An adaptive mesh refinement algorithm for compressible two-phase flow in porous media

We describe a second-order accurate sequential algorithm for solving two-phase multicomponent flow in porous media. The algorithm incorporates an unsplit second-order Godunov scheme that provides accurate resolution of sharp fronts. The method is implemented within a block structured adaptive mesh refinement (AMR) framework that allows grids to dynamically adapt to features of the flow and enables efficient parallelization of the algorithm. We demonstrate the second-order convergence rate of the algorithm and the accuracy of the AMR solutions compared to uniform fine-grid solutions. The algorithm is then used to simulate the leakage of gas from a Liquified Petroleum Gas (LPG) storage cavern, demonstrating its capability to capture complex behavior of the resulting flow. We further examine differences resulting from using different relative permeability functions.     

Calibration of the New Certified Reference Materials ERM‐AE633 and ERM‐AE647 for Copper and IRMM‐3702 for Zinc Isotope Amount Ratio Determinations

The commonly used, but no longer available, reference materials NIST SRM 976 (Cu) and ‘JMC Lyon’ (Zn) were calibrated against the new reference materials ERM^®‐AE633, ERM^®‐AE647 (Cu) and IRMM‐3702 (Zn), certified for isotope amount ratios. This cross‐calibration of new with old reference materials provides a continuous and reliable comparability of already published with future Cu and Zn isotope data. The Cu isotope amount ratio of NIST SRM 976 yielded δ^65/63Cu values of ?0.01 ± 0.05‰ and ?0.21 ± 0.05‰ relative to ERM^®‐AE633 and ERM^®‐AE647, respectively, and a δ^66/64Zn_IRMM‐3702 value of ?0.29 ± 0.05‰ was determined for ‘JMC Lyon’. Furthermore, we separated Cu and Zn from five geological reference materials (BCR‐2, BHVO‐2, BIR‐1, AGV‐1 and G‐2) using a two‐step ion‐exchange chromatographic procedure. Possible isotope fractionation of Cu during chromatographic purification and introduction of resin‐ and/or matrix‐induced interferences were assessed by enriched ⁶⁵Cu isotope addition. Instrumental mass bias correction for the isotope ratio determinations by MC‐ICP‐MS was performed using calibrator‐sample bracketing with internal Ni doping for Cu and a double spike approach for Zn. Our results for the five geological reference materials were in very good agreement with literature data, confirming the accuracy and applicability of our analytical protocol.     

Trematode parasites of Otago Harbour (New Zealand) soft‐sediment intertidal ecosystems: Life cycles,ecological roles and DNA barcodes

Parasites, in particular trematodes (Platyhelminthes: Digenea), play major roles in the population dynamics and community structure of invertebrates on soft‐sediment mudflats. Here, we provide a list of the 20 trematode species currently known to infect molluscs, crustaceans and polychaetes from Otago Harbour (New Zealand) soft‐sediment intertidal areas, as well as information on their transmission modes, life cycles, andknown ecological impacts. Several of the host‐parasite species combinations recorded here are reported for the first time. We also provide DNA barcodes, based on sequences of the cytochrome oxidase subunit l (CO1) gene, for 19 of the 20 trematode species, to facilitate future identification of these parasites in marine ecological studies.     

Source and possible tectonic driver for Jurassic–Cretaceous gold deposits in the West Qinling Orogen,China

The West Qinling Orogen (WQO) in Central China Orogenic Belt contains numerous metasedimentary rock-hosted gold deposits (>2000 t Au), which mainly formed during two pulses: one previously recognized in the Late Triassic to Early Jurassic (T3–J1) and one only recently identified in the Late Jurassic to Early Cretaceous (J3–K1). Few studies have focused on the origin and geotectonic setting of the J3–K1 gold deposits.Textural relationships, LA-ICP-MS trace element and sulfur isotope compositions of pyrites in hydrothermally altered T3 dykes within the J3–K1 Daqiao deposit were used to constrain relative timing relationships between mineralization and pyrite growth in the dykes, and to characterize the source of ore fluid. These results are integrated with an overview of the regional geodynamic setting, to advance understanding of the tectonic driver for J3–K1 hydrothermal gold systems. Pyrite in breccia- and dyke-hosted gold ores at Daqiao have similar chemical and isotopic compositions and are considered to be representative of J3–K1 gold deposits in WQO. Co/Ni and sulfur isotope ratios suggest that ore fluids were derived from underlying Paleozoic Ni- and Se-rich carbonaceous sedimentary rocks. The geochemical data do not support the involvement of magmatic fluids. However, in the EQO (East Qinling Orogen), J3–K1 deposits are genetically related to magmatism. Gold mineralization in WQO is contemporaneous with magmatic deposits in the EQO and both are mainly controlled by NE- and EW-trending structures produced by changes in plate motion of the Paleo-Pacific plate as it was subducted beneath the Eurasian continent. We therefore infer that the J3–K1 structural regime facilitated the ascent of magma in the EQO and metamorphic fluids in the WQO with consequent differences in the character of contemporaneous ore deposits. If this is correct, then the far-field effects of subduction along the eastern margin of NE Asia extended 1000's of km into the continental interior.     

Re-conceptualising desert landscapes: unpacking historical narratives and contemporary realities for sustainable livelihood development in central Australia

Desert landscapes of central Australia have inspired various narratives for nation building. These narratives, based upon discourses of land as a commodity for the colonial project, include the inferior peripheral wastelands of the colonial centre; the wild and pristine haven of ‘noble aborigines’; and the frontier home of heroic explorers and pastoralists. These narratives continue to influence land management policy and practice. However they do not reflect the diverse contemporary realities of individuals living in the region. In this paper I juxtapose these narratives and realities to reveal the multitude of ways in which desert landscapes are known and understood. A case study of a fire management project that involved Aboriginal, pastoral and conservation land managers from the southern Tanami region of central Australia provides evidence as to why desert landscapes should be re-conceptualized as cultural, contested and dynamic. To conceive of these spaces and places in this way can facilitate open discussion and dialogue between land managers from the region. It is the first step in working towards the process of cultural hybridity that I argue is necessary for equitable and sustainable environmental governance and management in Australia.     

Basinal setting and origin of thick (1·8 km) mass‐flow dominated Grand Conglomérat diamictites,Kamoa, Democratic Republic of Congo: Resolving climate and tectonic controls during Neoproterozoic glaciations

The Kamoa sub‐basin, in the south‐eastern part of the Democratic Republic of Congo, is a rift basin that hosts a world‐class stratiform copper deposit at the base of a very thick (1·8 km) succession of matrix‐supported conglomerates (diamictite) (Grand Conglomérat Formation) that has been interpreted by some as the product of deposition in the aftermath of a planet‐wide glaciation. Newly available subsurface data consisting of more than 300 km of drill core throws new light on the origin of diamictite and associated facies types, and their tectonic, basinal and palaeoclimatic setting. Initiation of rifting is recorded by a lowermost subaqueous succession of fault‐related mass flow conglomerates and breccias (the ‘Poudingue’) with interdigitating coeval and succeeding sandstone turbidites (Mwashya Subgroup). Overlying diamictites of the Grand Conglomérat were deposited as subaqueous debrites produced by mixing and homogenization of antecedent breccias and gravel from the Poudingue and Mwashya sediments with basinal muds. Failure of over‐steepened basin margins and debris flow was likely to be triggered by faulting and seismic activity, and was accompanied by syn‐depositional subaqueous basaltic magmatism recorded by peperites and pillow lavas within diamictites. The thickness of diamictites reflects recurring phases of faulting, volcanism and rapid subsidence allowing continued accommodation of rapidly deposited resedimented facies well below wave base. A distal or indirect, glacial influence in the form of rare dropstones and striated clasts is evident, but tectonically‐driven mass flow destroyed any primary record of glacial climate originally present in basin margin sediments. Such basin margin settings were common during Rodinia rifting and their stratigraphy and facies record a dominant tectonic, rather than climatic, control on sedimentation. Deposition occurred on tectonic timescales inconsistent with a Snowball Earth model for Neoproterozoic diamictites involving a direct glacial contribution to deposition.     

A transmission electron microscopy (TEM) study of silver nanoparticles associated with mine waste from New Caledonian nickel deposits: potential origins of silver toxicity in a World Heritage Site

The nature of silver nanoparticles associated with nickel-laterite ore deposits in New Caledonia (SW Pacific Ocean) is explored using transmission electron microscopy. The silver nanoparticles, dispersed in a matrix of amorphous silica, display complex textures such as linear aggregation and bimodal diameter distributions of 3–12 and 20–60 nm for one sample and 2–30 and 150–650 nm for the other, indicative of Ostwald ripening. These features as well as chemical heterogeneity (31–82% Ag—normalized X-ray energy dispersive spectrum), destructive assemblage interfaces, and amorphous and nanoparticle silica phases are consistent with those observed in epithermal gold deposits, potentially indicating a similar origin. Silver is highly toxic to a wide variety of organisms, and therefore, its significant presence in material directly related to mine runoff is a major threat to the New Caledonian environment, particularly the lagoons, which are listed as a World Heritage Site. Potential exists that the silver nanoparticles observed here provide the key to the origin of the toxic silver accumulation observed in New Caledonian reef organisms.     

Salt Spray Induces Osmotic Adjustment and Tissue Rigidity in Smooth Cordgrass, <Emphasis Type="Italic">Spartina alterniflora</Emphasis> (Loisel.)

Salt spray is one of many abiotic factors that can influence plant productivity and species composition in coastal ecosystems. However, little is known about how marsh plants respond physiologically to the accumulation of sea aerosols on foliar tissues. In this study, experimental microcosms maintained in controlled greenhouse conditions were used to evaluate how low- (1.7 mg dm⁻² day⁻¹, weekly averages) and high- (8.6 mg dm⁻² day⁻¹) salt-spray loads would influence plant–water relations in Spartina alterniflora (Loisel.). While no differences in plant performance (e.g., changes in biomass and leaf area) were observed between the treatments and control plants, a number of physiological modifications attributed to salt spray were observed. In general, salt-treated plants underwent significant decreases in water potential (Ψ) and osmotic potential (Ψ _π) and increases in leaf conductance (g) and bulk modulus of elasticity (ε). It is likely that these physiological responses were used to generate lower Ψ while maintaining osmotic and water homeostasis. That is, by decreasing Ψ _π and increasing g and ε, more efficient water flow through the soil–plant–atmosphere continuum can be achieved, thus generating lower Ψ without promoting loss of turgor.     

Field significance of performance measures in the context of regional climate model evaluation. Part 1: temperature

A new approach for rigorous spatial analysis of the downscaling performance of regional climate model (RCM) simulations is introduced. It is based on a multiple comparison of the local tests at the grid cells and is also known as “field” or “global” significance. New performance measures for estimating the added value of downscaled data relative to the large-scale forcing fields are developed. The methodology is exemplarily applied to a standard EURO-CORDEX hindcast simulation with the Weather Research and Forecasting (WRF) model coupled with the land surface model NOAH at 0.11 ^° grid resolution. Monthly temperature climatology for the 1990–2009 period is analysed for Germany for winter and summer in comparison with high-resolution gridded observations from the German Weather Service. The field significance test controls the proportion of falsely rejected local tests in a meaningful way and is robust to spatial dependence. Hence, the spatial patterns of the statistically significant local tests are also meaningful. We interpret them from a process-oriented perspective. In winter and in most regions in summer, the downscaled distributions are statistically indistinguishable from the observed ones. A systematic cold summer bias occurs in deep river valleys due to overestimated elevations, in coastal areas due probably to enhanced sea breeze circulation, and over large lakes due to the interpolation of water temperatures. Urban areas in concave topography forms have a warm summer bias due to the strong heat islands, not reflected in the observations. WRF-NOAH generates appropriate fine-scale features in the monthly temperature field over regions of complex topography, but over spatially homogeneous areas even small biases can lead to significant deteriorations relative to the driving reanalysis. As the added value of global climate model (GCM)-driven simulations cannot be smaller than this perfect-boundary estimate, this work demonstrates in a rigorous manner the clear additional value of dynamical downscaling over global climate simulations. The evaluation methodology has a broad spectrum of applicability as it is distribution-free, robust to spatial dependence, and accounts for time series structure.