Mechanisms of weathering of meteorites recovered from hot and cold deserts and the formation of phyllosilicates

Petrographic, mineralogical and chemical analysis of naturally weathered equilibrated ordinary chondrites collected from ‘ hot’ deserts and Antarctica has revealed striking similarities and also pronounced differences in weathering between the two environments. Terrestrial weathering in all meteorites studied is dominated by oxidation and hydration of Fe,Ni metal, producing Fe-oxides and oxyhydroxides that have partially replaced the metal grains and have also occluded primary intergranular pores to form veins. Troilite weathers readily in ‘ hot’ desert environments but undergoes very little alteration under Antarctic conditions. Most of the primary porosity of ordinary chondrites has been occluded by the time that ∼ 15 to 25% of the initial Fe⁰ and Fe²⁺ has been oxidised to Fe³⁺ in both environments. Results from modelling the volume changes upon alteration of primary minerals to a range of weathering products demonstrates that the primary porosity of most meteorites is sufficient to accommodate weathering products. Dilation of primary pores and brecciation, which has been observed in parts of some meteorites, will only occur if the meteorite is especially metal-rich, or has a low primary porosity. These weathering products are absent from recent falls but have formed in a fall after ∼ 100 yr of museum storage.Cl-bearing akaganéite and hibbingite are common weathering products in Antarctic finds but occur in abundance in only one ‘ hot’ desert meteorite, Daraj 014. The majority of Fe-rich weathering products in meteorites from both environments contain low, but variable concentrations of Si, Mg and Ca. In most meteorites a proportion of these elements are inferred to be present as a very finely crystalline mineral with a ∼ 1.0-nm lattice fringe spacing; where seen within intragranular fractures this mineral has a topotactic relationship with olivine and orthopyroxene. In the heavily-weathered Antarctic finds ALHA 78045 and 77002, Si is concentrated in cronstedtite, a Fe-rich phyllosilicate. An unidentified hydrous Si-Fe-Ni-Mg mineral or gel has also partially replaced taenite in ALHA 78045. In addition to Fe-rich weathering products, ‘ hot’ desert meteorites contain sulphates, Ca-carbonate and silica, whereas such minerals are largely absent from Antarctic finds. The abundance of silicate weathering products in Antarctic meteorites is unexpected and indicates that olivine and pyroxene undergo significant chemical weathering in these environments. As preterrestrial cronstedtite is abundant in CM2 carbonaceous chondrites, the Antarctic environment may be a powerful analog for aqueous alteration in the asteroidal parent bodies of primitive meteorites.     

Hydrogeochemical Anomalies in the Springs of the Chiayi Area in West-central Taiwan as Possible Precursors to Earthquakes

Water samples from both hot and artesian springs in Kuantzeling in west-central Taiwan have been collected on a regular basis from July 15, 1999 to the end of August 2001 to measure cation and anion concentrations as a tool to detect major earthquake precursors. The data identify chloride and sulfate ion anomalies few days prior to major quakes and lasting a few days afterward. These anomalies are characterized by increases in Cl^- concentrations from 34.9% to 41.2% and 71.5% to 138.1% as well as increases in SO₄^2- concentrations from 232.7% to 276.8% and 100.0% to 155.1% above the means in both hot and artesian springs. The occurrence of these anomalies is probably explained first as stress/strain-induced pressure changes in the subsurface water systems which then generate precursory limited geochemical discharges at the levels of subsurface reservoirs. Therefore, finally leading to the mixing of previously separated subsurface water bodies occurs. This suggests that the hot and artesian springs in the Kuantzeling area are possible ideal sites for recording strain changes serving well as earthquake precursors.     

Estimation of groundwater recharge using water balance coupled with base-flow-record estimation and stable-base-flow analysis

In this paper, the long-term mean annual groundwater recharge of Taiwan is estimated with the help of a water-balance approach coupled with the base-flow-record estimation and stable-base-flow analysis. Long-term mean annual groundwater recharge was derived by determining the product of estimated long-term mean annual runoff (the difference between precipitation and evapotranspiration) and the base-flow index (BFI). The BFI was calculated from daily streamflow data obtained from streamflow gauging stations in Taiwan. Mapping was achieved by using geographic information systems (GIS) and geostatistics. The presented approach does not require complex hydrogeologic modeling or detailed knowledge of soil characteristics, vegetation cover, or land-use practices. Contours of the resulting long-term mean annual P, BFI, runoff, groundwater recharge, and recharge rates fields are well matched with the topographical distribution of Taiwan, which extends from mountain range toward the alluvial plains of the island. The total groundwater recharge of Taiwan obtained by the employed method is about 18 billion tons per year.An erratum to this article can be found at     

Climatic Change, Wars and Dynastic Cycles in China Over the Last Millennium

In recent years, the phenomenon of global warming and its implications for the future of the human race have been intensively studied. In contrast, few quantitative studies have been attempted on the notable effects of past climatic changes upon human societies. This study explored the relationship between climatic change and war in China by comparing high-resolution paleo-climatic reconstructions with known war incidences in China in the last millennium. War frequencies showed a cyclic pattern that closely followed the global paleo-temperature changes. Strong and significant correlations were found between climatic change, war occurrence, harvest level, population size and dynastic transition. During cold phases, China suffered more often from frequent wars, population decline and dynastic changes. The quantitative analyses suggested that the reduction of thermal energy input during a cold phase would lower the land carrying capacity in the traditional agrarian society, and the population size, with significant accretions accrued in the previous warm phase, could not be sustained by the shrinking resource base. The stressed human-nature relationship generated a ‘push force’, leading to more frequent wars between states, regions and tribes, which could lead to the collapse of dynasties and collapses of human population size. War frequencies varied according to geographical locations (North, Central and South China) due to spatial variations in the physical environment and hence differential response to climatic change. Moreover, war occurrences demonstrated an obvious time lag after an episode of temperature fall, and the three geographical regions experienced different length of time lags. This research also shows that human population increases and collapses were correlated with the climatic phases and the social instabilities that were induced by climate changes during the last millennium. The findings proposed a new interpretation of human-nature relationship in the past, with implications for the impacts of anomalous global warming on future human conflicts.     

Shaking table tests on a high‐rise RC building model having torsional eccentricity in soft lower storeys

A series of shaking table tests on a 1:12‐scale model using scaled TaftN21E earthquake records were conducted to investigate the seismic performance of a 17‐storey high‐rise reinforced concrete structure with a high degree of torsional eccentricity and soft‐storey irregularities in the bottom two storeys. Based on the analysis of test results, the following conclusions were drawn: (1) the model responded mainly in the coupled mode of translation and torsion or in the torsional mode. Under severe table shaking, the flexible side underwent large inelastic deformation, and the predominant mode of the model changed from the coupled mode to the torsional mode, resulting in greatly increased torsional stiffness, thereby limiting damage in the flexible frame; (2) the shear force and deformation of the flexible side were governed by the torsional behaviour, whereas those of the stiff side were affected mainly by the overturning deformation. The lateral stiffness of the shear wall in the torsional mode was about four times that in the coupled mode because the warping deformation due to torsion counteracted the flexural deformation due to overturning moment in the torsional mode; and (3) the reversed cyclic overturning moments predicted by linear elastic dynamic analysis in the direction transverse to the table excitations contradicted unilateral overturning moments of the serviceability‐level test results, which showed a bias towards tension or compression in the columns. Copyright © 2006 John Wiley & Sons, Ltd.     

Ocean color reveals phase shift between marine plants and yellow substance

Daily high-resolution Sea-viewing Wide Field-of-view Sensor (SeaWiFS) images of the central North Atlantic Ocean (1998-2003) show that temporal changes in the absorption coefficient of colored dissolved organic matter (CDOM) or "yellow substance" follow changes in phytoplankton pigment absorption coefficient in time. CDOM peaks (between January and March) and troughs (late summer and fall) followed pigment peaks and troughs by approximately two and four weeks, respectively. This phase shift is additional strong evidence that CDOM in the marine environment is derived from phytoplankton degradation. The common assumption of linear covariation between chlorophyll and CDOM is a simplification even in this ocean gyre. Due to the temporal changes in CDOM, chlorophyll concentration estimated based on traditional remote sensing band-ratio algorithms may be overestimated by about 10% during the spring bloom and underestimated by a similar 10% during the fall. These observations are only possible through use of synoptic, precise, accurate, and frequent measurements afforded by space-based sensors because in situ technologies cannot provide the required sensitivity or synoptic coverage to observe these natural phenomena.     

Assessment of the geological and hydrogeological environment at a site of government-level conflict in Incheon, Korea

 The natural environment of an environmental conflict site in Incheon, Korea was assessed with a focus on the hydrogeological environment. Residents had made claims against a company because of health problems, including skin tumors. More specifically, the residents suspected that their drinking groundwater had been contaminated by glass fibers which had caused the health problems. Air, soil, and groundwater samples were analyzed to estimate whether environmental pollution could have caused the problems claimed by the residents. No specific evidence was found from this study to support the groundwater contamination by glass fibers, but groundwater contamination by leaked fuel oils was confirmed in the course of evaluating the glass fiber problem. Received: 16 May 1997 · Accepted: 18 August 1997     

Heterolocalism: an alternative model of the sociospatial behaviour of immigrant ethnic communities

"This paper evaluates critically the applicability of the well-known assimilation and pluralist models to the contemporary ethnic landscape of the U.S.... We then consider an alternative model, labelled heterolocalism, which suggests that members of certain newly arrived groups may be able to sustain their identity as an ethnic community despite immediate or rapid spatial dispersion. The applicability of the heterolocal perspective to non-metropolitan and transnational phenomena is evaluated in subsequent sections of the paper."     

An experimentally verified model for calcite precipitation in veins

Calcite is commonly found as a vein-filling mineral in rocks. However, the factors controlling its deposition are complex and not well understood in quantitative terms. In order to advance our understanding of the processes involved, we have refined the model for calcium carbonate mass transport in subsurface carbonate rocks of Morse and Mackenzie (1993) and developed a new experimental technique to test it. This technique uses a flow-through reactor that simulates a vein opening. Agreement was observed between model predictions and experimental observations for the deposition of calcite in synthetic veins. The influences of surface area to solution volume ratio, solution saturation state with respect to calcite, and flow velocity were well predicted by the model.

The model predicts that in order to have a fairly uniform deposition of calcite within a vein, solution flow must be quite rapid (tens to thousands of cm h⁻¹) or the solution must be only slightly supersaturated with respect to calcite. A low degree of solution supersaturation demands what may be unreasonably large volumes of solution flow to achieve vein filling for the vein configuration we have studied.