Quantitative C NMR of whole and fractionated Iowa Mollisols for assessment of organic matter composition

Both the concentrations and the stocks of soil organic carbon vary across the landscape. Do the amounts of recalcitrant components of soil organic matter (SOM) vary with landscape position? To address this question, we studied four Mollisols in central Iowa, two developed in till and two developed in loess. Two of the soils were well drained and two were poorly drained. We collected surface-horizon samples and studied organic matter in the particulate organic matter (POM) fraction, the clay fractions, and the whole, unfractionated samples. We treated the soil samples with 5 M HF at ambient temperature or at 60 °C for 30 min to concentrate the SOM. To assess the composition of the SOM, we used solid-state nuclear magnetic resonance (NMR) spectroscopy, in particular, quantitative ¹³C DP/MAS (direct-polarization/magic-angle spinning), with and without recoupled dipolar dephasing. Spin counting by correlation of the integral NMR intensity with the C concentration by elemental analysis showed that NMR was ?85% quantitative for the majority of the samples studied. For untreated whole-soil samples with <2.5 wt.% C, which is considerably less than in most previous quantitative NMR analyses of SOM, useful spectra that reflected ?65% of all C were obtained. The NMR analyses allowed us to conclude (1) that the HF treatment (with or without heat) had low impact on the organic C composition in the samples, except for protonating carboxylate anions to carboxylic acids, (2) that most organic C was observable by NMR even in untreated soil materials, (3) that esters were likely to compose only a minor fraction of SOM in these Mollisols, and (4) that the aromatic components of SOM were enriched to ∼53% in the poorly drained soils, compared with ∼48% in the well drained soils; in plant tissue and particulate organic matter (POM) the aromaticities were ∼18% and ∼32%, respectively. Nonpolar, nonprotonated aromatic C, interpreted as a proxy for charcoal C, dominated the aromatic C in all soil samples, composing 69-78% of aromatic C and 27-36% of total organic C in the whole-soil and clay-fraction samples.     

Localization and characterization of an active fault in an urbanized area in central Guatemala by means of geoelectrical imaging

The Polochic and Motagua faults define the active plate boundary between the North American and Caribbean plates in central Guatemala. A splay of the Polochic Fault traverses the rapidly growing city of San Miguel Uspantán that is periodically affected by destructive earthquakes. This fault splay was located using a 2D electrical resistivity tomography (ERT) survey that also characterized the fault damage zone and evaluated the thickness and nature of recent deposits upon which most of the city is built. ERT images show the fault as a ~50 m wide, near-vertical low-resistivity anomaly, bounded within a few meters by high resistivity anomalies. Forward modeling reproduces the key aspects of the observed electrical resistivity data with remarkable fidelity thus defining the overall location, geometry, and internal structure of the fault zone as well as the affected lithologies. Our results indicate that the city is constructed on a ~20 m thick surficial layer consisting of poorly consolidated, highly porous, water-logged pumice. This soft layer is likely to amplify seismic waves and to liquefy upon moderate to strong ground shaking. The electrical conductivity as well as the major element chemistry of the groundwater provides evidence to suggest that the local aquifer might, at least in part, be fed by water rising along the fault. Therefore, the potential threat posed by this fault splay may not be limited to its seismic activity per se, but could be compounded its potential propensity to enhance seismic site effects by injecting water into the soft surficial sediments. The results of this study provide the basis for a rigorous analysis of seismic hazard and sustainable development of San Miguel Uspantán and illustrate the potential of ERT surveying for paleoseismic studies.     

Learning from (small) disasters

In this article, disasters are understood as processes that have different impacts on social routines in terms of scale, scope and duration. The extent of adaptive processes in society can provide the ground for a rough classification of disaster types. Such classification has, on the one hand, practical and analytical advantages. On the other hand, they harbour the danger of overlooking transitions of scale and discourage comprehensive scale-related learning forms. Based on the disaster scale by Fischer (Int J Mass Emerg Disasters 1:91–107, 2003), flash floods in mountain rivers and torrents are described as extreme emergencies or small-town disasters. Three given examples will clearly show that learning rarely takes place within an institutional setting that is subjected to small disasters, because the stakeholder’s focus remains on only one level. Therefore, we propose to implement a system of self-organised and scale-independent learning, so called deutero learning, within the political subsystem. Following a damaging event, participative processes that involve all levels should be initialised. Their task would be to assess the combination of causes and draw conclusions for mitigation measures. An aggregation of these assessments would help the responsible political subsystems to adapt the current natural disasters policy to the changing environmental conditions.     

Erosion rates on different timescales derived from cosmogenic 10Be and river loads: implications for landscape evolution in the Rhenish Massif, Germany

We determined erosion rates on timescales of 10¹–10⁴ years for two catchments in the northeastern Rhenish Massif, in order to unravel the Quaternary landscape evolution in a Variscan mountain range typical of central Europe. Spatially averaged erosion rates derived from in situ produced ¹⁰Be concentrations in stream sediment of the Aabach and M?hne watersheds range from 47 ± 6 to 65 ± 14 mm/ka and integrate over the last 9–13 ka. These erosion rates are similar to local rates of river incision and rock uplift in the Quaternary and to average denudation rates since the Mesozoic derived from fission track data. This suggests that rock uplift is balanced by denudation, i.e., the landscape is in a steady state. Short-term erosion rates were derived from suspended and dissolved river loads subsequent to (1) correcting for atmospheric and anthropogenic inputs, (2) establishing calibration curves that relate the amount of suspended load to discharge, and (3) estimating the amount of bedload. The resulting solid mass fluxes (suspended and bedload) agree with those derived from the sediment volume trapped in three reservoirs. However, resulting geogenic short-term erosion rates range from 9 to 25 mm/ka and are only about one-third of the rates derived from ¹⁰Be. Model simulations in combination with published sediment yield data suggest that this discrepancy is caused by at least three factors: (1) phases with higher precipitation and/or lower evapotranspiration, (2) rare flood events not captured in the short-term records, and (3) prolonged periods of climatic deterioration with increased erosion and sediment transport on hillslopes.     

Description of an aerodynamic levitation apparatus with applications in Earth sciences

Background  

In aerodynamic levitation, solids and liquids are floated in a vertical gas stream. In combination with CO₂-laser heating, containerless melting at high temperature of oxides and silicates is possible. We apply aerodynamic levitation to bulk rocks in preparation for microchemical analyses, and for evaporation and reduction experiments.     

Present and projected degree days in China from observation,reanalysis and simulations

Degree days are usually defined as the accumulated daily mean temperature varying with the base temperature, and are one of the most important indicators of climate changes. In this study, the present-day and projected changes of four degree days indices from daily mean surface air temperature output simulated by Max Planck Institute, Earth Systems Model of low resolution (MPI-ESM-LR) model are evaluated with the high resolution gridded-observation dataset and two modern reanalyses in China. During 1979–2005, the heating degree days (HDD) and the numbers of HDD (NHDD) have decreased for observation, reanalyses (ERA-Interim and NCEP/NCAR) and model simulations (historical and decadal experiments), consistent with the increasing cooling degree days (CDD) and the numbers of CDD (NCDD). These changes reflect the general warming in China during the past decades. In most cases, ERA-Interim is closer to observation than NCEP/NCAR and model simulations. There are discrepancies between observation, reanalyses and model simulations in the spatial patterns and regional means. The decadal hindcast/forecast simulation performance of MPI-ESM-LR produce warmer than the observed mean temperature in China during the entire period, and the hindcasts forecast a trend lower than the observed. Under different representative concentration pathway (RCP) emissions scenarios, HDD and NHDD show significant decreases, and CDD and NCDD consistently increase during 2006–2100 under RCP8.5, RCP4.5 and RCP2.6, especially before the mid-21 century. More pronounced changes occur under RCP8.5, which is associated with a high rate of radiative forcing. The 20th century runs reflect the sensitivity to the initial conditions, and the uncertainties in terms of the inter-ensemble are small, whereas the long-term trend is well represented with no differences among ensembles.     

Origin and age of ultramafic rocks and gabbros in the southern Puna of Argentina: an alleged Ordovician suture revisited

Ultramafic rocks and gabbros are exposed in the southern Puna (NW Argentina) in tectonic association with continental arc-related Ordovician (volcano) sedimentary successions and granitoids. The origin of this mafic rock suite has been debated for three decades as either representing an Ordovician terrane suture, primitive Ordovician arc-related rocks or relics of the pre-Ordovician basement in tectonic contact with the Ordovician retro-arc basin successions. We present the first U–Pb ages of primary and inherited zircon from gabbros of this mafic–ultramafic assemblage. LA-ICP-MS analyses on cores and rims of these zircon grains yielded a concordia age of 543.4 ± 7.2 Ma for the gabbroic rocks. Other analysed zircons have Mesoproterozoic, and Early Ediacaran core and rim ages indicating that the magmas also assimilated Meso- and Neoproterozoic crustal material prior to final crystallization. The mafic rocks witnessed higher metamorphic grade than associated Ordovician rocks, which are unmetamorphosed or only affected by anchimetamorphism. The gabbros are mostly tholeiitic and enriched in Zr, Th, as well as other incompatible elements and have εNd _t=540Ma ranging from 1.3 to 7.4 with most of the values between 5 and 7. ¹⁴⁷Sm/¹⁴⁴Nd ratios show evidence of weak crustal contamination. The mafic rocks do not reveal any affinity to mid-ocean ridge basalts in their geochemistry but point instead to an emplacement in an active plate margin arc environment. Chromites from ultramafic rocks show typical Ti, Al, Cr#, Fe³⁺ abundances found in magmatic arc rocks. The formation of the gabbros and the associated ultramafic rocks in the southern Argentine Puna is related to the evolution of the margin of the Pampia terrane, including the Puncoviscana basin, during the Late Neoproterozoic and earliest Cambrian. In contrast to previous interpretations, the rocks predate the Ordovician evolution of the Central proto-Andean active margin. Consequently, interpretations assuming these rocks to represent an oceanic terrane suture of Ordovician age have to be dismissed as much as all palaeotectonic models that define Ordovician terranes in the Central Andes based on assumption that the ultramafic rocks and gabbros exposed in the southern Puna mark plate boundaries.     

http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

Implementing quality control on a random number stream to improve a stochastic weather generator

For decades, stochastic modellers have used computerized random number generators to produce random numeric sequences fitting a specified statistical distribution. Unfortunately, none of the random number generators we tested satisfactorily produced the target distribution. The result is generated distributions whose mean even diverges from the mean used to generate them, regardless of the length of run. Non‐uniform distributions from short sequences of random numbers are a major problem in stochastic climate generation, because truly uniform distributions are required to produce the intended climate parameter distributions. In order to ensure generation of a representative climate with the stochastic weather generator CLIGEN within a 30‐year run, we tested the climate output resulting from various random number generators. The resulting distributions of climate parameters showed significant departures from the target distributions in all cases. We traced this failure back to the uniform random number generators themselves. This paper proposes a quality control approach to select only those numbers that conform to the expected distribution being retained for subsequent use. The approach is based on goodness‐of‐fit analysis applied to the random numbers generated. Normally distributed deviates are further tested with confidence interval tests on their means and standard deviations. The positive effect of the new approach on the climate characteristics generated and the subsequent deterministic process‐based hydrology and soil erosion modelling are illustrated for four climatologically diverse sites. Copyright © 2007 John Wiley & Sons, Ltd.