Effects of new antifouling compounds on the development of sea urchin

Tributyltin oxide (TBTO) has been used worldwide in marine antifouling paints as a biocide for some time. However, it produced toxic effects, especially in marine water/sediment ecosystems. Consequently, its use in antifouling paints has been prohibited in many countries. In this study, the toxicity of alternative and/or new antifouling biocides compared with TBTO is assessed by a biological method. The effects of these chemicals on marine species have not been well studied. This paper assesses, comparatively, the effects of eight biocides on sea urchin eggs and embryos. The chemicals assessed were TBTO, Irgarol 1051, M1 (the persistent degradation product of Irgarol), Diuron, zinc pyrithione, 'KH101', 'Sea-Nine 211', and copper pyrithione. For these chemicals, toxicity appears to be in the order zinc pyrithione > Sea-Nine 211 > KH101 > copper pyrithione > TBTO > Diuron approximately = Irgarol 1051 > M1. Here, we show that zinc pyrithione, Sea-Nine 211, KH101, and copper pyrithione are much more toxic to sea urchins than TBTO or the other chemicals.     

Dust ring formation due to ice sublimation of radially drifting dust particles under the Poynting-Robertson effect in debris disks

In a disk with a low optical depth, dust particles drift radially inward by the Poynting-Robertson (P-R) drag rather than are blown out by stellar radiation pressure following destructive collisions. We investigate the radial distribution of icy dust composed of pure ice and refractory materials in dust-debris disks taking into account the P-R drag and ice sublimation. We find that icy dust particles form a dust ring by their pile-ups at the edge of their sublimation zone, where they sublime substantially at the temperature 100-110 K. The distance of the dust ring is 20-35 AU from the central star with its luminosity L_??30L_⊙ and 65(L_?/100L_⊙)^1/2 AU for L_??30L_⊙, where L_⊙ is the solar luminosity. The effective optical depth is enhanced by a factor of 2 for L_??100L_⊙ and more than 10 for L_??100L_⊙. The optical depth of the outer icy dust disk exceeds that of the inner disk filled with refractory particles, namely, the residue of ice sublimation, which are further subjected to the P-R effect. As a result, an inner hole is formed inside the sublimation zone together with a dust ring along the outer edge of the hole.     

The 10 ka multiple vent pyroclastic eruption sequence at Tongariro Volcanic Centre, Taupo Volcanic Zone, New Zealand: Part 2. Petrological insights into magma storage and transport during regional extension

The six eruption episodes of the 10 ka Pahoka–Mangamate (PM) sequence (see companion paper) occurred over a ?200–400-year period from a 15-km-long zone of multiple vents within the Tongariro Volcanic Centre (TgVC), located at the southern end of the Taupo Volcanic Zone (TVZ). Most TgVC eruptives are plagioclase-dominant pyroxene andesites and dacites, with strongly porphyritic textures indicating their derivation from magmas that ascended slowly and stagnated at shallow depths. In contrast, the PM pyroclastic eruptives show petrographic features (presence of phenocrystic and groundmass hornblende, and the coexistence of olivine and augite without plagioclase during crystallisation of phenocrysts and microphenocrysts) which suggest that their crystallisation occurred at depth. Depths exceeding 8 km are indicated for the dacitic magmas, and >20 km for the andesitic and basaltic andesitic magmas. Other petrographic features (aphyric nature, lack of reaction rims around hornblende, and the common occurrence of skeletal microphenocrystic to groundmass olivine in the andesites and basaltic andesites) suggest the PM magmas ascended rapidly immediately prior to their eruption, without any significant stagnation at shallow depths in the crust. The PM eruptives show three distinct linear trends in many oxide–oxide diagrams, suggesting geochemical division of the six episodes into three chronologically-sequential groups, early, middle and late. Disequilibrium features on a variety of scales (banded pumice, heterogeneous glassy matrix and presence of reversely zoned phenocrysts) suggest that each group contains the mixing products of two end-member magmas. Both of these end-member magmas are clearly different in each of the three groups, showing that the PM magma system was completely renewed at least three times during the eruption sequence. Minor compositional diversity within the eruptives of each group also allows the PM magmas to be distinguished in terms of their source vents. Because petrography suggests that the PM magmas did not stagnate at shallow levels during their ascent, the minor diversity in magmas from different vents indicates that magmas ascended from depth through separate conduits/dikes to erupt at different vents either simultaneously or sequentially. These unique modes of magma transport and eruption support the inferred simultaneous or sequential tapping of small separate magma bodies by regional rifting in the southern Taupo Volcanic Zone during the PM eruption sequence (see companion paper).     

Trajectories of Moving Objects on a Network: Detection of Similarities,Visualization of Relations,and Classification of Trajectories

Development in techniques of spatial data acquisition enables us to easily record the trajectories of moving objects. Movement of human beings, animals, and birds can be captured by GPS loggers. The obtained data are analyzed by visualization, clustering, and classification to detect patterns frequently or rarely found in trajectories. To extract a wider variety of patterns in analysis, this article proposes a new method for analyzing trajectories on a network space. The method first extracts primary routes as subparts of trajectories. The topological relations among primary routes and trajectories are visualized as both a map and a graph‐based diagram. They permit us to understand the spatial and topological relations among the primary routes and trajectories at both global and local scales. The graph‐based diagram also permits us to classify trajectories. The representativeness of primary routes is evaluated by two numerical measures. The method is applied to the analysis of daily travel behavior of one of the authors. Technical soundness of the method is discussed as well as empirical findings.     

Photoluminescence of baratovite and katayamalite

The photoluminescence (PL) and optical excitation spectra of baratovite in aegirine syenite from Dara-i-Pioz, Tien Shan Mts., Tajikistan and katayamalite in aegirine syenite from Iwagi Islet, Ehime, Japan were obtained at 300 and 80 K. Under short wave (253.7 nm) ultraviolet light, baratovite and katayamalite exhibited bright blue-white luminescence. The PL spectrum of baratovite at 300 K consisted of a wide band with a peak at approximately 406 nm and a full width at half maximum (FWHM) of approximately 6.32k cm⁻¹. The excitation spectrum of the blue-white luminescence from baratovite at 300 K consisted of a prominent band with a peak at approximately 250 nm. The PL and excitation spectra of katayamalite were similar to those of baratovite. The luminescence from these minerals was attributed to the intrinsic luminescence from the TiO₆ center.     

Stability Dependence of Canopy Flows over a Flat Larch Forest

The dependence on atmospheric stability of flow characteristics adjacent to a very rough surface was investigated in a larch forest in Japan. Micrometeorological measurements of three-dimensional wind velocity and air temperature were taken at two heights above the forest, namely 1.7 and 1.2 times the mean canopy height h. Under near-neutral and stable conditions, the observed turbulence statistics suggest that the flow was likely to be that of the atmospheric surface layer (ASL) at 1.7h, and of the roughness sublayer (RSL) at 1.2h. However, in turbulence spectra, canopy-induced large coherent motions appeared clearly at both heights. Even under strongly stable conditions, the large-scale motions were retained at 1.2h, whereas they were overwhelmed by small-scale motions at 1.7h. This phenomenon was probably due to the enhanced contribution of the ASL turbulence associated with nocturnal decay of the RSL depth, because the small-scale motions appeared at frequencies close to the peak frequencies of well-known ASL spectra. This result supports the relatively recent concept that canopy flow is a superimposition of coherent motions and the ASL turbulence. The large-scale motions were retained in temperature spectra over a wider region of stability compared to streamwise wind spectra, suggesting that a canopy effect extended higher up for temperature than wind. The streamwise spacing of dominant eddies according to the plane mixing-layer analogy was only valid in a narrow range at near neutral, and it was stabilised at nearly half its value under stable conditions.     

The transition zone chlorophyll front, a dynamic global feature defining migration and forage habitat for marine resources

Pelagic ecosystem dynamics on all temporal scales may be driven by the dynamics of very specialized oceanic habitats. One such habitat is the basin-wide chlorophyll front located at the boundary between the low chlorophyll subtropical gyres and the high chlorophyll subarctic gyres. Global satellite maps of surface chlorophyll clearly show this feature in all oceans. In the North Pacific, the front is over 8000 km long and seasonally migrates north and south about 1000 km. In the winter this front is located at about 30–35°N latitude and in the summer at about 40–45°N. It is a zone of surface convergence where cool, vertically mixed, high chlorophyll, surface water on the north side sinks beneath warm, stratified, low chlorophyll water on the south side. Satellite telemetry data on movements of loggerhead turtles and detailed fisheries data for albacore tuna show that both apex predators travel along this front as they migrate across the North Pacific. The front is easily monitored with ocean color satellite remote sensing. A change in the position of the TZCF between 1997 and 1998 appears to have altered the spatial distribution of loggerhead turtles. The position and dynamics of the front varied substantially between the 1998 El Niño and the 1999 La Niña. For example, from May to July 1999 the transition zone chlorophyll front (TZCF) remained between about 35°N and 40°N latitude showing very little meandering, whereas in 1998, during the same period, the TZCF exhibited considerable meandering and greater monthly latitudinal movement. Catch rates for albacore were considerably higher in 1998 than in 1999, and we hypothesize that a meandering TZCF creates regions of convergence, which enhances the foraging habitat for apex predators along the front.     

Upward longwave radiation from a non-black urban canopy

The longwave upward radiation was calculated for an urban canopy by using a Monte Carlo model. The effects of the urban geometry were examined in terms of the fractional roof area, the height of the buildings and the emissivity. The urban canopy consists of identically sized buildings and the ground surfaces. The model allows for the temperature differences between the buildings and the ground surface and for multiple reflections in the canyon.The Monte Carlo results show that neglect of the geometric effects causes significant errors in calculated upward radiation: calculations with area-weighting of the radiation emitted from flat homogeneous surfaces are not appropriate. The upward flux is a nonlinear function of the fractional roof area, which may be approximated by a function of the square or cube of the fractional roof area. Neglect of the reflections by non-black surfaces (emissivity<1) underestimates the upward flux by a few percent for a canopy of emissivity=0.9. Radiation effects due to multiple reflections in the canyon are parameterized by use of the view factor and the fractional roof area. The parameterization scheme yields accurate results.     

Capability of the penetrator seismometer system for lunar seismic event observation

We developed a seismometer system for a hard landing “penetrator” probe in the course of the former Japanese LUNAR-A project to deploy new seismic stations on the Moon. The penetrator seismometer system (PSS) consists of two short-period sensor components, a two-axis gimbal mechanism for orientation, and measurement electronics. To carry out seismic observations on the Moon using the penetrator, the seismometer system has to function properly in a lunar environment after a hard landing (impact acceleration of about 8000 G), and requires a signal-to-noise ratio to detect lunar seismic events. We evaluated whether the PSS could satisfactorily observe seismic events on the Moon by investigating the frequency response, noise level, and response to ground motion of our instrument in a simulated lunar environment after a simulated impact test. Our results indicate that the newly developed seismometer system can function properly after impact and is sensitive enough to detect seismic events on the Moon. Using this PSS, new seismic data from the Moon can be obtained during future lunar missions.