Acapulcoite-lodranite meteorites: Ultramafic asteroidal partial melt residues

Acapulcoites (most ancient Hf-W ages are 4,563.1?±?0.8 Ma), lodranites (most ancient Hf-W ages are 4,562.6?±?0.9 Ma) and rocks transitional between them are ancient residues of different degrees of partial melting of a chondritic source lithology (e.g., as indicated by the occurrence of relict chondrules in 9 acapulcoites), although the precise chondrite type is unknown. Acapulcoites are relatively fine- grained (～150–230?μm) rocks with equigranular, achondritic textures and consist of olivine, orthopyroxene, Ca-rich clinopyroxene, plagioclase, metallic Fe,Ni, troilite, chromite and phosphates. Lodranites are coarser grained (540–700?μm), with similar equigranular, recrystallized textures, mineral compositions and contents, although some are significantly depleted in eutectic Fe,Ni-FeS and plagioclase- clinopyroxene partial melts. The acapulcoite-lodranite clan is most readily distinguished from other groups of primitive achondrites (e.g., winoanites/IAB irons) by oxygen isotopic compositions, although more than 50% of meteorites classified as acapulcoites currently lack supporting oxygen isotopic data. The heat source for melting of acapulcoites-lodranites was internal to the parent body, most likely ²⁶Al, although some authors suggest it was shock melting. Acapulcoites experienced lower temperatures of ～980–1170?°C and lower degrees of partial melting (～1–4?vol.%) and lodranites higher temperatures of ～1150–1200?°C and higher degrees (～5?≥?10?vol.%) of partial melting. Hand-specimen and thin section observations indicate movement of Fe,Ni-FeS, basaltic, and phosphate melts in veins over micrometer to centimeter distances. Mineralogical, chemical and isotopic properties, Cosmic Ray Exposure (CRE) ages which cluster around 4–6 Ma and the occurrence of some meteorites consisting of both acapulcoite and lodranite material, indicate that these meteorites come from one parent body and were most likely ejected in one impact event. Whereas the precise parent asteroid of these meteorites is unknown, there is general agreement that it was an S-type object. There is nearly total agreement that the acapulcoite-lodranite parent body was <～100?km in radius and, based on the precise Pb–Pb age for Acapulco of 4555.9?±?0.6 Ma, combined with the Hf/W and U/Pb records and cooling rates deduced from mineralogical and other investigations, that the parent body was fragmented during its cooling which the U/Pb system dates at precisely 4556?±?1 Ma. Hf-W chronometry suggests that the parent body of the acapulcoites-lodranites and, in fact, the parent bodies of all “primitive achondrites” accreted slightly later than those of the differentiated achondrites and, thus, had lower contents of ²⁶Al, the heat producing radionuclide largely responsible for heating of both primitive and differentiated achondrites. Thus, the acapulcoite-lodranite parent body never experienced the high degrees of melting responsible for the formation of the differentiated meteorites, but arrested its melting history at relatively low degrees of ～15?vol.%.     

Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes

In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined ⁸⁷Sr/⁸⁶Sr ratios of several carbonate (JCt‐1, JCp‐1, MACS‐1, MACS‐3) and phosphate (MAPS‐4, MAPS‐5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi‐collector inductively coupled plasma‐mass spectrometers (MC‐ICP‐MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for some RMs. For MACS‐1, we present the first ⁸⁷Sr/⁸⁶Sr value. We tested the suitability of these materials for microanalytical analyses by LA‐MC‐ICP‐MS, with two different laser ablation systems: a conventional nanosecond laser and a state‐of‐the‐art femtosecond laser. We investigated the RMs micro‐homogeneity and compared the data with our solution data. Both laser ablation systems yielded identical ⁸⁷Sr/⁸⁶Sr ratios within uncertainty to the solution data for RMs with low interferences of REEs. Therefore, these carbonate and phosphate RMs can be used to achieve accurate and precise results for in situ Sr isotope investigations by LA‐MC‐ICP‐MS of similar materials.     

Age constraints on faulting and fault reactivation: a multi-chronological approach

Movement within the Earth’s upper crust is commonly accommodated by faults or shear zones, ranging in scale from micro-displacements to regional tectonic lineaments. Since faults are active on different time scales and can be repeatedly reactivated, their displacement chronology is difficult to reconstruct. This study represents a multi-geochronological approach to unravel the evolution of an intracontinental fault zone locality along the Danube Fault, central Europe. At the investigated fault locality, ancient motion has produced a cataclastic deformation zone in which the cataclastic material was subjected to hydrothermal alteration and K-feldspar was almost completely replaced by illite and other phyllosilicates. Five different geochronological techniques (zircon Pb-evaporation, K–Ar and Rb–Sr illite, apatite fission track and fluorite (U-Th)/He) have been applied to explore the temporal fault activity. The upper time limit for initiation of faulting is constrained by the crystallization age of the primary rock type (known as “Kristallgranit”) at 325 ± 7 Ma, whereas the K–Ar and Rb–Sr ages of two illite fractions <2 μm (266–255 Ma) are interpreted to date fluid infiltration events during the final stage of the cataclastic deformation period. During this time, the “Kristallgranit” was already at or near the Earth’s surface as indicated by the sedimentary record and thermal modelling results of apatite fission track data. (U–Th)/He thermochronology of two single fluorite grains from a fluorite–quartz vein within the fault zone yield Cretaceous ages that clearly postdate their Late-Variscan mineralization age. We propose that later reactivation of the fault caused loss of helium in the fluorites. This assertion is supported by geological evidence, i.e. offsets of Jurassic and Cretaceous sediments along the fault and apatite fission track thermal modelling results are consistent with the prevalence of elevated temperatures (50–80°C) in the fault zone during the Cretaceous.     

GGR Biennial Review: Reference Materials in Geoanalytical and Environmental Research – Review for 2008 and 2009

This review gives an overview of the literature on reference materials of geochemical and environmental interest for the two-year period 2008–2009. Reference materials play an increasingly important role in all fields of geoanalytical research. This is demonstrated by the large number of publications containing data on reference materials. Although many reference materials exist, there is still a great need for certified samples, so-called delta zero materials for stable isotopic work and homogeneous microanalytical reference materials. This review focuses on six topics: developments of certification processes of reference materials mainly postulated in ISO guidelines and the IAG protocol, new developments of the GeoReM database, investigations of powdered rock reference materials, Chinese reference materials published in Chinese journals, microanalytical reference materials and isotopic reference materials.     

Geochemical characteristics and Sr–Nd–Hf isotope compositions of mantle xenoliths and host basalts from Assab, Eritrea: implications for the composition and thermal structure of the lithosphere beneath the Afar Depression

The Afar Depression offers a rare opportunity to study the geodynamic evolution of a rift system from continental rifting to sea floor spreading. This study presents geochemical data for crustal and mantle xenoliths and their alkaline host basalts from the region. The basalts have enriched REE patterns, OIB-like trace element characteristics, and a limited range in isotopic composition (⁸⁷Sr/⁸⁶Sr = 0.70336–0.70356, ε _Nd = +6.6 to +7.0, and ε _Hf = +10.0 to +10.7). In terms of trace elements and Sr–Nd isotopes, they are similar to basalts from the Hanish and Zubair islands in the southern Red Sea and are thus interpreted to be melts from the Afar mantle. The gabbroic crustal xenoliths vary widely in isotope composition (⁸⁷Sr/⁸⁶Sr = 0.70437–0.70791, ε _Nd = −8.1 to +2.5, and ε _Hf = −10.5 to +4.9), and their trace element characteristics match those of Neoproterozoic rocks from the Arabian–Nubian Shield and modern arc rocks, suggesting that the lower crust beneath the Afar Depression contains Neoproterozoic mafic igneous rocks. Ultramafic mantle xenoliths from Assab contain primary assemblages of fresh ol + opx + cpx + sp ± pl, with no alteration or hydrous minerals. They equilibrated at 870–1,040°C and follow a steep geothermal gradient consistent with the tectonic environment of the Afar Depression. The systematic variations in major and trace elements among the Assab mantle xenoliths together with their isotopic compositions suggest that these rocks are not mantle residues but rather series of layered cumulate sills that crystallized from a relatively enriched picritic melt related to the Afar plume that was emplaced before the eruption of the host basalts.     

An impact model of Newton’s law of gravitation

The far-reaching gravitational force—in the approximation of Newton’s law of gravitation—is described by a heuristic model with hypothetical massless particles propagating at the speed of light in vacuum and transferring momentum and energy between physical entities through interactions on a local basis. The model has some similarities with the impact theory presented by Nicolas Fatio de Duillier to the Royal Society in 1690. Objections raised against this idea are dispelled by invoking the Special Theory of Relativity, considering non-local interactions, and replacing the shielding concept by a secular mass increase of massive bodies. Some consequences and applications of the model are discussed.     

Ejection behavior characteristics in experimental cratering in sandstone targets

Abstract– Within the frame of the MEMIN research unit (Multidisciplinary Experimental and Numerical Impact Research Network), impact experiments on sandstone targets were carried out to systematically study the influence of projectile mass, velocity, and target water saturation on the cratering and ejection processes. The projectiles were accelerated with two‐stage light‐gas guns (Ernst‐Mach‐Institute) onto fine‐grained targets (Seeberger sandstone) with about 23% porosity. Collection of the ejecta on custom‐designed catchers allowed determination of particle shape, size distribution, ejection angle, and microstructures. Mapping of the ejecta imprints on the catcher surface enabled linking of the different patterns to ejection stages observed on high‐speed videos. The increase in projectile mass from 0.067 to 7.1 g correlates with an increase in the total ejected mass; ejecta angles, however, are similar in range for all experiments. The increase in projectile velocity from 2.5 to 5.1 km s^?1 correlates with a total ejecta mass increase as well as in an increase in comminution efficiency, and a widening of the ejecta cone. A higher degree of water saturation of the target yields an increase in total ejecta mass up to 400% with respect to dry targets, higher ejecta velocity, and a steeper cone. These data, in turn, suggest that the reduced impedance contrast between the quartz grains of the target and the pores plays a primary role in the ejecta mass increase, while vaporization of water determines the ejecta behavior concerning ejecta velocity and particle distribution.     

Daily streamflow trends in Western versus Eastern Norway and their attribution to hydro-meteorological drivers

Regional warming and modifications in precipitation regimes has large impacts on streamflow in Norway, where both rainfall and snowmelt are important runoff generating processes. Hydrological impacts of recent changes in climate are usually investigated by trend analyses applied on annual, seasonal, or monthly time series. None of these detect sub-seasonal changes and their underlying causes. This study investigated sub-seasonal changes in streamflow, rainfall, and snowmelt in 61 and 51 catchments respectively in Western (Vestlandet) and Eastern (Østlandet) Norway by applying the Mann–Kendall test and Theil–Sen estimator on 10-day moving averaged daily time series over a 30-year period (1983–2012). The relative contribution of rainfall versus snowmelt to daily streamflow and the changes therein have also been estimated to identify the changing relevance of these driving processes over the same period. Detected changes in 10-day moving averaged daily streamflow were finally attributed to changes in the most important hydro-meteorological drivers using multiple-regression models with increasing complexity. Earlier spring flow timing in both regions occur due to earlier snowmelt. Østlandet shows increased summer streamflow in catchments up to 1100 m a.s.l. and slightly increased winter streamflow in about 50% of the catchments. Trend patterns in Vestlandet are less coherent. The importance of rainfall has increased in both regions. Attribution of trends reveals that changes in rainfall and snowmelt can explain some streamflow changes where they are dominant processes (e.g., spring snowmelt in Østlandet and autumn rainfall in Vestlandet). Overall, the detected streamflow changes can be best explained by adding temperature trends as an additional predictor, indicating the relevance of additional driving processes such as increased glacier melt and evapotranspiration.     

The Weierbach experimental catchment in Luxembourg: A decade of critical zone monitoring in a temperate forest - from hydrological investigations to ecohydrological perspectives

The Weierbach experimental catchment (0.45 km²) is the most instrumented and studied sub-catchment in the Alzette River basin in Luxembourg. Within the last decade, it has matured towards an interdisciplinary critical zone observatory focusing on a better understanding of hydrological and hydro-geochemical processes. The Weierbach catchment is embedded in an elevated sub-horizontal plateau, characterized by slate bedrock and representative of the Ardennes Massif. Its climate is semi-marine, with precipitation being rather evenly distributed throughout the year. Base flow is lowest from July to September, essentially due to higher losses through evapotranspiration in summer. The regolith is composed of Devonian slates, overlaid by Pleistocene slope deposits and entirely covered by forest with 70% deciduous and 30% coniferous trees. Since 2009, the Weierbach has been extensively equipped for continuously monitoring water fluxes and physico-chemical parameters within different compartments of the critical zone. Additionally, these compartments are sampled fortnightly at several locations to analyze δ¹⁸O and δ²H isotopic composition of water including rainfall, throughfall, soil water, groundwater and streamwater. This ongoing monitoring and sampling programme is used for answering pressing questions related to fundamental catchment functions of water infiltration, storage, mixing and release in forest ecosystems. A recently started research line aims at investigating interactions between forest eco-hydrosystems with the atmosphere and understanding how catchments will respond to a non-stationary climate.     

What are robust strategies in the face of uncertain climate threshold responses?

We use an integrated assessment model of climate change to analyze how alternative decision-making criteria affect preferred investments into greenhouse gas mitigation, the distribution of outcomes, the robustness of the strategies, and the economic value of information. We define robustness as trading a small decrease in a strategy’s expected performance for a significant increase in a strategy’s performance in the worst cases. Specifically, we modify the Dynamic Integrated model of Climate and the Economy (DICE-07) to include a simple representation of a climate threshold response, parametric uncertainty, structural uncertainty, learning, and different decision-making criteria. Economic analyses of climate change strategies typically adopt the expected utility maximization (EUM) framework. We compare EUM with two decision criteria adopted from the finance literature, namely Limited Degree of Confidence (LDC) and Safety First (SF). Both criteria increase the relative weight of the performance under the worst-case scenarios compared to EUM. We show that the LDC and SF criteria provide a computationally feasible foundation for identifying greenhouse gas mitigation strategies that may prove more robust than those identified by the EUM criterion. More robust strategies show higher near-term investments in emissions abatement. Reducing uncertainty has a higher economic value of information for the LDC and SF decision criteria than for EUM.