Multi‐method virtual electromagnetic experiments for developing suitable monitoring designs: A fictitious CO2 sequestration scenario in Northern Germany

We present a numerical study for 3D time‐lapse electromagnetic monitoring of a fictitious CO₂ sequestration using the geometry of a real geological site and a suite of suitable electromagnetic methods with different source/receiver configurations and different sensitivity patterns. All available geological information is processed and directly implemented into the computational domain, which is discretized by unstructured tetrahedral grids. We thus demonstrate the performance capability of our numerical simulation techniques. The scenario considers a CO₂ injection in approximately 1100 m depth. The expected changes in conductivity were inferred from preceding laboratory measurements. A resistive anomaly is caused within the conductive brines of the undisturbed reservoir horizon. The resistive nature of the anomaly is enhanced by the CO₂ dissolution regime, which prevails in the high‐salinity environment. Due to the physicochemical properties of CO₂, the affected portion of the subsurface is laterally widespread but very thin. We combine controlled‐source electromagnetics, borehole transient electromagnetics, and the direct‐current resistivity method to perform a virtual experiment with the aim of scrutinizing a set of source/receiver configurations with respect to coverage, resolution, and detectability of the anomalous CO₂ plume prior to the field survey. Our simulation studies are carried out using the 3D codes developed in our working group. They are all based on linear and higher order Lagrange and Nédélec finite‐element formulations on unstructured grids, providing the necessary flexibility with respect to the complex real‐world geometry. We provide different strategies for addressing the accuracy of numerical simulations in the case of arbitrary structures. The presented computations demonstrate the expected great advantage of positioning transmitters or receivers close to the target. For direct‐current geoelectrics, 50% change in electric potential may be detected even at the Earth's surface. Monitoring with inductive methods is also promising. For a well‐positioned surface transmitter, more than 10% difference in the vertical electric field is predicted for a receiver located 200 m above the target. Our borehole transient electromagnetics results demonstrate that traditional transient electromagnetics with a vertical magnetic dipole source is not well suited for monitoring a thin horizontal resistive target. This is due to the mainly horizontal current system, which is induced by a vertical magnetic dipole.     

The Deformational Response of a Viscoelastic Solid Earth Model Coupled to a Thermomechanical Ice Sheet Model

We apply a coupled thermomechanical ice sheet—self-gravitating viscoelastic solid Earth model (SGVEM), allowing for the dynamic exchange of ice thickness and bedrock deformation, in order to investigate the effect of viscoelastic deformation on ice dynamics and vice versa. In a synthetic glaciation scenario, we investigate the interaction between the ice sheet and the solid Earth deformation, the glacial-isostatic adjustment (GIA), accounting for an atmospheric forcing depending on the ice sheet surface altitude. We compare the results from the coupled model to runs with the common elastic lithosphere/relaxing asthenosphere (ELRA) model, where the lithosphere is represented by a thin plate and the mantle relaxes with one characteristic relaxation time, as well as to a rigid Earth without any deformation. We find that the deformational behaviour of the SGVEM on ice dynamics (i.e. stored ice volume, ice thickness and velocity field) is comparable to the ELRA for an optimal choice of the parameters in steady state, but exhibits differences in the transient behaviour. Beyond the ice sheet, in the region of peripheral forebulge, the differences in the transient surface deformation between ELRA and SGVEM are substantial, demonstrating the inadequacy of the ELRA model for interpreting constraints on GIA in the periphery of the ice sheet, such as sea-level indicators and GPS uplift rates.     

Analysis of low-flow characteristics for catchments in Dongjiang Basin, China

Low-flow indices have been determined from long-term daily streamflow data for 13 catchments in Dongjiang Basin in southern China. The Brutsaert-Nieber method was applied to estimate catchment-scale effective groundwater parameters; representative values were 4.5?×?10^?4 m² s^?1 for the hydraulic diffusivity; 3.19?×?10^?5 m² s^?1/2 for the hydraulic desorptivity; 2.27?×?10^?4 m s^?1 for the hydraulic conductivity; and 0.2617 for the drainable porosity. The response constants correlate well with the total stream length and catchment area. Solutions of the linearised Boussinesq equation were used to guide the development of regional multivariate regression models for estimating low-flow indices from the catchment-scale effective parameters. Results showed that these catchments exhibit similar low-flow characteristics. The 7-day lowest average streamflows with return periods of 10 and 2 years (7Q10 and 7Q2) are highly correlated with the catchment-scale response constants. The low-flow ratio Q95/Q50 (ratio of daily streamflow exceeded 95 and 50% of the time, respectively) varied between 0.3 and 0.5, indicating a high proportion of groundwater in the streamflow. The advantage of the regional regression model is its conceptual basis and use of the catchment-scale effective parameters. The method has the potential to be applied to ungauged catchments for estimating low-flow statistics from stream length and catchment area.     

Comparison of an Electrochemical and Luminescence‐Based Oxygen Measuring System for Use in the Biodegradability Testing According to Closed Bottle Test (OECD 301D)

The effects of persistent organic pollutants on the aquatic environment still can hardly be assessed. Therefore, ready biodegradability is a desired key characteristic of chemicals. Accordingly, biodegradation testing is of utmost importance and is a vital part within the risk assessment for organic chemicals. In the closed bottle test (CBT; OECD 301D) the degree of biological degradation of a chemical is assessed by monitoring the oxygen consumption so far with a Clark electrode as standard method. However, this method is time‐consuming, laborious and led to frequent fluctuations of the test results, which limited their validity. Due to these shortcomings, an optical system that enables contact‐free measuring of the oxygen concentration in a closed bottle, based on dynamic luminescence quenching, was examined. The test results were compared to those obtained with the “classical” electrochemical technique (Clark electrode). At first, a basic standard for the handling of the new instrument in the laboratory was developed. Then possible influencing factors, reliability, comparability, and reproducibility of the test results were investigated by running the CBTs in parallel with the electrode and optode method. The findings proved the new optode method to be unambiguously superior to the electrode technique. The frequency of fluctuations of the test results and time and effort necessary for the test run could considerably be reduced. The degradation kinetics of the test substances could be followed easily in the CBT by increasing the measuring points without much additional effort.     

Simultaneous Determination of 11 Sulfonamides by HPLC–UV and Application for Fast Screening of Their Aerobic Elimination and Biodegradation in a Simple Test

Sulfonamides (SAs) are one of the most frequently used antibiotics. SAs have been found in various environmental compartments. If SAs are not degraded in the environment, they can affect bacteria by their antibiotic properties and contribute to bacterial antibiotic resistance. Therefore, the biodegradability of 11 SAs (sulfanilamide, sulfaguanidine monohydrate, sulfadiazine, sulfathiazole, sulfapyridine, sulfamerazine, sulfamethoxypyridazine, sulfachloropyridazine, sulfamethazine, sulfamethoxazole, and sulfadimethoxine) was studied. For this purpose, the Closed Bottle Test (CBT, OECD 301D) was performed, which includes a toxicity control. In order to monitor the environmental fate of the parent compound and to check for transformation products, a simple, efficient, and reliable HPLC–UV method for the simultaneous determination of these SAs has been developed. Acetonitrile and water (with 0.1% formic acid) were used as mobile phase solvents for gradient elution. The method was validated in terms of precision, detection and quantitation limits, selectivity, and analytical solution stability. In the CBT, none of these SAs was readily biodegradable. The HPLC–UV analysis confirmed that no degradation of any SA took place. In the toxicity control, these SAs showed no toxic effect in the used concentration of environmental bacteria applied in the test.     

Rockfall Hazard Analysis From Discrete Fracture Network Modelling with Finite Persistence Discontinuities

Developing an accurate representation of the rock mass fabric is a key element in rock fall hazard analysis. The orientation, persistence and density of fractures control the volume and shape of unstable blocks or compartments. In this study, the discrete fracture modelling technique and digital photogrammetry were used to accurately depict the fabric. A volume distribution of unstable blocks was derived combining polyhedral modelling and kinematic analyses. For each block size, probabilities of failure and probabilities of propagation were calculated. A complete energy distribution was obtained by considering, for each block size, its occurrence in the rock mass, its probability of falling, its probability to reach a given location, and the resulting distribution of energies at each location. This distribution was then used with an energy–frequency diagram to assess the hazard.     

Chemical characteristics (REE,etc.) of Paleozoic and Mesozoic graywackes and sandstones from Central Europe

During the Variscan orogeny in Central Europe, partial melting in the lower continental crust formed granitic magmas, which intruded into the upper crust and left compounds of Ca (plus Eu²⁺), Mg, etc. in the lower crust. From the late Paleozoic decomposition of the tonalitic upper crust, sedimentary graywackes were produced reflecting the composition of this crust. The repeated reworking of the sedimentary cover caused the formation of sands. Sandstones as their products of consolidation contain increasing fractions of quartz and decreasing feldspar from Carboniferous and Triassic to Cretaceous age. A distinct negative Eu anomaly characterizes the majority of these rocks. The latter is imprinted by the Variscan magmatism. Quartz as used for numerous Medieval wood ash glasses is marked for its Central European origin by a distinct negative Eu anomaly in contrast to many soda glasses produced outside Germany mostly with a small or none Eu anomaly.