Contributions to mineral chemistry of Hawaiian rocks

Small gabbroic dikes of high TiO₂ content transect massive hawaiite in the Kaena Quarry, Waianae Range, Oahu. One dike studied consists of two rock types: (a) border zone alkali gabbro of high titanomagnetite and titanaugite content and, (b) interior mugearite that contains iron-rich pyroxenes and K-feldspar. The dike probably formed as an in situ latestage segregation enriched in TiO₂, SiO₂, and alkalis.     

A Sr isotope study on fluorite and siderite from post-orogenic mineral veins in the eastern Harz Mountains,Germany

Rb–Sr isotope data for siderite and fluorite from sediment-hosted epithermal mineral veins in the eastern Harz Mountains (Germany) are presented. Several fluorite and siderite-bearing paragenetic stages have been proposed for these veins, with the most important mineralization being related to a quartz–sulfide and a subsequent calcite–fluorite–quartz stage, which occurred at 226±1 and 209±2 Ma, respectively. Our Rb–Sr data do not permit the identification of distinct generations of siderite and fluorite, but rather reveal straight internal mixing relations, reflecting mixing of fluids or differential fluid–rock interaction processes. This indicates merely two significant phases of mineral deposition related to the quartz–sulfide and calcite–fluorite–quartz stages. It is shown that the Paleozoic sedimentary host rocks of the veins are the most likely source for the siderite Sr, whereas fluorite displays a two-component mixture between sedimentary Sr and radiogenic Sr derived from locally occurring Permian metavolcanic rocks. Editorial handling: B. Lehmann     

中国日降雨量变化特征分析

将旋转主成分分析和复变量莫莱特小波分析应用于14a中国境内实测与ECMWF再分析日降雨量资料,研究其年际、季际与季节内变化的时空分布特征和再分析日降雨量资料的有效性。结果表明:从实测资料中分析的降水特征,都可以由再分析资料再现出来。除周内振荡大有出入外,其余频率的振荡二者大致相符或基本吻合。因此,周内振荡还不能被再分析数据较好地刻划,但是与旱涝灾害和季风爆发联系密切的周际以上振荡,在再分析日降雨量中基本上能被正确地表现出来。     

A Ca ii H&K survey of γ Doradus candidates

In an investigation of the starspot hypothesis as it applies to the 'slowly variable' F-type dwarfs, we spectroscopically observed eight promising γ Doradus candidates to search for Ca  ii H&K emission. We found that there are no significant emission reversals in the cores of these resonance lines. Based on the ceiling flux calculations of the Ca  ii K line and on calculations of the Rossby number, we conclude that there is no support for the presence of strong magnetic activity and the starspot hypothesis in these objects.     

THE BEAVER-HARRISON,BEAVER COUNTY,UTAH L6 CHONDRITE

The Beaver-Harrison, Utah chondrite (find July 24, 1979), a single, shock-veined stone of 925 grams, consists of major olivine (Fa_25.0), low-Ca pyroxene (En_77.3Fs_21.1Wo_1.6) and metallic nickel-iron; minor troilite and plagioclase (Ab_82.6An_11.1Or_6.3), accessory high-Ca pyroxene (En_47.0Fs_8.5Wo_44.5), chromite (Cm_8.7Sp_10.6Uv_9.4Pc_0.6Hc_0.7), chlorapatite and whitlockite; and hydrous ferric oxide of terrestrial weathering origin. Mineral compositions indicate L-group classification, and homogeneity of minerals, highly recrystallized texture and presence of clear plagioclase suggest that the meteorite belongs to petrologic type 6.     

Tectonics of the Laptev Sea – Moma `Rift' Region: Investigation with Seismologic Broadband Data

Based on teleseismic broadband data, mainly recorded from stationsof the Incorporated Research Institute for Seismology (IRIS) and theGräfenberg (GRF) array in Germany, the focal mechanism and thefocal depth of the largest earthquakes in northeastern Siberia in thetime interval 1976–1996 were determined. For 9 events the relativeanelastic attenuation of the shear wave with respect to the compressionalwave along the travel paths could be calculated. Using the slip vectorsfrom the best constrained focal mechanisms and additional slip vectorsfrom Jemsek et al. (1986) and Parfenov et al. (1988), we obtained the North American–Eurasian pole of rotation west of the Cherskii mountainsat 67.1^° N, 132.3^° E.The investigation shows that the extension of the Arctic Mid-Ocean Ridgeinto the continental shelf acts as a continental graben structure.Actually, the crustal extension is concentrated on the eastern LaptevSea area and the seismicity of the western part of the Laptev Sea canbe explained by the assumption of a separate microplate. In the continentsoutheast of the Laptev Sea a series of northwest trending depressions,known as the Moma `Rift', are observed. Although in this region elevatedheat flow, recent volcanism and a low crustal thickness were found (i.e.Duchkov and Sokolova, 1985; Devyatkin, 1985), there is only a poorcorrelation between the seismicity and the rift valleys. So the Momastructures seem to be related to an aborted rift structure.     

Bayes estimation: A novel approach to derivation of internally consistent thermodynamic data for minerals,their uncertainties,and correlations. Part II: Application

Internally consistent thermodynamic data, including their uncertainties and correlations, are reported for 22 phases of the quaternary system CaO-Al₂O₃-SiO₂-H₂O. These data have been derived by simultaneous evaluation of the appropriate phase properties (PP) and reaction properties (RP) by the novel technique of Bayes estimation (BE). The thermodynamic model used and the theory of BE was expounded in Part I of this paper. Part II is the follow-up study illustrating an application of BE. The input for BE comprised, among others, the a priori values for standard enthalpy of formation of the i-th phase, Δ_f H _i ⁰ , and its standard entropy, S _i ⁰ , in addition to the reaction reversal constraints for 33 equilibria involving the relevant phases. A total of 269 RP restrictions have been processed, of which 107 turned out to be non-redundant. The refined values for Δ_f H _i ⁰ and S _i ⁰ obtained by BE, including their 2σ-uncertainties, appear in Table 4; the Appendix reproduces the corresponding correlation matrix. These data permit generation of computed phase diagrams with 2σ-uncertainty envelopes based on conventional error propagation; Fig. 3 depicts such a phase diagram for the system CaO-Al₂O₃-SiO₂. It shows that the refined dataset is capable of yielding phase diagrams with uncertainty envelopes narrow enough to be geologically useful. The results in Table 4 demonstrate that the uncertainties of the prior values for Δ_f H _i ^Emphasis>0 , given in Table 1, have decreased by up to an order of magnitude, while those for S _i ⁰ improved by a factor of up to two. For comparison, Table 4 also lists the refined Δ_f H _i ⁰ and S _i ⁰ data obtained by mathematical programming (MAP), minimizing a quadratic objective function used earlier by Berman (1988). Examples of calculated phase diagrams are given to demonstrate the advantages of BE for deriving internally consistent thermodynamic data. Although P-T curves generated from both MAP and BE databases will pass through the reversal restrictions, BE datasets appear to be better suited for extrapolations beyond the P-T range explored experimentally and for predicting equilibria not constrained by reversals.     

Simulating coseismic deformation of quartz in the middle crust and fabric evolution during postseismic stress relaxation — An experimental study

Non-steady state deformation and annealing experiments on vein quartz are designed to simulate earthquake-driven episodic deformation in the middle crust. Three types of experiments were carried out using a modified Griggs-type solid medium deformation apparatus. All three start with high stress deformation at a temperature of 400 °C and a constant strain rate of 10^− 4 s^− 1 (type A), some are followed by annealing in the stability field of α-quartz for 14–15 h at zero nominal differential stress and temperatures of 800–1000 °C (type A + B), or by annealing for 15 h at 900 °C and at a residual stress (type A + C).The quartz samples reveal a very high strength > 2 GPa at a few percent of permanent strain. The microstructures after short-term high stress deformation (type A) record localized brittle and plastic deformation. Statisc annealing (type A + B) results in recrystallisation restricted to the highly damaged zones. The new grains aligned in strings and without crystallographic preferred orientation, indicate nucleation and growth. Annealing at non-hydrostatic conditions (type A + C) results in shear zones that also develop from deformation bands or cracks that formed during the preceding high stress deformation. In this case, however, the recrystallised zone is several grain diameters wide, the grains are elongate, and a marked crystallographic preferred orientation indicates flow by dislocation creep with dynamic recrystallisation. Quartz microstructures identical to those produced in type A + B experiments are observed in cores recovered from Long Valley Exploratory Well in the Quaternary Long Valley Caldera, California, with considerable seismic activity.The experiments demonstrate the behaviour of quartz at coseismic loading (type A) and subsequent static annealing (type A + B) or creep at decaying stress (type A + C) in the middle crust. The experimentally produced microfabrics allow to identify similar processes and conditions in exhumed rocks.