Nano‐Powdered Calcium Carbonate Reference Materials: Significant Progress for Microanalysis?

Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano‐powdered pellets are compared. Our results using nanosecond and femtosecond LA‐(MC)‐ICP‐MS show that the nano‐pellets of the RMs MACS‐3NP, JCp‐1NP and JCt‐1NP are about a factor of 2–3 more homogeneous than the original samples MACS‐3, JCp‐1 and JCt‐1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS‐3 agree with its fine‐grained analogue MACS‐3NP. Very small, but significant, differences between original and nano‐pellets are observed in the RMs JCp‐1 and JCt‐1 for some trace elements with very low contents, indicating the need for re‐certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg^?1), and their isotope compositions determined by LA‐MC‐ICP‐MS in the original and the nano‐pellets agree within uncertainty limits.     

广东河源断裂带地热成因及与构造关系初探

广东省河源断裂带位于中国东南沿海地热异常区,地热资源十分丰富,但其形成机制和利用前景尚不确定。为此文章开展了多学科综合分析,获得以下初步认识:温泉是断裂带内深循环地下水被地温加热而成,断裂剪切热和花岗岩浆残余热的贡献基本可以排除;沿断裂展布的厚层硅化带是古水热活动的产物;硅化带形成时期的挤压应力方向为北东-南西,与河源断裂及河源盆地晚白垩世以来的伸展活动对应,现代构造应力场为北西西-南东东方向挤压,与古应力场相比发生了明显变化;现今构造应力场使得北东向河源断裂呈右旋挤压运动,而北西向断裂则发生左旋张剪,导致地下水循环格局也发生相应改变;目前温泉沿河源断裂呈带分布,沿北西向断裂呈线性溢出,断裂交汇部位是热泉上升的主要通道。总体而言,河源地区拥有令人鼓舞的地热资源及应用前景,有可能达到建设地热发电厂的目标。建议继续深入开展地质学、地球物理、水文地质学和地热成因机理等多学科综合研究,从而更好地定量评价地热潜能与开发前景。     

Seismic attenuation and velocity dispersion in fractured rocks: The role played by fracture contact areas

The presence of fractures in fluid‐saturated porous rocks is usually associated with strong seismic P‐wave attenuation and velocity dispersion. This energy dissipation can be caused by oscillatory wave‐induced fluid pressure diffusion between the fractures and the host rock, an intrinsic attenuation mechanism generally referred to as wave‐induced fluid flow. Geological observations suggest that fracture surfaces are highly irregular at the millimetre and sub‐millimetre scale, which finds its expression in geometrical and mechanical complexities of the contact area between the fracture faces. It is well known that contact areas strongly affect the overall mechanical fracture properties. However, existing models for seismic attenuation and velocity dispersion in fractured rocks neglect this complexity. In this work, we explore the effects of fracture contact areas on seismic P‐wave attenuation and velocity dispersion using oscillatory relaxation simulations based on quasi‐static poroelastic equations. We verify that the geometrical and mechanical details of fracture contact areas have a strong impact on seismic signatures. In addition, our numerical approach allows us to quantify the vertical solid displacement jump across fractures, the key quantity in the linear slip theory. We find that the displacement jump is strongly affected by the geometrical details of the fracture contact area and, due to the oscillatory fluid pressure diffusion process, is complex‐valued and frequency‐dependent. By using laboratory measurements of stress‐induced changes in the fracture contact area, we relate seismic attenuation and dispersion to the effective stress. The corresponding results do indeed indicate that seismic attenuation and phase velocity may constitute useful attributes to constrain the effective stress. Alternatively, knowledge of the effective stress may help to identify the regions in which wave induced fluid flow is expected to be the dominant attenuation mechanism.     

Trends in extreme temperature indices in the Poyang Lake Basin,China

Based on daily maximum and minimum temperature records at 78 meteorological stations in the Basin of China’s largest fresh water lake (Poyang Lake Basin), the temporal and spatial variability of 11 extreme temperature indices are investigated for the period 1959–2010. The analysis indicates that the annual mean of daily minimum temperature (T_min) has increased significantly, while no significant trends were observed in the annual mean of daily maximum temperature (T_max), resulting in a significant decrease in the diurnal temperature range. Trends and percentages of stations with significant trends in T_min-related indices are generally stronger and higher than those in T_max-related indices; however, no significant trends can be found in T_max-related indices (TXMean, TX90p, TXx and TX10p) at both seasonal and annual time scale. Low correlations with Global-SST ENSO index are also detected in T_max-related indices. Significant positive relationships can be found in T_min-related indices (TNMean, TNx, TNn and TN90p), however, the most significant negative coefficient was also found in cold nights (TN10p) with the Global-SST ENSO index. Singular value decomposition (SVD) correlating extreme temperatures over the Poyang Lake Basin and the North Pacific SST indicates the East China Sea, Western Pacific and Bering Sea to be stronger linked with T_min than T_max with the first mode (SVD-1) explaining 90 and 94 % of annual T_max and T_min respectively.     

VARIABILITY OF DAILY PRECIPITATION IN CHINA(1980-1993):PCA AND WAVELET ANALYSIS OF OBSERVATION AND ECMWF REANALYSIS DATA

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Origin of the color in cobalt-doped quartz

Synthetic Co-doped quartz was grown hydrothermally in steel autoclaves at the Technological Center of Minas Gerais (CETEC), Brazil. The quartz samples, originally yellow in the as-grown state acquired blue coloration after prolonged heat treatment times at 500°C near the alpha–beta transition temperature. UV–VIS–NIR absorption spectroscopy shows the characteristic spectra of Co³⁺ before heat treatment. After heat treatment, the optical absorption spectrum is dominated by two split-triplet bands the first in the near infrared region centered at about 6,700 cm⁻¹ (1,490 nm) and the second in the visible spectral range at about 16,900 cm⁻¹ (590 nm). Both split-triplet bands are typical for Co²⁺ ions in tetrahedral coordination environments. From the absence of electron paramagnetic resonance (EPR) spectra, we conclude that the Co²⁺ found in the optical absorption spectra of the blue quartz is not due to an isolated structural site in the quartz lattice. Instead, the blue color is associated with electronic transitions of Co²⁺ in small inclusions in which the Co site has tetrahedral symmetry. The non-observation of polarization-depend optical absorption spectra is also in agreement with this model. The results for Co²⁺ in quartz are different from Co-bearing spinel and staurolite and other silicates like orthopyroxene, olivine, and beryls. The formation process of the color center is discussed.     

Chemical Characterisation of the USGS Reference Glasses GSA-1G, GSC-1G, GSD-1G, GSE-1G, BCR-2G, BHVO-2G and BIR-1G Using EPMA, ID-TIMS, ID-ICP-MS and LA-ICP-MS

The USGS reference glasses GSA-1G, GSC-1G, GSD-1G, GSE-1G, BCR-2G, BHVO-2G and BIR-1G were investigated by different analytical techniques. All these materials have a geological (basaltic) matrix and are therefore useful in igneous geochemistry as matrix-matched reference materials for microanalytical techniques. The new GS glasses have trace elements in groups at concentration levels of about < 0.01, 5, 50 and 500 μg g^-1. Their major element compositions have been determined by EPMA, and trace elements have been analysed by LA-ICP-MS and two isotope dilution techniques using TIMS and ICP-MS. EPMA and LA-ICP-MS analyses indicated that the USGS reference glasses are homogeneous at the μm to mm scale with respect to major (variations < 1-2%) and most trace elements (variations 1-4%). Trace element data obtained from the different analytical techniques agreed within an uncertainty of 1-5%, indicating that between method results are comparable. Therefore, the preliminary working values for the four USGS GS glasses calculated from these data have a low level of uncertainty.     

Suitability of Mn‐ and Fe‐Rich Reference Materials for Microanalytical Research

Manganese‐ and iron‐rich materials are of major geoscientific and economic interest, many of which contain microscopic features that provide valuable information. To obtain accurate results, a homogeneous microanalytical reference material for calibration is needed. Several researchers have used the Mn‐ and Fe‐rich RMs, JMn‐1, NOD‐A‐1, NOD‐P‐1 and FeMn‐1, for this purpose; therefore, they were tested in this study to determine their suitability for microanalysis. Their homogeneity was investigated by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) with two different types of lasers (nano‐ and femtosecond), with spot and line scan analyses and with different operating parameters, such as spot size, pulse repetition rate and fluence. As the established manganese nodule RMs revealed inhomogeneities for picogram to microgram test portions, we also investigated the new synthetic Fe‐ and Mn‐rich RM, FeMnOx‐1. FeMnOx‐1 was found to be homogeneous for large (ø 40 μm: 2% RSD repeatability) and small (ø 8–10 μm: 10% RSD repeatability) spot sizes. This homogeneity is in the range of the homogeneous NIST SRM 610 and GSE‐1G reference glasses. Furthermore, FeMnOx‐1 revealed a large‐scale homogeneity within uncertainties of a few per cent, using test portions in the ng range, when measuring four individual mounts of this material.