Time-dependent greenhouse warming computations with a coupled ocean-atmosphere model

Climate changes during the next 100 years caused by anthropogenic emissions of greenhouse gases have been simulated for the Intergovernmental Panel on Climate Change Scenarios A (business as usual) and D (accelerated policies) using a coupled ocean-atmosphere general circulation model. In the global average, the near-surface temperature rises by 2.6 K in Scenario A and by 0.6 K in Scenario D. The global patterns of climate change for both IPCC scenarios and for a third step-function 2 x CO₂ experiment were found to be very similar. The warming delay over the oceans is larger than found in simulations with atmospheric general circulation models coupled to mixed-layer models, leading to a more pronounced land-sea contrast and a weaker warming (and in some regions even an initial cooling) in the Southern Ocean. During the first forty years, the global warming and sea level rise due to the thermal expansion of the ocean are significantly slower than estimated previously from box-diffusion-upwelling models, but the major part of this delay can be attributed to the previous warming history prior to the start of present coupled ocean-atmosphere model integration (cold start).     

Evidence for Holocene environmental changes in the northern Fertile Crescent provided by pedogenic carbonate coatings

Holocene environmental changes in the northern Fertile Crescent remain poorly understood because of the scarcity of local proxy records in the region. In this study we investigated pedogenic (soil-formed) carbonate coatings on stones at the Pre-Pottery Neolithic site Göbekli Tepe as an indicator of local early-mid Holocene environmental changes. The ¹⁴C ages and stable isotopic composition of carbon and oxygen in thin (0.2–0.3 mm thick) pedogenic carbonate lamina indicate two main periods of coating formation: the early-Holocene (ca. 10000–6000 cal yr BP) and the mid-Holocene (ca. 6000–4000 cal yr BP). During the first period, there was an inverse relationship between δ¹³C and δ¹⁸O curves: a decrease in δ¹³C values coincide with an increase in δ¹⁸O values. For this period a trend towards higher temperatures is suggested. In the mid-Holocene, the mean rate of coating growth was 2–3 times higher than in the early Holocene. Both δ¹³C and δ¹⁸O reached their maximum values during this time and the direction of changes of the δ¹³C and δ¹⁸O curves became similar. The combination of data suggests that this period was the most humid in the Holocene and on average warmer than the early Holocene. At ca. 4000 cal yr BP secondary accumulation of carbonate ceased, presumably reflecting a shift to a more arid climate.     

Calcium Isotopes (δ44/40Ca) in MPI-DING Reference Glasses, USGS Rock Powders and Various Rocks: Evidence for Ca Isotope Fractionation in Terrestrial Silicates

We report δ^44/40Ca_{(SRM 915a)} values for eight fused MPI‐DING glasses and the respective original powders, six USGS igneous rock reference materials, the U‐Th disequilibria reference material TML, IAEA‐CO1 (Carrara marble) and several igneous rocks (komatiites and carbonatites). Sample selection was guided by three considerations: (1) to address the need for information values on reference materials that are widely available in support of interlaboratory comparison studies; (2) support the development of in situ laser ablation and ion microprobe techniques, which require isotopically homogenous reference samples for ablation; and (3) provide Ca isotope values on a wider range of igneous and metamorphic rock types than is currently available in the scientific literature. Calcium isotope ratios were measured by thermal ionisation mass spectrometry in two laboratories (IFM‐GEOMAR and Saskatchewan Isotope Laboratory) using ⁴³Ca/⁴⁸Ca‐ and ⁴²Ca/⁴³Ca‐double spike techniques and reported relative to the calcium carbonate reference material NIST SRM 915a. The measurement uncertainty in both laboratories was better than 0.2‰ at the 95% confidence level. The impact of different preparation methods on the δ^44/40Ca_{(SRM 915a)} values was found to be negligible. Except for ML3‐B, the original powders and the respective MPI‐DING glasses showed identical δ^44/40Ca_{(SRM 915a)} values; therefore, possible variations in the Ca isotope compositions resulting from the fusion process are excluded. Individual analyses of different glass fragments indicated that the glasses are well homogenised on the mm scale with respect to Ca. The range of δ^44/40Ca_{(SRM 915a)} values in the igneous rocks studied was larger than previously observed, mostly owing to the inclusion of ultramafic rocks from ophiolite sections. In particular, the dunite DTS‐1 (1.49 ± 0.06‰) and the peridotite PCC‐1 (1.14 ± 0.07‰) are enriched in ⁴⁴Ca relative to volcanic rocks (0.8 ± 0.1‰). The Carrara marble (1.32 ± 0.06‰) was also found to be enriched in ⁴⁴Ca relative to the values of assumed precursor carbonates (< 0.8‰). These findings suggest that the isotopes of Ca are susceptible to fractionation at high temperatures by, as yet, unidentified igneous and metamorphic processes.     

Organic geochemical investigation of far-field tsunami deposits of the Kahana Valley,O‘ahu,Hawai‘i

Far-field tsunami deposits observed in the Kahana Valley, O‘ahu, Hawai‘i (USA), were investigated for their organic-geochemical content. During short high-energy events, (tsunamis and storms) organic and chemical components are transported with sediment from marine to terrestrial areas. This study investigates the use of anthropogenic based organic geochemical compounds (such as polycyclic aromatic hydrocarbons, pesticides and organochlorides) as a means to identify tsunami deposits. Samples were processed by solid–liquid extraction and analyzed using gas chromatography–mass spectrometry. A total of 21 anthropogenic marker compounds were identified, of which 11 compounds were selected for detailed analysis. Although the tsunami deposits pre-date industrial activity in Hawai‘i by several hundred years, distinct changes were found in the concentrations of anthropogenic marker compounds between sandy tsunami deposits and the surrounding mud/peat layers, which may help in identifying tsunami deposits within cores. As expected, low overall concentrations of anthropogenic markers and pollutants were observed due to the lack of industrial input-sources and little anthropogenic environmental impact at the study site. This geochemical characterization of tsunami deposits shows that anthropogenic markers have significant potential as another high-resolution, multi-proxy method for identifying tsunamis in the sedimentary record.     

Average ice crystal size and bulk short-wave single-scattering properties of cirrus clouds

The bulk single-scattering properties of cirrus clouds required for driving the radiation scheme in large-scale climate models are computed with respect to various size distributions and ice crystal shapes. It is shown that the average ice crystal size, defined as the ratio of total volume to the total projected area, can well-characterize the effect of various size distributions in determining the bulk radiative properties of cirrus clouds. Details of the size distributions are not significant in specifying the radiative properties of these clouds if the effective average size is thus defined. Therefore, the ratio of the total volume to the total projected area is an ideal parameter for describing the bulk single-scattering properties. The effect of ice crystal shape is not critical in the parameterization of the extinction coefficient and single-scattering albedo. However, the various crystal habits must be accounted for in the parameterization of the asymmetry parameter. The resulting parameterization is intended for radiative transfer calculations involving cirrus clouds in large-scale models.     

Formation of feldspathic and metallic melts by shock in enstatite chondrite Reckling Peak A80259

Abstract— The enstatite chondrite reckling peak (rkp) a80259 contains feldspathic glass, kamacite, troilite, and unusual sets of parallel fine‐grained enstatite prisms that formed by rapid cooling of shock melts. Metallic Fe,Ni and troilite occur as spherical inclusions in feldspathic glass, reflecting the immiscible Fe‐Ni‐S and feldspathic melts generated during the impact. The Fe‐Ni‐S and feldspathic liquids were injected into fractures in coarse‐grained enstatite and cooled rapidly, resulting in thin (≤ 10 μm) semicontinuous to discontinuous veins and inclusion trails in host enstatite. Whole‐rock melt veins characteristic of heavily shocked ordinary chondrites are conspicuously absent. Raman spectroscopy shows that the feldspathic material is a glass. Elevated MgO and SiO₂ contents of the glass indicate that some enstatite and silica were incorporated in the feldspathic melt. Metallic Fe,Ni globules are enclosed by sulfide and exhibit Nienrichment along their margins characteristic of rapid crystallization from a Fe‐Ni‐S liquid. Metal enclosed by sulfide is higher in Si and P than metal in feldspathic glass and enstatite, possibly indicating lower O fugacities in metal/sulfide than in silicate domains. Fine‐grained, elongate enstatite prisms in troilite or feldspathic glass crystallized from local pyroxene melts that formed along precursor grain boundaries, but most of the enstatite in the target rock remained solid during the impact and occurs as deformed, coarsegrained crystals with lower CaO, Al₂O₃, and FeO than the fine‐grained enstatite. Reckling Peak A80259 represents an intermediate stage of shock melting between unmelted E chondrites and whole‐rock shock melts and melt breccias documented by previous workers. The shock petrogenesis of RKPA80259 reflects the extensive impact processing of the enstatite chondrite parent bodies relative to those of other chondrite types.     

North-east Greenland Shelf north of 79°N: results of a reflection seismic experiment in sea ice

The first multichannel seismic reflection measurements of the north-east Greenland shelf north of 79°N were made as part of the R.V. Polarstern cruise ARK V/1988. This area is perennially covered by sea ice. The sparse seismic data show a very deep rift basin filled with up to 10 km of high velocity rocks interpreted as Carboniferous and Permian sediments. Conspicuous structures interpreted as marginal reefs are associated with the western flank of the rift basin.     

A regional-scale climate reconstruction of the last 4000 years from lakes in the Nebraska Sand Hills,USA

High-resolution paleohydrological reconstructions were carried out in five shallow lakes in the Nebraska Sand Hills across an east–west transect in order to 1) determine whether long-term droughts of the past 4000 years were spatially and temporally coherent across the region, 2) distinguish local variation in climate or hydrology from regional patterns of change, and 3) compare the paleolimnological results with the existing dune-inferred drought records. Diatom-inferred lake-level was reconstructed for all sites and compared with other regional records. Alterations between high and low lake-levels were frequent during the past 4000 years, which suggests that shifts between dry and wet periods were prevalent across the Sand Hills. Extended multi-decadal to centennial-scale droughts were more common prior to 2000 years BP, while the last two millennia were hydrologically more variable and climate conditions alternated on shorter timescales. Despite some discrepancies among the five records, the paleohydrological reconstructions refine the Holocene drought history of the Nebraska Sand Hills, particularly between ～2200 and 4000 cal a BP. Many of the observed drought events are contemporaneous with severe droughts documented at sites in the northern Great Plains and Rocky Mountains, lending support for the severity and regional significance of these events in western North America.     

Stage‐dependent transient storage of phosphorus in alluvial floodplains

Models for contaminant transport in streams commonly idealize transient storage as a well mixed but immobile system. These transient storage models capture rapid (near‐stream) hyporheic storage and transport, but do not account for large‐scale, stage‐dependent interaction with the alluvial aquifer. The objective of this research was to document transient storage of phosphorus (P) in coarse gravel alluvium potentially influenced by large‐scale, stage‐dependent preferential flow pathways (PFPs). Long‐term monitoring was performed at floodplain sites adjacent to the Barren Fork Creek and Honey Creek in northeastern Oklahoma. Based on results from subsurface electrical resistivity mapping which was correlated to hydraulic conductivity data, observation wells were installed both in higher hydraulic conductivity and lower hydraulic conductivity subsoils. Water levels in the wells were monitored over time, and water samples were obtained from the observation wells and the stream to document P concentrations at multiple times during high flow events. Contour plots indicating direction of flow were developed using water table elevation data. Contour plots of total P concentrations showed the alluvial aquifer acting as a transient storage zone, with P‐laden stream water heterogeneously entering the aquifer during the passage of a storm pulse, and subsequently re‐entering the stream during baseflow conditions. Some groundwater in the alluvial floodplains had total P concentrations that mirrored the streams' total P concentrations. A detailed analysis of P forms indicated that particulate P (i.e. P attached to particulates greater than 0·45 µm) was a significant portion of the P transport. This research suggests the need for more controlled studies on stage‐dependent transient storage in alluvial systems. Copyright © 2011 John Wiley & Sons, Ltd.