawan Deposit, Negros Occidental, Philippines

Abstract: The Bulawan deposit is located in the porphyry copper belt of southwest Negros island, Philippines. Propylitic, K–feldspar, sericitic, and carbonate alteration types can be distinguished in the deposit. Propylite alteration occurs mainly in Cretaceous-Eocene andesitic lavas and agglomerates while K–feldspar, sericite and carbonate alteration types occur mostly in the Middle Miocene dacite porphyry breccia pipes and stocks which were intruded into the andesites. K-feldspar zones occur in the inner parts of the sericitized zone. Sericite alteration overprinted the propylitized and K-feldspar alteration zones, at lower temperature than epidote and chlorite in the propylitized zone. Carbonate alteration is associated with the mineralization in the center of the breccia pipes and along faults. Mineralization consists of gold-silver telluride ores that are hosted by the carbonate– and sericite-altered dacite porphyry breccia pipes. The Bulawan ores occur mainly as disseminations, but unlike many epithermal gold deposits, lack classical epithermal colloform and crustiform quartz veins. The ore minerals are sphalerite, galena, chalcopyrite, pyrite and tetrahedite-tennantite with minor amounts of electrum, calaverite, petzite, sylvanite, hessite, tellurobismuthite, coloradoite, altaite, and rucklidgeite. Electrum and telluride minerals are associated mostly with calcite and dolomite-ankerite minerals. Fluid inclusions in quartz and calcite in clasts of propylitized andesite in the breccia pipes homogenize from about 300° to 400°C while fluid inclusions in quartz, calcite and sphalerite within the dacite porphyry breccia pipes homogenize between 300° to 310°C. The ores were formed around 300°C from hydrothermal solutions with salinity of about 6. 6 wt % NaCl equivalent. The presence of sylvanite and calaverite as intergrowths with each other, and the Ag content of calaverite are consistent with the above temperature estimate. Based on paragenesis, the Bulawan deposit formed in a pyrite-stable environment, with pH between 3. 4 and 5. 5, f_O2 between 10^-32 to 10^-30 atm, f_S2 between 10^-9.8 to 10^-7.8 atm, f_Te2 between 10^-8.9 to 10^-6.5 atm, and total sulfur content about 10^-2.8 molal. The dominant reduced sulfur species in the ore solutions may have been H₂S_(aq), and the likely aqueous tellurium species were H₂Te_(aq) and H₂TeO_3(aq). The ore minerals in the Bulawan deposit were probably formed by mixing of slightly saline and low salinity fluids.     

Mid-infrared spectra of the shocked Murchison CM chondrite: Comparison with astronomical observations of dust in debris disks

We present laboratory mid-infrared transmission/absorption spectra obtained from matrix of the hydrated Murchison CM meteorite experimentally shocked at peak pressures of 10-49 GPa, and compare them to astronomical observations of circumstellar dust in different stages of the formation of planetary systems. The laboratory spectra of the Murchison samples exhibit characteristic changes in the infrared features. A weakly shocked sample (shocked at 10 GPa) shows almost no changes from the unshocked sample dominated by hydrous silicate (serpentine). Moderately shocked samples (21-34 GPa) have typical serpentine features gradually replaced by bands of amorphous material and olivine with increasing shock pressure. A strongly shocked sample (36 GPa) shows major changes due to decomposition of the serpentine and due to devolatilization. A shock melted sample (49 GPa) shows features of olivine recrystallized from melted material.The infrared spectra of the shocked Murchison samples show similarities to astronomical spectra of dust in various young stellar objects and debris disks. The spectra of highly shocked Murchison samples (36 and 49 GPa) are similar to those of dust in the debris disks of HD113766 and HD69830, and the transitional disk of HD100546. The moderately shocked samples (21-34 GPa) exhibit spectra similar to those of dust in the debris disks of Beta Pictoris and BD+20307, and the transitional disk of GM Aur. An average of the spectra of all Murchison samples (0-49 GPa) has a similarity to the spectrum of the older protoplanetary disk of SU Auriga. In the gas-rich transitional and protoplanetary disks, the abundances of amorphous silicates and gases have widely been considered to be a primary property. However, our study suggests that impact processing may play a significant role in generating secondary amorphous silicates and gases in those disks. Infrared spectra of the shocked Murchison samples also show similarities to the dust from comets (C/2002 V1, C/2001 RX14, 9P/Tempel 1, and Hale Bopp), suggesting that the comets also contain shocked Murchison-like material.     

Chaotic Itinerancy and Thermalization in a One-Dimensional Self-Gravitating System

Long time behavior of one-dimensional self-gravitating system is numerically investigated. Itinerant behavior among quasiequilibria is discovered, and its origin is clarified. The macroscopic distributions of the quasiquilibria are different from the isothermal distribution, but the transient states, which appears between two successive quasiequilibria, resemble the isothermal distribution. Averaging over the is itinerancy gives approximately the thermal equilibrium. This revised version was published online in July 2006 with corrections to the Cover Date.