Attribution of uranium ore concentrates using elemental and anionic data

The capability to correctly identify the geological or geographical source of unknown uranium ore concentrates (UOCs) has obvious nuclear security benefits. This paper reports on a scoping study where the trace elemental and anionic compositions of 24 UOC samples, sourced mainly from mines in Australia and Canada, were examined for their ability to allow attribution of the sample to a particular geological U deposit type or to a particular geographical source. Results of statistical analysis using canonical analysis of principal coordinates (CAP) showed that samples originating from certain U ore deposit types, especially phosphorite and quartz-pebble conglomerate, contained a distinct impurity composition. Samples grouped according to their geographical region of origin appeared to contain distinctive impurities in certain cases (Elliot Lake and Bancroft, Ontario). The key impurities responsible for differentiating groups of samples from a particular geological deposit type were identified and the use of certain impurities as signatures of processing history is discussed. The methodology described in this scoping study provides a promising approach for more comprehensive databases.     

Seismic coda due to non-linear elasticity

Non-linear elastic response of rocks has been widely observed in laboratory, but very few seismic studies are reported in the literature, even though it is the most natural environment where this feature could be observed. Analytic solutions to the non-linear wave propagation phenomena are not readily available, and there is a need to use approximated techniques. It is clear that when a seismic wave propagates through a homogeneous non-linear elastic media, it will be perturbed by the non-linearity. This perturbation can be treated as a source of scattering, spreading the energy of the primary wave in space and time, contributing to the seismic coda. This is in some sense similar to the effect of heterogeneities. The properties of the coda due to the non-linearity depend on the amount of non-linearity and the seismic moment. Using a perturbation approach we calculate the amplitude of the scattered waves, and show that it can describe reasonably well the main features of real seismic codas.     

Northwest Africa 2526: A partial melt residue of enstatite chondrite parentage

Abstract— NWA 2526 is a coarse‐grained, achondritic rock dominated by equigranular grains of polysynthetically twinned enstatite (?85 vol%) with frequent 120° triple junctions and ?10–15 vol% of kamacite + terrestrial weathering products. All other phases including troilite, daubreelite, schreibersite, and silica‐normative melt areas make up 相似文献   

Loss of optical and molecular indicators of terrigenous dissolved organic matter during long-term photobleaching

Two water samples from the Great Dismal Swamp National Wildlife Refuge with high dissolved organic matter (DOM) concentrations (51 and 121 mg C L^?1) were subjected to ultraviolet (UV) light for up to 110 days. During the course of the irradiations, 74–88 % of the original dissolved organic carbon was lost along with 95–99 % of the absorption at 300 nm. Based on changes observed during light exposure, three pools of DOM were identified: photo-labile, photo-refractory, and photo-produced compounds. Solid-state ¹³C nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR) spectroscopy were used to determine structural moieties characteristic to each of these pools. These analyses showed aromatic carbons were preferentially removed while carbohydrate-like and amide/peptide-like carbons were preserved during UV exposure. An increase in carbon normalized ¹³C NMR signal in the 0–50 ppm region suggests that alkyl moieties were produced, while FTIR signal at 1,745 cm^?1 and two-dimensional ¹H–¹³C NMR results confirmed the photochemical production of acetate. Several properties typically used to trace terrigenous DOM in ocean margin and marine environments were significantly altered. Optical properties, including absorption spectral slopes and fluorescence indices, as well as carbon-normalized lignin yields shifted from terrestrial values towards those more typical of coastal or open ocean samples. The loss of terrestrial signatures during irradiation highlights the difficulty faced when quantifying the contribution of terrigenous DOM to aquatic carbon pools.     

Precipitation climate of Central Asia and the large-scale atmospheric circulation

The precipitation climate in the larger Tian Shan region of Central Asia is described in terms of the climatological seasonal moisture fluxes and background circulation based on the ERA-40 reanalysis data and a precipitation reanalysis. The study area is partitioned into (1) the Tarim river basin, (2) bordering regions of China, Kyrgyzstan and Kazakhstan, and (3) Northwestern China. Moisture supply to these areas is primarily due to the midlatitude westerlies with contributions from higher latitudes. In addition, moisture from the Indian Ocean is notably imported into the Tarim drainage area. Monthly interannual precipitation variability relates to the variability of hemispheric circulation patterns. Extreme precipitation above and below normal in Western China and Central Asia is analyzed using the standardized precipitation index. Related circulation composites show that, despite regional and seasonal differences, episodes of extreme and severe dryness are dominated by various upstream standing wave patterns from the North Atlantic to Central Asia. These features extend further downstream to the North Pacific. Non-symmetry between wet and dry composites is noted upstream and in regional moisture flux composites.     

Transient response to well-mixed greenhouse gas changes

A change in CO₂ concentration induces a direct radiative forcing that modifies the planetary thermodynamic state, and hence the surface temperature. The infrared cooling, by assuming a constant temperature lapse-rate during the process, will be related to the surface temperature through the Stefan–Boltzmann law in a ratio proportional to the new infrared opacity. Other indirect effects, such as the water vapor and ice-albedo feedbacks, may amplify the system response. In the present paper, we address the question of how a global climate model with a mixed layer ocean responds to different rates of change of a well-mixed greenhouse gas such as CO₂. We provide evidence that different rates of CO₂ variation may lead to similar transient climates characterized by the same global mean surface temperature but different values of CO₂ concentration. Moreover, it is shown that, far from the bifurcation points, the model’s climate depends on the history of the radiative forcing displaying a hysteresis cycle that is neither static nor dynamical, but is related to the memory response of the model. Results are supported by the solutions of a zero-dimensional energy balance model.     

Evaluation of the Interpretation of Ceilometer Data with RASS and Radiosonde Data

Since 2006 different remote monitoring methods for determining mixing-layer height have been operated in parallel in Augsburg (Germany). One method is based on the operation of eye-safe commercial mini-lidar systems (ceilometers). The optical backscatter intensities recorded with ceilometers provide information about the range-dependent aerosol concentration; gradient minima within this profile mark the tops of mixed layers. Special software for these ceilometers provides routine retrievals of lower atmospheric layering. A second method, based on sodar observations, detects the height of a turbulent layer characterized by high acoustic backscatter intensities due to thermal fluctuations and a high variance of the vertical velocity component. This information is extended by measurements with a radio-acoustic sounding system (RASS) that directly provides the vertical temperature profile from the detection of acoustic signal propagation and thus temperature inversions that mark atmospheric layers. Ceilometer backscatter information is evaluated by comparison with parallel measurements. Data are presented from 2 years of combined ceilometer and RASS measurements at the same site and from comparison with a nearby (60 km) radiosonde for larger-scale humidity information. This evaluation is designed to ensure mixing-layer height monitoring from ceilometer data more reliable.     

Assessment of climate change impacts on the quantity and quality of a coastal catchment using a coupled groundwater–surface water model

The hydrology of coastal catchments is influenced by both sea level and climate. Hence, a comprehensive assessment of the impact of climate change on coastal catchments is a challenging task. In the present study, a coupled groundwater–surface water model is forced by dynamically downscaled results from a general circulation model. The effects on water quantity and quality of a relatively large lake used for water supply are analyzed. Although stream inflow to the lake is predicted to decrease during summer, the storage capacity of the lake is found to provide a sufficient buffer to support sustainable water abstraction in the future. On the other hand, seawater intrusion into the stream is found to be a significant threat to the water quality of the lake, possibly limiting its use for water supply and impacting the aquatic environment. Additionally, the results indicate that the nutrient load to the lake and adjacent coastal waters is likely to increase significantly, which will increase eutrophication and have negative effects on the surface water ecology. The hydrological impact assessment is based on only one climate change projection; nevertheless, the range of changes generated by other climate models indicates that the predicted results are a plausible realization of climate change impacts. The problems identified here are expected to be relevant for many coastal regimes, where the hydrology is determined by the interaction between saline and fresh groundwater and surface water systems.     

Change and variability in sea ice during the 2007–2008 Canadian International Polar Year program

In this paper we describe sea ice change and variability during the Canadian International Polar Year (IPY) program and examine several regional and hemispheric causes of this change. In a companion paper (Barber et al., Climate Change 2012) we present an overview of the consequences of this observed change and variability on ecosystem function, climatically relevant gas exchange, habitats of primary and apex predators, and impacts on northern peoples. Sea ice-themed research projects within the fourth IPY were designed to be among the most diverse international science programs. They greatly enhanced the exchange of Inuit knowledge and scientific ideas across nations and disciplines. This interdisciplinary and cultural exchange helped to explain and communicate the impacts of a transition of the Arctic Ocean and ecosystem to a seasonally ice-free state, the commensurate replacement of perennial with annual sea ice types and the causes and consequences of this globally significant metamorphosis. This paper presents a synthesis of scientific sea ice research and traditional knowledge results from Canadian-led IPY projects between 2007 and 2009. In particular, a summary of sea ice trends, basin-wide and regional, is presented in conjunction with Inuit knowledge of sea ice, gathered from communities in northern Canada. We focus on the recent observed changes in sea ice and discuss some of the causes of this change including atmospheric and oceanic forcing of both dynamic and thermodynamic forcing on the ice. Pertinent results include: 1) In the Amundsen Gulf, at the western end of the Northwest Passage, open water persists longer than normal and winter sea ice is thinner and more mobile. 2) Large areas of summer sea ice are becoming heavily decayed during summer and can be broken up by long-period waves being generated in the now extensive open water areas of the Chukchi Sea. 3) Cyclones play an important role in flaw leads??regions of open water between pack ice and land-fast ice. They delay the formation of new ice and the growth of multi-year ice. 4) Feedbacks involving the increased period of open water, long-period wave generation, increased open-ocean roughness, and the precipitation of autumn snow are all partially responsible for the observed reduction in multiyear sea ice. 5) The atmosphere is observed as remaining generally stable throughout the winter, preventing vertical entrainment of moisture above the surface.