Assessment of nitrogen loading from the Kiso-Sansen Rivers into Ise Bay using stable isotopes

Concentrations of particulate organic nitrogen (PN), dissolved inorganic nitrogen (DIN), and their nitrogen isotope ratios (δ ¹⁵N) in the Kiso-Sansen Rivers were determined from monthly observations over the course of a year to assess variations in the form and sources of riverine nitrogen discharged into Ise Bay. The δ ¹⁵N values of NO₃ ⁻ observed in the Kiso-Sansen Rivers showed a logarithmic decreasing trend from 8 to 0‰, which varied with the river discharge, indicating mixing between point sources with high δ ¹⁵N and non-point sources with low δ ¹⁵N. The influence of isotope fractionation of in situ biogeochemical processes (mainly DIN assimilation by phytoplankton) on δ ¹⁵N of NO₃ ⁻ was negligible, because sufficient concentrations of NH₄ ⁺ for phytoplankton demand would inhibit the assimilation of NO₃ ⁻. A simple relationship between river discharge and δ ¹⁵N of NO₃ ⁻ showed that the fraction of total NO₃ ⁻ flux arising from point sources increased from 4.0–6.3% (1.1–1.8 tN day⁻¹) during higher discharge (>600 m³ s⁻¹) to 30.2–48.3% (2.6–4.1 tN day⁻¹) during lower discharge (<300 m³ s⁻¹). Riverine NO₃ ⁻ discharge from the Kiso-Sansen Rivers can explain 75% of the variations in surface NO₃ ⁻ at the head of Ise Bay over the year.     

Comparison of groundwater age models for assessing nitrate loading,transport pathways,and management options in a complex aquifer system

In an aquifer system with complex hydrogeology, mixing of groundwater with different ages could occur associated with various flow pathways. In this study, we applied different groundwater age‐estimation techniques (lumped parameter model and numerical model) to characterize groundwater age distributions and the major pathways of nitrate contamination in the Gosan agricultural field, Jeju Island. According to the lumped parameter model, groundwater age in the study area could be explained by the binary mixing of the young groundwater (4–33 years) and the old water component (>60 years). The complex hydrogeologic regimes and local heterogeneity observed in the study area (multilayered aquifer, well leakage hydraulics) were particularly well reflected in the numerical model. The numerical model predicted that the regional aquifer of Gosan responded to the fertilizer applications more rapidly (mean age: 9.7–22.3 years) than as estimated by other models. Our study results demonstrated that application and comparison of multiple age‐estimation methods can be useful to understand better the flow regimes and the mixing characteristics of groundwater with different ages (pathways), and accordingly, to reduce the risk of improper groundwater management plans arising from the aquifer heterogeneity.     

Hydrogeochemistry and environmental isotopes of ground water in Jeju volcanic island,Korea: implications for nitrate contamination

Ground water from springs and public supply wells was investigated for hydrochemistry and environmental isotopes of ³H, ¹⁸O and D in Jeju volcanic island, Korea. The wells are completed in a basaltic aquifer and the upper part of hydrovolcanic sedimentary formation. Nitrate contamination is conspicuous in the coastal area where most of the samples have nitrate concentrations well above 1 mg NO₃ N/l. Agricultural land use seems to have a strong influence on the distribution of nitrate in ground water. Comparison of stable isotopic compositions of precipitation and ground water show that ground water mostly originates from rainy season precipitation without significant secondary modification and that local recharge is dominant. ³H concentration of ground water ranged from nearly zero to 5 TU and is poorly correlated with vertical location of well screens. The occurrence of the ³H‐free, old ground water is due to the presence of low permeability layers near the boundary of the basaltic aquifer and the hydrovolcanic sedimentary formation, which significantly limits ground water flow from the upper basaltic aquifer. The old ground water exhibited background‐level nitrate concentrations despite high nitrate loadings, whereas young ground water had considerably higher nitrate concentrations. This correlation of ³H and nitrate concentration may be ascribed to the history of fertilizer use that has increased dramatically since the early 1960s in the island. This suggests that ³H can be used as a qualitative indicator for aquifer vulnerability to nitrate contamination. Copyright © 2005 John Wiley & Sons, Ltd.     

Tracking an upper limit of the “Carnian Crisis” and/or Carnian stage in the Western Carpathians (Slovakia)

International Journal of Earth Sciences - The Late Triassic timescale, especially the Carnian–Norian boundary, is poorly constrained mainly due to a paucity of high-precision radio-isotopic...     

Flow and Pollutant Transport in Urban Street Canyons of Different Aspect Ratios with Ground Heating: Large-Eddy Simulation

A validated large-eddy simulation model was employed to study the effect of the aspect ratio and ground heating on the flow and pollutant dispersion in urban street canyons. Three ground-heating intensities (neutral, weak and strong) were imposed in street canyons of aspect ratio 1, 2, and 0.5. The detailed patterns of flow, turbulence, temperature and pollutant transport were analyzed and compared. Significant changes of flow and scalar patterns were caused by ground heating in the street canyon of aspect ratio 2 and 0.5, while only the street canyon of aspect ratio 0.5 showed a change in flow regime (from wake interference flow to skimming flow). The street canyon of aspect ratio 1 does not show any significant change in the flow field. Ground heating generated strong mixing of heat and pollutant; the normalized temperature inside street canyons was approximately spatially uniform and somewhat insensitive to the aspect ratio and heating intensity. This study helps elucidate the combined effects of urban geometry and thermal stratification on the urban canyon flow and pollutant dispersion.     

Simultaneous vertical measurements of in situ pH and CO2 in the sea using spectrophotometric profilers

We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO₂ (fCO₂) in the ocean using spectrophotometric analysis (pH and CO₂ profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO₂ profiler analyzed in situ fCO₂ by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of pH and CO₂ profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4 ± 3 μatm (SE, n = 31).     

Tracing metamorphism,exhumation and topographic evolution in orogenic belts by multiple thermochronology: a case study from the Nízke Tatry Mts., Western Carpathians

A combination of four thermochronometers [zircon fission track (ZFT), zircon (U–Th)/He (ZHe), apatite fission track (AFT) and apatite (U–Th–[Sm])/He (AHe) dating methods] applied to a valley to ridge transect is used to resolve the issues of metamorphic, exhumation and topographic evolution of the Nízke Tatry Mts. in the Western Carpathians. The ZFT ages of 132.1 ± 8.3, 155.1 ± 12.9, 146.8 ± 8.6 and 144.9 ± 11.0 Ma show that Variscan crystalline basement of the Nízke Tatry Mts. was heated to temperatures >210°C during the Mesozoic and experienced a low-grade Alpine metamorphic overprint. ZHe and AFT ages, clustering at ~55–40 and ~45–40 Ma, respectively, revealed a rapid Eocene cooling event, documenting erosional and/or tectonic exhumation related to the collapse of the Carpathian orogenic wedge. This is the first evidence that exhumation of crystalline cores in the Western Carpathians took place in the Eocene and not in the Cretaceous as traditionally believed. Bimodal AFT length distributions, Early Miocene AHe ages and thermal modelling results suggest that the samples were heated to temperatures of ~55–90°C during Oligocene–Miocene times. This thermal event may be related either to the Oligocene/Miocene sedimentary burial, or Miocene magmatic activity and increased heat flow. This finding supports the concept of thermal instability of the Carpathian crystalline bodies during the post-Eocene period.     

Silicon flux and distribution of biogenic silica in deep-sea sediments in the western North Pacific Ocean

We investigated biogenic silica, several biological components, and silicate in pore-water in the abyssal sediment to determine silicon flux of western North Pacific during several cruises. The surficial sediment biogenic silica content was high at high latitudes with the boundary running along the Kuroshio Extension, and maximum values (exceeding 20%) were found in the Oyashio region. In the subtropical region to the south, most stations showed less than 5% biogenic silica content. This distribution pattern reflected primary production and ocean currents in the surface layer very well. Pore-water samples were collected from 4 stations along the east coast of Japan. The highest asymptotic silicic acid concentration (670 μmol L^?1) in pore-water was observed at the junction of Kuroshio and Oyashio, followed by samples from the Oyashio region. It is at the southern station that the lowest value (450 μmol L^?1) was observed, and the primary production is low under the influence of Kuroshio there. The diffusive flux followed the same geographic trend as the asymptotic silicic acid concentrations did, ranging 77–389 mmol m^?2 yr ^?1. Multiple sampling of pore-water was conducted throughout the year at one station at high latitude. The average annual biogenic silica rain flux observed using sediment traps was 373 mmol m^?2 yr^?1; the diffusive flux and burial flux at the sediment–water interface were 305 and 9 mmol m^?2 yr^?1, respectively. We concluded that most of the settling silica particles dissolved and diffused at the sediment–water interface and approximately 3% only were preserved in this area. In addition, the obvious time lag observed between the peak rain flux and the maximum diffusive flux suggested that primary production in the surface layer has a great influence on the sedimentation environment of abyssal western North Pacific. These transitions of Si flux at the sediment–water interface were considerably greater in northwestern North Pacific than in southwestern North Pacific. In addition, a station in the Philippine Sea indicated high biogenic silica content because of Ethmodiscus ooze, which are scattered randomly on the sea floor in the subtropical region.