Lithic fragments,glasses and chondrules from Luna 16 fines

Bulk compositions of igneous and microbreccia lithic fragments, glasses, and chondrules from Luna 16 fines as well as compositions of minerals in basaltic lithic fragments were determined with the electron microprobe. Igneous lithic fragments and glasses are divided into two groups, the anorthositic-noritic-troctolitic (hereafter referred to as ANT) and basaltic groups. Chondrules are always of ANT composition and microbreccia lithic fragments are divided into groups 1 and 2. The conclusions reached may be summarized as follows: (1) Luna 16 fines are more similar in composition to Apollo 11 than to Apollo 12 and 14 materials (e.g. Apollo 11 igneous lithic fragments and glasses fall into similar ANT and basaltic groups; abundant norites in Luna 16 and Apollo 11 are not KREEP as in Apollo 12 and 14; Luna 16 basaltic lithic fragments may represent high-K and low-K suites as is the case for Apollo 11; rare colorless to greenish, FeO-rich and TiO₂-poor glasses were found in both Apollo 11 and Luna 16; Luna 16 spinels are similar to Apollo 11 spinels but unlike those from Apollo 12). (2) No difference was noted in the composition of lithic fragments, glasses and chondrules from Luna 16 core tube layers A and D. (3) Microbreccia lithic fragments of group 1 originated locally by mixing of high proportions of basaltic with small proportions of ANT materials. (4) Glasses are the compositional analogs to the lithic fragments and not to the microbreccias; most glasses were produced directly from igneous rocks. (5) Glasses show partial loss of Na and K due to vaporization in the vitrification process. (6) Luna 16 chondrules have ANT but not basaltic composition. It is suggested that either liquid droplets of ANT composition are more apt to nucleate from the supercooled state; or basaltic droplets have largely been formed in small and ANT droplets in large impact events (in the latter case, probability for homogeneous and inhomogeneous nucleation is larger. (7) No evidence for ferric iron and water-bearing minerals was found. (8) Occurrence of a great variety of igneous rocks in Luna 16 samples (anorthosite, noritic anorthosite, anorthositic norite, olivine norite, troctolite, and basalt) confirm our earlier conclusion that large-scale melting or partial melting to considerable depth and extensive igneous differentiation must have occurred on the moon.     

On the stability of the solar wind

The stability of the solar wind is studied in the case of spherical symmetry and constant temperature. It is shown that the stability problem must be formulated as a mixed initial and boundary-value problem in which are prescribed the perturbation values of velocity and density at an initial time and additionally the velocity perturbation at the base of the corona for all times. The solution is constructed by linear superposition of normal solutions, which contain the time only in an exponential factor. The stability problem becomes a singular eigenvalue problem for the amplitudes of the velocity and pressure perturbations, since additionally to the boundary condition at the base of the corona one must add the condition that the amplitudes behave regularly at the critical point. It is proved that only stable eigenvalues exist.     

Magma mixing as the probable origin of some Permian volcanic rocks of the Saar-Nahe-Basin (SW-Germany)

Some Permian calc-alkaline rocks of the Saar-Nahe-Basin are briefly described and their origin is discussed in the light of a magma-mixing model for the intermediate members. The model is based on high trace element concentrations of Ni, Cr, Rb, Sr, Zr and Nb, straight-line chemical variations, mineralogical features and stratigraphie sequence of the volcanic rocks. The model is in accord with a geodynamic model for the Hercynian belt as suggested by Lorenz & Nicholls (in prep.).     

Ein stratiformes Fluoritvorkommen im Zechsteindolomit bei Eschwege und Sontra in Hessen

Zusammenfassung Im Hauptdolomit (Ca₂) und im Plattendolomit (Ca₃) des mittleren Zechsteins bei Eschwege und Sontra in Hessen wurde 1974 erstmals Fluorit entdeckt. Durch Bohrungen, chemische und geochemische Untersuchungen konnte nachgewiesen werden, daß im Hauptdolomit der Fluorit schichtgebunden, gelegentlich in dunklen Lagen und Linsen bis 0,5 m mächtig, makroskopisch sichtbar auftritt. Häufiger kommt er in 18–20 m mächtigen Zonen vor, die aber wegen des geringen Fluoritgehaltes von unter 10 % CaF₂ sich von dem grauweißen Dolomit ohne Fluorit nicht unterscheiden.In den dunklen bis schwarz gefärbten Lagen schwanken die Fluoritgehalte zwischen 10 und 50 % CaF₂. Einzelproben enthalten bis 80 % CaF₂. Die Dunkelfärbung ist teils durch den Gehalt von violettem Fluorit, mehr noch durch Bitumen bedingt.Fluorit wurde ferner im stratigraphisch höher gelegenen Plattendolomit (Ca₃) der Leine-Serie Z3 gefunden. In Aufschlüssen und Steinbrüchen in der Nähe von Sontra enthält der Plattendolomit lokal 1–4 % CaF₂.Die makro- und mikroskopisch sichtbare Wechsellagerung von Fluorit und Dolomit mit einem deutlichen Lagengefüge und das Fehlen von hydrothermalem Fluorit und anderen Mineralien auf Gängen und Klüften sind Beweise für eine synsedimentäre Bildung des Fluorites im Hauptdolomit (Ca₂) und Plattendolomit (Ca₃) in Hessen. Für den Hauptdolomit wird angenommen, daß er spätdiagenetisch entstanden ist. Dies dürfte auch für den Fluorit zutreffen. Als Bildungsbereich werden flache Lagunen mit salinärer Fazies angenommen. Das Fluor stammt aus dem normalen Gehalt des Meerwassers. Es muß aber angenommen werden, daß der Fluorgehalt des Meerwassers durch Zufuhr von Fluor aus dem Festlande, z. B. aus den fluorreichen Graniten des Harzes merklich erhöht wurde. Nur so sind die großen Fluoritmengen im Zechsteindolomit in Hessen zu erklären. Sie werden auf 5–7·10⁶ + CaF₂ geschätzt.

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In 1974, fluorite was detected for the first time in the Hauptdolomit (Ca₂) and in the Plattendolomit (Ca₃) of the Middle Zechsteinformation near Eschwege and Sontra, Hessia. It was confirmed by means of drilling, chemical and geochemical investigations that the fluorite in the Hauptdolomit is stratabound. It occurs both locally in the form of macroscopic dark layers and lenses of up to 0,5 m thickness and moreoften, as zones up to 18–20 m thick which cannot macroscopically be distinguished from the greyish white dolomite without fluorite because of the low CaF₂ content (less than 10 %).The fluorite contents vary between 10 an 50 % CaF₂ in the dark black layers. Special samples may contain up to 80 % CaF₂. The dark colour derives partly from the lilac fluorite but to a greater degree from bitumous material.Fluorite has also been detected in the stratigraphically higher Plattendolomit (Ca₃) of the Leine-Series Z 3. Outcrops and quarries near Sontra have local contents of 1–4 % CaF₂.The macroscopic and microscopic interstratification of fluorite and dolomite with clear layer textures and the absence of hydrothermal fluorite and other minerals in veins of fissures are evidence for a synsedimentary formation of the fluorite in the Hauptdolomit (Ca₂) and the Plattendolomit (Ca₃). The Hauptdolomit is thought to have developed during late diagenesis. This should be valid for the fluorite, too. Shallow lagoons of a salinar facies are thought to have been the depositional environment. The fluorite precipitated from the sea waters, which were apparently enriched in fluorine by erosion at the fluorine rich granites of the Harz mountains. This is the only obvious explanation of the large amounts of fluorine in the Zechstein dolomite, estimated at 5–7×10⁶ tonnes CaF₂.

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Résumé En 1974, de la fluorine fut découverte dans la dolomie dite »Hauptdolomit« (Ca₂) et dans la dolomie dite »Plattendolomit» (Ca₃) du Zechstein moyen, près d'Eschwege et de Sontra, en Hesse. Les sondages effectués ainsi que les analyses chimiques et géochimiques ont montré que la fluorine se rencontre de façon stratiforme dans la »Hauptdolomit«, quelquefois en couches et lentilles foncées d'une épaisseur maximale de 0,5 m, ou elle est visible macroscopiquement. La fluorine est souvent présente en faibles teneurs (moins de 10% de CaF₂) dans des couches de 18 à 20 m d'épaisseur; de ce fait, ces dernières ne se distinguent pas de la dolomie gris-blanche exempte de fluorine.La teneur en fluorine varie de 10 % à 50% de CaF₂ dans les couches foncées à noires. Certains échantillons renferment jusqu'à 80% de CaF₂. La coloration foncée est due en partie à la fluorine violette, mais plus encore à la présence de bitume.De la fluorine fut également localisée dans la »Plattendolomit« (Ca₃) de la »LeineSerie Z 3«, qui est située à un niveau stratigraphique supérieur. Cette »Plattendolomit« telle qu'on la rencontre dans les affleurements et carrières des environs de Sontra, contient de 1–4% de CaF₂.L'alternance de fluorine et de dolomie qui, avec sa structure en couches nettement développées, est visible tant macroscopiquement que microscopiquement, ainsi que l'absence de fluorine hydrothermale et d'autres minéraux dans les filons et cassures, sont considérées comme preuves de la formation syn-sédimentaire de la fluorine dans la »Hauptdolomit« (Ca₂) et dans la »Plattendolomit« (Ca₃) de la Hesse. On suppose que la formation de la »Hauptdolomit« est diagénétique tardive. Cette hypothèse devrait également s'appliquer à la fluorine. Il est probable que ce processus a eu lieu dans les lagunes peu profondes à faciès salin. Le fluor provient de l'eau de mer à teneur normale. On peut cependant supposer que la teneur en fluor de l'eau de mer s'est accrue suite à l'apport de fluor provenant du continent, p.ex. à partir de granites riches en fluor du Harz. C'est seulement ainsi que peuvent s'expliquer les grandes quantités de fluorine de la dolomie du Zechstein, en Hesse. Elles sont évaluées entre 5 et 7 · 10⁶ de CaF₂.

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(Ca₂) (Ca₃) . , , , 0,5 . 18–20 , - — CaF₂ 10% — , . 10 50% CaF₂. 80% CaF₂. , . (Ca₃). 1–4% CaF₂. , , ; , . , Ca₂ . . , . . , ., , . . 5–7 × 10⁶ CaF₂.

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Unserem Lehrer, Herrn Professor Dr. Georg Fischer, München, zum 80. Geburtstag gewidmet.     

Boundary-layer diffusion modelling: The Gaussian plume approach versus the spectral solution

The equation of turbulent diffusion is solved for a vertical area source within the planetary boundary layer. The traditional Gaussian-plume approach is compared with the spectral solution of the diffusion equation used together with the barotropic boundary-layer model of Lettau and Dabberdt (1970). The results of the numerical computations are presented and the differences between the solutions are discussed.