Monte Carlo evaluation of microbial-mediated contaminant reactions in heterogeneous aquifers

Monte Carlo simulations are conducted to evaluate microbial-mediated contaminant reactions in an aquifer comprised of spatially variable microbial biomass concentrations, aquifer hydraulic conductivities, and initial electron donor/acceptor concentrations. A finite element simulation model is used that incorporates advection, dispersion, and Monod kinetic expressions to describe biological processes. Comparisons between Monte Carlo simulations of heterogeneous systems and simulations using homogeneous formulation of the same two-dimensional transport problem are presented. For the assumed set of parameters, physical aquifer heterogeneity is found to have a minor effect on the mass of contaminant biodegraded/transformed when compared to a homogeneous system; however, it noticeably changes the dispersion, skewness, and peakness of contaminant concentration distributions. Similarly, for low microbial growth rate, given favorable microbial growth characteristics, biological heterogeneity has minor effect on the mass of contaminant biodegraded/transformed when compared to a homogeneous system. On the other hand, when higher effective growth rates are assumed, biological heterogeneity and spatial heterogeneities in essential electron donor/acceptors reduce the efficiency of biotic contaminant reactions; consequently, model simulations derived from heterogeneous biomass distributions predict remediation time scales that are longer than those simulated for homogeneous systems. When correlations between physical aquifer and biological heterogeneities are considered, the assumed correlation affects predicted mean and variance of contaminant concentration and biomass distributions. For example, an assumed negative correlation between hydraulic conductivity and the initial biomass distribution produces a plume where less efficient biotic contaminant reactions occur at the leading edge of the plume; this is consistent with less degradation/transformation occurring over regions of higher groundwater velocities. However, the presence and absence of these correlations do not appear to affect the efficiency of microbial-mediated contaminant attenuation.     

Crustal-scale seismic profiles across Taiwan and the western Philippine Sea

We have used combined onshore and offshore wide-angle seismic data sets to model the velocity structure of the Taiwan arc–continent collision along three cross-island transects. Although Taiwan is well known as a collisional orogen, relatively few data have been collected that reveal the deeper structure resulting from this lithospheric-scale process. Our southern transect crosses the Hengchun Peninsula of southernmost Taiwan and demonstrates characteristics of incipient collision. Here, 11-km-thick, transitional crust of the Eurasian plate (EUP) subducts beneath a large, rapidly growing accretionary prism. This prism also overrides the N. Luzon forearc to the east as it grows. Just west of the arc axis there is an abrupt discontinuity in the forearc velocity structure. Because this break is accompanied by intense seismicity, we interpret that the forearc block is being detached from the N. Luzon arc and Philippine Sea plate (PSP) at this point. Our middle transect illustrates the structure of the developing collision. Steep and overturned velocity contours indicate probable large-scale thrust boundaries across the orogen. The leading edge of the coherent PSP appears to extend to beneath the east coast of Taiwan. Deformation of the PSP is largely limited to the remnant N. Luzon arc with no evidence of crustal thickening to the east in the Huatung basin. Our northern transect illustrates slab–continent collision—the continuing collision of the PSP and EUP as the PSP subducts. The collisional contact is below 20 km depths along this transect NE of Hualien. This transect shows elements of the transition from arc–continent collision to Ryukyu arc subduction. Both of our models across the Central Range suggest that the Paleozoic to Mesozoic basement rocks there may have been emplaced as thick, coherent thrust sheets. This suggests a process of partial continental subduction followed by intra-crustal detachment and buoyancy-aided exhumation. Although our models provide previously unknown structural information about the Taiwan orogen, our data do not define the deepest orogenic structure nor the structure of western Taiwan. Additional seismic (active and passive), geologic, and geodynamic modeling work must be done to fully define the structure, the active deformation zones, and the key geodynamic process of the Taiwan arc–continent collision.     

Geochemical constraints on the origin of the Kicking Horse and Monarch Mississippi Valley-type lead-zinc ore deposits, southeast British Columbia, Canada

Two Mississippi Valley-type (MVT) ore deposits, Kicking Horse and Monarch, have been studied with the aim of comparing the ores at the two localities and to characterize the origin of the mineralizing fluids and the ore formation process(es). Both deposits are hosted by the Middle Cambrian Cathedral Formation carbonate host rocks, Kicking Horse on the north and Monarch on the south flank of the Kicking Horse valley near Field (SE British Columbia). The ore bodies are situated at the transition of (western) basinal to (eastern) shallow-water strata of the paleo-Pacific passive margin succession in the Cordilleran Foreland Province of the Western Canada Sedimentary Basin. Both deposits are related spatially to normal faults. In both localities, the ore minerals are dominated by pyrite, sphalerite, and galena. Dolomite, minor quartz, and calcite are also present in close association with the ores. The salinity (21–30 wt% NaCl eq.) and homogenization temperatures (63–182°C) measured in fluid inclusions in carbonate, quartz, and sphalerite lie within the typical range of MVT fluid conditions. The good stoichiometry (50–53 mol% CaCO₃), low δ¹⁸O values (−21 to −14‰ Vienna Peedee belemnite) and relatively high homogenization temperatures (>95°C) of the dolomite suggest the dolomites were formed under burial diagenesis. The ore-forming fluids probably interacted with siliciclastic units, based on elevated Li contents and ⁸⁷Sr/⁸⁶Sr ratios, which are highest in the dolomite type after the main ore stage. We propose that the ores formed from the mixing of a downward-infiltrating, sulfur-bearing halite-dissolution fluid with an upward-migrating, metal-rich evaporated seawater fluid, which had already undergone minor mixing with a dilute fluid.     

Geoarchaeological evidence for multidecadal natural climatic variability and ancient Peruvian fisheries

Understanding the influence of natural climatic variability on modern fisheries is complicated by over a century of industrial fishing. Archaeological data provide unique opportunities for assessing precolonial and preindustrial fisheries. Records show that anchoveta-vs sardine-dominated fisheries correlate with 20th-century climate change in the Pacific Basin and are linked to multidecadal climatic variability. The “anchovy regime” is characterized by cooler conditions and lower frequency El Niño/Southern Oscillation (ENSO) events, while the “sardine regime” is associated with warmer conditions and higher frequency ENSO. Fish remains excavated at Lo Demás, an Inca-period (ca. A.D. 1480–1540) fishing site at 13°25′S on the Peruvian coast, document a shift from an anchoveta-to a sardine-dominated fishery at about A.D. 1500. This shift correlates with records for increasing ENSO frequency at the same time. Middle and late Holocene sites have archaeofish assemblages that also suggest regime changes. Here we show that changes in fish regimes can result from natural variability and we support the potential role of archaeological assemblages in tracking multidecadal climate change in the Pacific Basin throughout the Holocene (0–11,500 cal yr B.P.).     

Amenability of nitrilotriacetic acid to biodegradation in a marine simulation

The behaviour of the detergent builder nitrilotriacetic acid (NTA) has been studied in the presence of a marine bacterial population potentially associated with a sewage discharge to coastal waters. Additions of 500 μg l^?1 NTA were made over a period of 80 days and 7500 μg l^?1 NTA over 40 days in both aerobic and anoxic environments. It was concluded that NTA was not degraded at either concentration under aerobic or anoxic conditions, despite the presence of a significant bacterial population under aerobic conditions. Possible effects of NTA recalcitrance and its accumulation in coastal marine waters are discussed.     

Fine scale distributions of porosity and particulate excessPb, organic carbon and CaCO3 in surface sediments of the deep equatorial Pacific

Sediment samples were recovered from the central equatorial Pacific Ocean, sectioned at 1-mm intervals, and analyzed for porosity, organic carbon, excess²¹⁰Pb and CaCO₃. Steep porosity gradients were measured in the upper 1 cm of the sediment column with extremely high values observed near the sediment surface. Similarly, particulate organic carbon contents are highest at the sediment surface, decrease sharply in the upper 1 cm, and are relatively constant between 1 and 5 cm. CaCO₃ values, on the other hand, are lowest at the sediment surface and increase to a constant value below 5–10 mm depth. At the carbonate ooze sites, excess²¹⁰Pb is present throughout the upper 5 cm of the sediments suggesting relatively rapid particle mixing rates. However, extremely high excess²¹⁰Pb activities (> 100 dpm/g) are observed at the sediment surface with sharp gradients present in the upper 1 cm which would suggest slow rates of mixing. This apparent contradiction along with the major features of the CaCO₃ and particulate organic carbon profiles can be explained by a particle-selective feeding mechanism in which organic carbon, excess²¹⁰Pb-enriched particles are preferentially maintained at the sediment surface via ingestion and defecation by benthic organisms.     

Regionalizing spain's continuous and discontinuous settlement

The expected increase of the world's population will be accompanied by a growth of the rural part. Some of the latter will be reflected in expansion of the inhabited area into the uninhabited. To provide knowledge for efficiency of this expansion a classification of the areally continuous and discontinuous settlement of Spain is delineated. The Continuous Settlement Region is in the north, east of a Léon-Bilbao line, north of the latitude of Toledo, and split in two by a NE-SW line through Teruel. The rest is the Discontinuous Settlement Region comprised of four occurrences of Inner Fringe Zone near the country's corners, two of the Middle Fringe Zone, and three of Outer Fringe Zone. Though new rural settling began in Spain in 1907 the principal effort has been during the past two decades under the National Colonization Institute whose work has been concentrated in the Inner Fringe Zone. It is there that continuing study is needed to provide guides for new rural settling elsewhere in the world.