Chlorine isotope evidence for the anthropogenic origin of tris-(4-chlorophenyl)methane

Compound-specific Cl-isotope analysis was performed on the persistent and bioaccumulating compound tris-(4-chlorophenyl)methane (4,4′,4″-TCPMe, referred to as TCPMe in this study) to elucidate whether its main source is natural or anthropogenic. Blubber from the Baltic grey seal (Halichoerus grypus) was extracted by continuous acetonitrile partitioning, and the TCPMe was isolated from the extract by preparative-capillary gas chromatography. Chlorine isotope analysis was subsequently performed by sealed-tube combustion in conjunction with thermal-ionization mass spectrometry (TIMS). The δ³⁷Cl of TCPMe was −3.5 ± 0.5‰, similar to the previously reported δ³⁷Cl of technical grade p,p′-DDT (referred to as DDT in this study). The data is not consistent with a putative marine natural source of TCPMe, as enzymatic (biotic) production is reported to give values of δ³⁷Cl < −10‰. The δ³⁷Cl–TCPMe data thus supports the hypothesis that TCPMe is produced as a byproduct during DDT synthesis and is released to the environment through the same pathways as DDT. It is also consistent with tris-(4-chlorophenyl)methanol as the primary biotransformation product of TCPMe.     

Anisotropic Cosmological Models with a Perfect Fluid and a Λ Term

We consider a self-consistent system of Bianchi type-I (BI) gravitational field and a binary mixture of perfect fluid and dark energy given by a cosmological constant. The perfect fluid is chosen to be the one obeying either the usual equation of state, i.e., p = ζ, with ζ ∊ [0, 1] or a van der Waals equation of state. Role of the Λ term in the evolution of the BI Universe has been studied.     

Response of the Baltic Sea to climate change—theory and observations

The dynamics controlling the response of the Baltic Sea to changed atmospheric and hydrologic forcing are reviewed and demonstrated using simple models. The response time for salt is 30 times longer than for heat in the Baltic Sea. In the course of a year, the Baltic Sea renews most of its heat but only about 3% of its salt. On the seasonal scale, surface temperature and ice-coverage are controlled by the atmospheric conditions over the Baltic Sea as demonstrated by e.g. the strong inter-annual variations in winter temperature and ice-coverage due to variations in dominating wind directions causing alternating mild and cold winters. The response of surface temperature and ice-coverage in the Baltic Sea to modest climate change may therefore be predicted using existing statistics. Due to the long response time in combination with complicated dynamics, the response of the salinity of the Baltic Sea cannot be predicted using existing statistics but has to be computed from mechanistic models. Salinity changes primarily through changes in the two major forcing factors: the supply of freshwater and the low-frequency sea level fluctuations in the Kattegat. The sensitivity of Baltic Sea salinity to changed freshwater supply is investigated using a simple mechanistic steady-state model that includes baroclinic geostrophic outflow from the Kattegat, the major dynamical factor controlling the freshwater content in the Kattegat and thereby the salinity of water flowing into the Baltic Sea. The computed sensitivity of Baltic Sea surface salinity to changes of freshwater supply is similar to earlier published estimates from time-dependent dynamical models with higher resolution. According to the model, the Baltic Sea would become fresh at a mean freshwater supply of about 60 000 m³ s⁻¹, i.e. a 300% increase of the contemporary supply. If the freshwater supply in the different basins increased in proportion to the present-day supply, the Bothnian Bay would become fresh already at a freshwater supply of about 37 000 m³ s⁻¹ and the Bothnian Sea at a supply of about 45 000 m³ s⁻¹. The assumption of baroclinic geostrophic outflow from the Kattegat, crucial for the salinity response of the Baltic Sea to changed freshwater supply, is validated using daily salinity profiles for the period 1931–1977 from lightship Läsö Nord.     

Differential transport and degradation of bulk organic carbon and specific terrestrial biomarkers in the surface waters of a sub-arctic brackish bay mixing zone

Detailed organic geochemical analyses were performed on surface water particulate samples of the lower Kalix River and northern Bothnian Bay collected during the spring flood of 2005. Both bulk geochemical and molecular biomarker analyses indicated a predominance of terrestrially-derived particulate organic matter (POM), both of higher plant and Sphagnum origin in the low salinity zone (LSZ) of the Kalix River estuary, with an increasing contribution of marine-derived POM in the offshore Bothnian Bay basin.Two-dimensional box modeling of the mixed surface layer in the LSZ indicated that 65% of the particulate organic carbon (POC) and between 73 and 93% of the terrestrial biomarker classes analyzed (high molecular weight n-alkanes, n-alkanoic acids and n-alkanols as well as sitosterol) were degraded in the course of their weeklong transit through the inner LSZ during the spring flood. This corresponds to field-based degradation rate constants for the biomarkers of 0.5 and 2.5 day^− 1, which are similar to results reported from mesocosm experiments for related compounds. The degradation rate constant for terrestrial POC of 0.38 day^− 1 was about 20 times larger than for DOC and suggests that POC mineralization stands for 44% of the total mineralization, which is much larger than previously considered.This sub-arctic river-export regime has a geochemistry resembling that of neighboring western Russian Arctic Rivers, suggesting that a large part of the OM coastally exported from northernmost Eurasian soils may be degraded within the vicinity of the river mouths and putatively be released as carbon dioxide. The 65% degradation of terrestrial POC in the coastal surface water of this sub-arctic recipient is substantially larger than a global-average of 35% used in recent budget estimates of the fate of terrestrially-exported POC on the pan-arctic shelves. Considering ongoing and predicted changes in the Arctic Region due to global warming a more efficient degradation of river-exported terrestrial POC may have far-reaching consequences for the large-scale biogeochemical cycling of carbon in the pan-arctic region and beyond.     

Summer algal blooms in a coastal ecosystem: the role of atmospheric deposition versus entrainment fluxes

The nitrogen inputs from atmospheric deposition and bottom water entrainment to the surface layer were modelled in the summer period (May–September) over a 11-year period (1989–1999) and compared to investigate the significance of these fluxes for generating blooms in the Kattegat. In the summer periods the average atmospheric deposition was 2.81 mg N m⁻² d⁻¹ compared to average entrainment fluxes of 5.42 mg N m⁻² d⁻¹, 1.21 mg N m⁻² d⁻¹ and 1.15 mg N m⁻² d⁻¹ for the northern, central and southern part of the Kattegat, respectively. Atmospheric nitrogen deposition alone could not sustain biomass increases associated with observed blooms and entrainment fluxes dominated the high nitrogen inputs to the surface layer. The potential for a bloom through growth was typically obtained after several days of high nitrogen inputs from entrainment in the frontal area of the northern Kattegat and to some extent from atmospheric deposition. The modelled nitrogen input in this area could account directly for 30% of the observed blooms in the Northern sub-basin, and through advective transport 24% and 19% of the observed blooms in the central and southern Kattegat. The direct nitrogen inputs through atmospheric deposition and entrainment to the central and southern sub-basins were small and could not be linked to any bloom observation.     

Regional and structural effects of North Sea oil in Norway

The discovery of oil in the North Sea has had an important impact on Norway. The article presents the development of the oil policy. Of particular interest is the heavy involvement in Norway in products as mobile rigs, supply ships and concrete platforms. The distribution of the oil activities in Norway as related to locational factors is discribed, with examples of the local impacts of oil activities. Of particular concern are the regional effects. Norway will be a high cost country and low-wage industries (e.g. textiles, furniture) may be squeezed. Industrial decay areas like in Britain and Europe are feared. Also some main problems and decisions such as the landing of Statfjord oil by pipeline are considered.     

Contrasting tonalite genesis in the Lyngen magmatic complex, north Norwegian Caledonides

The Lyngen gabbro (LG), defining the major part of the Lyngen magmatic complex, is characterised by layered gabbros of N-MORB affinity (western suite) and layered gabbronorites, quartz-bearing gabbros and diorites/quartz-diorites of IAT (island-arc tholeiite) to boninitic affinity (eastern suite). The boundary between the eastern and western suites is generally defined by a large-scale ductile shear zone of suboceanic origin, the Rypdalen shear zone (RSZ). Tonalites occur within the RSZ and in the eastern suite of the LG. Variations in field occurrence and chemical composition of the tonalites suggest that they represent two petrologically different groups. Tonalite intrusion (the Vakkas pluton) up to 5 km² large occur in the eastern suite of the LG, and are characterised by high Y contents (average 26 ppm) and high K₂O/Rb ratios (average 0.062) compared to tonalites on the RSZ. The Vakkas pluton has lightly concave REE (rare earth element) patterns with negative Eu-anomalies, and positive _ND-values (+3.7 to +3.9). Geochemical modelling based on the REE and field evidence suggests that these tonalites may have formed by fractional crystallization from a boninitic parental magma. Tonalites related to the RSZ form irregular veins and dikes that net vein the shear zone. They are characterised by low Y contents (average 6 ppm), low K₂O/Rb ratios (average 0.025), and highly variable contents of Na₂O, K₂O, Sr and Ba, compared to the Vakkas pluton. Tonalites related to the RSZ show substantial variation in the content of the LREEs. They possess low abundances of the HREEs, and absence of, or slightly positive Eu-anomalies. The tonalites have highly variable _ND-values (−0.6 to −9.4), probably resulting from enrichment of Nd from an external source. Geochemical modelling suggests that the LREE-rich tonalites formed by H₂O-rich partial melting of differentiated products from the eastern suite of the LG. The presence of B in the fluid phase is suggested by the presence of tourmaline-bearing tonalite pegmatites. Thus, the anatectic tonalites of this group could have been formed by water-excess melting of a variety of gabbroic cumulates of the LG. In the LG, LREE-depleted tonalites (_ND-values +5.1) also occur, and these are best explained in terms of partial melting of gabbroic cumulates from the transition zone between the eastern and the western suites of the LG.     

Upper layer circulation of the Nordic seas as inferred from the spatial distribution of heat and freshwater content and potential energy

The spatial distribution of heat and freshwater content and potential energy of a several hundred metre thick surface layer are computed for the Nordic seas and adjacent parts of the northern North Atlantic and the Arctic Ocean using a total of almost 100 000 hydrographic stations. The fields clearly show the major features of the area's circulation, with warm salty water in the eastern part and fresher, colder water in the western part. Comparisons with published estimates show that the potential energy field, representing the baroclinic part of the flow, accounts for about 30 % of the total flow but roughly 100 % of the flow of Polar Water in the northern part of the East Greenland Current, about 50 % of the total flow in the Norwegian Atlantic Current, and just a small fraction of the flow in the eastern part of Fram Strait. This suggests that the barotropic circulation is quite important in many parts of the Nordic seas. The barotropic circulation is also clearly seen by its effects on the integrated fields with isolines following deep bathymetric contours. We speculate that the barotropic circulation in combination with topographic obstacles, like the Greenland–Scotland Ridge and the ridge system in the Jan Mayen area, may have large impact on the spreading of freshwater and heat in the Nordic seas.