Environmental policy as a factor in a new security policy

Environmental policy is increasingly becoming an indispensable part of modern policy to maintain peace and security. After the end of the East-West conflict, a new cold war between North and South is looming on the horizon. It is caused by a steadily widening gap between the poverty of the South and the wealth of the North, which has been gained not least at the expense of the environment worldwide, and thus also of the South.There is a need for a parallel development between the disarmament process in the classical sense and a disarmament process in a material sense to promote an economic, social and ecological development which is consistent in itself and coordinated with regard to its effects.Appropriate instruments to achieve this, besides international conventions, include the opening up of markets, ecologically honest prices, technical cooperation and not least the enforcement of environmentally compatible and resource-saving forms of industry and ways of life in the industrialised countries.     

Proterozoic metavolcanics from western Sierras Pampeanas terrane, Argentina

A series of medium grade metamorphic rocks of the western sector of the Sierras Pampeanas Terrane in central western Argentina are represented by amphibolites, gneisses and schists derived from sedimentary as well as from igneous rocks. The metavolcanics consist of amphibolites, quartz-K-feldspar-muscovite schists, and hornblende-biotite and biotite-epidote-plagioclase schists. Based on petrographic and geochemical data they are interpreted as originating as basaltic tholeiites, rhyolites and mesosilicic volcanics. The distribution and geochemical behavior are similar to present day western Pacific lavas, mainly those developed on island arcs or heavily attenuated continental crust. Based on these characteristics, an accretionary tectonic model involving a series of island-arc collisions is proposed for the Proterozoic. The complex Proterozoic tectonic history of the western Sierras Pampeanas has been partially obliterated by the emplacement of the Early Paleozoic magmatic arc rocks.     

Copper(II) carbonate complexation in seawater

Cupric carbonate and cupric bicarbonate complexation constants were determined in natural seawater and in a variety of synthetic media. The formation constants of CuHCO₃⁺, CuCO₃⁰ and Cu(CO₃)₂^2? at 25°C and zero ionic strength are: log β_H⁰ = 1.8, log β₁⁰ = 6.82 and log β⁰₂ = 10.6. Formation constants of these species appropriate to 0.7 molar ionic strength and 25°C are log β_H ～- 1, log β₁ = 5.73, log β₂ = 9.3. Our results indicate that the inorganic speciation scheme of Cu(II) in seawater is dominated by CuCO₃⁰ and that the ternary species, CuCO₃OH^?, is of substantial importance.     

Distribution of forms of sulfur in peats from saline environments in the Florida Everglades

Although there is published information on the mechanism of sedimentary pyrite formation resulting from bacterial reduction of sulfate, little is known about the distribution of forms of sulfur, including organic, in peats. In order to increase understanding of the geochemistry of sulfur in coals, we have determined distributions of forms of sulfur in five cores of saline peat and one of brackish peat, all from areas near the Shark River and Whitewater Bay in the coastal swamps of south Florida. All concentrations vary widely with depth. Total sulfur concentrations range up to 6% of dry solids. Minor amounts of sulfur are present as H₂S, S⁰, SO₄²⁻, and acid-soluble sulfide, but the principal forms are usually pyritic and organic. The ratio, organic/pyritic, is highly variable, but at a majority of levels in a profile is considerably greater than unity. It is inferred that topochemical factors are important in determining the distribution of sulfur forms in any element of volume.     

Aminostratigraphy of European marine interglacial deposits

Molluscan fossils collected from shallow water marine sediment across NW Europe and nearby Arctic regions have been analysed for the extent of isoleucine epimerization ( ratio) in indigenous protein residues. The ratios confirm that essentially all ‘classical’ Eemian sites from NW Europe are of the same age, and are correlative with the type locality near Amersfoort in the Netherlands; shells from interglacial marine sediment beneath the type Weichselian till in Poland also correlate with the type Eemian site. ratios in Holsteinian marine shells (0.29) are substantially higher than in their Eemian counterparts (0.17); ‘Late Cromerian’ shells yield even higher ratios (0.46). ratios in late glacial shells (0.06) and Middle Weichselian shells (0.09) permit differentiation from modern (0.01) and last interglacial material. Based on the position of the Matuyama-Brunhes boundary and the differences in ratios, the Eemian must correlate with isotope substage 5e, whereas the Holsteinian is most likely substage 7c, possibly stage 9 but certainly younger than stage 11. Intra-Saalian warm periods may be terrestrial equivalents of the younger substages of stage 7. Extensive pre-Eemian marine sediments along the SW coast of Denmark previously correlated with the Holsteinian are shown to be of ‘Late Cromerian’ age. The underlying till there is the first widespread evidence of a pre-Elsterian till in NW Europe. ratios in molluscs from last interglacial sites along the Arctic coast of the USSR, the Arctic Islands and eastern Greenland are substantially lower than in their European counterparts due to their low thermal histories. The combined mid- and high-latitude data are used to develop a predictive model for the expected ratio in any of several moderate epimerization-rate taxa for last interglacial sites with mean temperatures between −20 and +15°C.Not all sites could be unambiguously assigned to an established interglacial. The Fjøsanger (Norway) and Margareteberg (Sweden) sites previously thought to be Eemian, yield ratios higher than in secure nearby Eemian material. It is yet unresolved whether these are aberrant sites or if they predate the last interglacial. In situ shoreline deposits encountered in borings in SW Belgium and in exposures on the Belgium coastal plain contain molluscs that yield ratios intermediate between secure Eemian and Late Weichselian ratios, raising the possibility that a late stage 5 high-sea-level event attained near-modern levels in the southern North Sea basin. Resolution of these uncertainties is the focus of future work.     

Anisotropy in the Ironton and Galesville Sandstones Near a Thermal-Energy-Storage Well, St. Paul, Minnesota

The U.S. Geological Survey is studying the potential for storage of heated water in a sandstone aquifer in St. Paul, Minnesota. The efficiency of the aquifer to store thermal energy is related, in part, to the hydrogeologic characteristics of the aquifer. The movement of heat away from the injection well is directly related to the anisotropy. Aquifer tests were conducted to determine the anisotropy near the heated-water injection well. The maximum and minimum values of transmissivity along the principal directions of the hydraulic conductivity tensors of the Ironton and Galesville Sandstones in St. Paul, Minnesota are approximately 1,090 and 480 feet squared per day. The storage coefficient is 4.5 × 10⁻⁵. These values represent the average of four determinations of nonsteady flow to a well in an idealized infinite anisotropic aquifer. Analysis of the values of transmissivity and storage coefficient for hypothetical changes in location of two of the monitoring wells where depth-deviation surveys were not available indicates that computed transmissivities vary less than 5 percent and storage coefficients vary less than ±6 percent.     

The Application of Telemetry to Large-Scale Horizontal Anisotropic Permeability Determinations by Surface Tiltmeter Survey

An advanced two-way radio link (transceiver units) and data logging system have provided a powerful means of real-time series data collection and analysis. The application of this telemetry system to surface tiltmeter surveys provides significant cost savings for testing and analysis of deep, large-scale horizontal anisotropic permeability and heterogeneity determinations.
The determination of horizontal anisotropic properties requires one pumping well and eight to 10 tiltmeter monitoring stations. The validity of the depth of the test may reach 4,000 feet below land surface. With the addition of one partially penetrating observation well, the entire three-dimensional anisotropic permeability can be determined. With the addition of a fully penetrating well, the storage coefficient can be determined as well as leakage property (including vertical permeability of the confining layers). An example test case was analyzed for horizontal anisotropic permeability with remarkable success despite relatively unfavorable detection conditions.
A thorough understanding of the geology overlying the aquifer system must be made in order to assess the applicability of the surface tiltmeter survey to large-scale horizontal anisotropic permeability determinations.