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31.
The spatial distribution of upstream migrating Atlantic salmon (Salmo salar) spawners was studied in 2008 and 2009 in the surroundings of the tailrace from a hydropower station in the River Umeälven. This area is problematic because the fish have difficulties finding their way into the original riverbed, which prompted an investigation on the feasibility of adding a fishway in the area. Echo sounding was used in 2008 to investigate the spatial use of fish in the tailrace channel during the time of salmon migration. Presence of other fish species was so low that all echo sounding detections were assumed to be salmon. In 2009, data on wild radio-tagged salmon (n = 94) was collected in the same tailrace by an array of underwater antennas with a detection radius of approximately 10 m, to validate the results from the echo sounding. Both types of surveys showed aggregations of fish in one part of the tailrace. As a final step, Computational Fluid Dynamics (CFD) modeling was performed to analyze hydrodynamics. This CFD modeling showed a coincidence of fish detections in areas with turbulence intensities between 0.6 and 0.8, which may be an indication that the fish are holding in these areas to reduce energy expenditure during migration. A high proportion of the radio-tagged salmon were observed in the tailrace area (a median of 21 days between their first and last detection), indicating that the salmon are delayed in their upstream migration by the attraction to the tailrace in this area. The overall data on fish behavior in the tailrace led us to suggest a location for a new fishway where the fish aggregation was most pronounced. The number of detections from either technology had similar distributions over the tailrace, suggesting that the results are comparable. Thus, the split beam echo sounder can preferably be used to investigate which location is most appropriate for locations of entrances to new fishways since many more individual fishes are covered by this method compared to telemetry. Furthermore, there is no need to handle the fish in the echo sounding studies as is required in telemetry studies.  相似文献   
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Uranium(VI), which is often elevated in granitoidic groundwaters, is known to adsorb strongly to Fe (hydr)oxides under certain conditions. This process can be used in water treatment to remove U(VI). To develop a consistent geochemical model for U(VI) adsorption to ferrihydrite, batch experiments were performed and previous data sets reviewed to optimize a set of surface complexation constants using the 3-plane CD-MUSIC model. To consider the effect of dissolved organic matter (DOM) on U(VI) speciation, new parameters for the Stockholm Humic Model (SHM) were optimized using previously published data. The model, which was constrained from available X-ray absorption fine structure (EXAFS) spectroscopy evidence, fitted the data well when the surface sites were divided into low- and high-affinity binding sites. Application of the model concept to other published data sets revealed differences in the reactivity of different ferrihydrites towards U(VI). Use of the optimized SHM parameters for U(VI)-DOM complexation showed that this process is important for U(VI) speciation at low pH. However in neutral to alkaline waters with substantial carbonate present, Ca–U–CO3 complexes predominate. The calibrated geochemical model was used to simulate U(VI) adsorption to ferrihydrite for a hypothetical groundwater in the presence of several competitive ions. The results showed that U(VI) adsorption was strong between pH 5 and 8. Also near the calcite saturation limit, where U(VI) adsorption was weakest according to the model, the adsorption percentage was predicted to be >80%. Hence U(VI) adsorption to ferrihydrite-containing sorbents may be used as a method to bring down U(VI) concentrations to acceptable levels in groundwater.  相似文献   
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The common assumption that the ratio between particulate organic carbon (POC) and particulate 234Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / 234Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / 234Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / 234Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / 234Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex 234Th (i.e., high POC / 234Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly 234Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / 234Th) of the total spectrum of particles settling out of the upper ocean.  相似文献   
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1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.  相似文献   
35.
Summary  We compared two one-dimensional simulation models for heat and water fluxes in the soil-snow-atmosphere system with respect to their mathematical formulations of the surface heat exchange and the snow pack evolution. They were chosen as examples of a simple one-layer snow model and a more detailed multiple-layer snow model (SNTHERM). The snow models were combined with the same one-dimensional model for the heat and water balance of the underlying soil (CoupModel). Data from an arable field in central Sweden (Marsta), covering two years (1997–1999) of soil temperature, snow depth and eddy-correlation measurements were successfully compared with the models. Conditions with a snow pack deeper or shallower than 10 cm and bare soil resulted in similar discrepancies. The simulated net radiation and sensible heat flux were in good agreement with that measured during snow-covered periods, except for situations with snowmelt when the downward sensible heat flux was overestimated by 10–20 Wm−2. The results showed that the uncertainties in parameter values were more important than the model formulation and that both models were useful in evaluating the limitations and uncertainties of the measurements. Received November 1, 1999 Revised April 20, 2000  相似文献   
36.
Prevention of oil spill from shipping by modelling of dynamic risk   总被引:1,自引:0,他引:1  
This paper presents a new dynamic environmental risk model, with intended use within a new, dynamical approach for risk based ship traffic prioritisation. The philosophy behind this newly developed approach is that shipping risk can be reduced by directing efforts towards ships and areas that have been identified as high priority (high risk), prior to a potential accident. The risk model proposed in this paper separates itself from previous models by drawing on available information on dynamic factors and by focusing on the ship's surroundings. The model estimates the environmental risk of drift grounding accidents for oil tankers in real time and in forecast mode, combining the probability of grounding with oil spill impact on the coastline. Results show that the inherent dynamic risk introduced by an oil tanker sailing along the North Norwegian coast depends, not surprisingly, significantly upon wind and ocean currents, as well as tug position and cargo oil type. Results of this study indicate that the risk model is well suited for real time risk assessment, and effectively separates low risk and high risk situations. The model is well suited as a tool to prioritise oil tankers and coastal segments. This enables dynamic risk based positioning of tugs, using both real-time and projected risk, for effective support in case of a drifting ship situation.  相似文献   
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The discovery of oil in the North Sea has had an important impact on Norway. The article presents the development of the oil policy. Of particular interest is the heavy involvement in Norway in products as mobile rigs, supply ships and concrete platforms. The distribution of the oil activities in Norway as related to locational factors is discribed, with examples of the local impacts of oil activities. Of particular concern are the regional effects. Norway will be a high cost country and low-wage industries (e.g. textiles, furniture) may be squeezed. Industrial decay areas like in Britain and Europe are feared. Also some main problems and decisions such as the landing of Statfjord oil by pipeline are considered. The original version received valuable criticism from Prof. J. Chr. Hansen, Bergen, and Dr. W. Tietze, Wolfsburg, Germany. The author would be grateful for further comments from the readers.  相似文献   
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