Dissolution rates and activation energy for dissolution of brucite (001) : A new method based on the microtopography of crystal surfaces

Scanning Force Microscopy (SFM) was used to develop a method which can provide quantitative kinetic data of crystal growth and dissolution. Based on observations of single crystal faces in monolayer resolution, morphology and temperature dependent growth and dissolution rates can be obtained. From these kinetic data activation energies can be calculated and compared with existing theories. The experimental method works by extracting grown or dissolved terrace areas and step densities from image sequences taken at different temperatures. As an example, the method is applied for dissolution on the brucite (001) surface in acidic water (pH 2.7) within the temperature range of 21 to 35°C. At these conditions the dissolution rate depends nonlinearly on the step density and gives evidence for interstep interaction. The calculated activation energy for dissolution is 60 ± 12 kJ mol⁻¹. With this high activation energy, dissolution cannot be regarded as a transport-controlled process, and is therefore surface controlled.     

Reconstruction of palaeosalinity using carbon isotopes and benthic associations: a comparison

Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data.     

Regional climate modelling over complex terrain: an evaluation study of COSMO-CLM hindcast model runs for the Greater Alpine Region

In this study the results of the regional climate model COSMO-CLM (CCLM) covering the Greater Alpine Region (GAR, 4°–19°W and 43°–49°N) were evaluated against observational data. The simulation was carried out as a hindcast run driven by ERA-40 reanalysis data for the period 1961–2000. The spatial resolution of the model data presented is approx. 10 km per grid point. For the evaluation purposes a variety of observational datasets were used: CRU TS 2.1, E-OBS, GPCC4 and HISTALP. Simple statistics such as mean biases, correlations, trends and annual cycles of temperature and precipitation for different sub-regions were applied to verify the model performance. Furthermore, the altitude dependence of these statistical measures has been taken into account. Compared to the CRU and E-OBS datasets CCLM shows an annual mean cold bias of ?0.6 and ?0.7 °C, respectively. Seasonal precipitation sums are generally overestimated by +8 to +23 % depending on the observational dataset with large variations in space and season. Bias and correlation show a dependency on altitude especially in the winter and summer seasons. Temperature trends in CCLM contradict the signals from observations, showing negative trends in summer and autumn which are in contrast to CRU and E-OBS.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

The internal structures and densities of asteroids

Abstract— Four asteroidal bodies (the Martian satellites Phobos and Deimos and the main-belt asteroids 243 Ida and 253 Mathilde) have now been the subjects of sufficiently close encounters by spacecraft that the masses and sizes and, hence, the densities of these bodies can be estimated to ～10%. All of these asteroids are significantly less dense than most members of the classes of meteorites identified as being compositionally most nearly similar to them on the basis of spectral characteristics. We show that two processes can act, independently or in concert, during the evolutionary histories of asteroids to produce a low bulk density. One of these processes is the result of one or more impact events and can affect any asteroid type, whereas the other can occur only for certain types of small asteroids that have undergone aqueous alteration.     

Preserving the Ocean Circulation: Implications for Climate Policy

Climate modelers have recognized the possibility of abrupt climate changes caused by a reorganization of the North Atlantic's current pattern (technically known as a thermohaline circulation collapse). This circulation system now warms north-western Europe and transports carbon dioxide to the deep oceans. The posited collapse of this system could produce severe cooling in northwestern Europe, even when general global warming is in progress. In this paper we use a simple integrated assessment model to investigate the optimal policy response to this risk. Adding the constraint of avoiding a thermohaline circulation collapse would significantly reduce the allowable greenhouse gas emissions in the long run along an optimal path. Our analysis implies that relatively small damages associated with a collapse (less than 1% of gross world product) would justify a considerable reduction of future carbon dioxide emissions.     

Features and evaluation of sea/saltwater intrusion in southern Laizhou Bay

Understanding the degree of sea/saltwater intrusion in coastal regions is of great significance to treating the intrusion and improving the environment. Based on the character analysis of the sea/saltwater intrusion, five factors were selected in the fuzzy-synthetical evaluation approach to form the index system, so as to evaluate the degree of sea/saltwater intrusion in southern Laizhou Bay. The results show that the sea/saltwater intrusion is stronger in the middle and northern areas and weaker on the sides and in southern area; currently, the intrusion is relatively serious, and the intrusion area has covered about 68.2% of the areas under study, among which the heavily intruded area is over 50%. Based on the factors analysis of the occurrence and development of sea/saltwater intrusion, the thesis proposes treatment measures.     

Relative influence of vegetation on urban energy budgets and surface temperatures

Two deterministic models were combined: one for canopy leaf energy budgets and one for street canyon energy budgets. The effects of street parks and roof gardens in contrast to non-vegetated city blocks were examined by the use of four typical urban morphologies, which were exposed latitudinally to summer and winter simulations. A variety of increases and decreases in shortwave radiation, net radiation, sensible heat flux, and system reradiation resulted. These changes appear to represent the generalized limits of the possible responses to the addition of vegetation to non-vegetated city blocks.