Discriminating between background and mine-impacted groundwater at the Phoenix mine,Nevada USA

Differentiating between mineralized and non-mineralized background groundwater chemistry at a mine site can be challenging if there is an overprint of past and/or current mining on naturally mineralized conditions. At the Phoenix mine in the Copper Canyon mining district of Nevada, quantile–quantile H⁺/SO₄ plots were used to segregate four wells clearly impacted by historical mining activity. The mineralogy of rock at the elevation of the well screen interval was used to partition the 53 remaining wells into mineralized and non-mineralized populations. For each class, groundwater chemistry was examined to identify if SO₄ and H⁺ trends were stable (unimpacted) or increasing (impacted). Then each well was mapped as one of four resulting groundwater types across the mine site, defining the spatial extent of the different groups. Several groundwater regions were identified. A group of mineralized, mine-impacted wells (Type II) are located in Philadelphia Canyon adjacent to the Cu leach facility, with the anthropogenically impacted area bounded by several hydrologically downgradient, mineralized, unimpacted wells (Type I) to the south and east. There is a set of non-mineralized, impacted wells (Type III) downgradient from the tailings pond facility, where a historical release of SO₄ is apparent in the well record. However, in some downgradient wells the tailings pond pump-back mitigation system has resulted in recovery of the groundwater quality to a non-mineralized background condition. Finally, in the vicinity of the Reona heap leach pad, there is a group of non-mineralized, unimpacted wells (Type IV). Not surprisingly, most mineralized wells (Types I and II) are located in or near mined areas, while non-mineralized wells (Types III and IV) tend to be in the southern portion of the facility in the alluvia of Buffalo and Reese River valleys.     

Macroscopic and spectroscopic analysis of lanthanide adsorption to bacterial cells

This study was designed to combine surface complexation modelling of macroscopic adsorption data with X-ray Absorption Spectroscopic (XAS) measurements to identify lanthanide sorption sites on the bacterial surface. The adsorption of selected representatives for light (La and Nd), middle (Sm and Gd) and heavy (Er and Yb) lanthanides was measured as a function of pH, and biomass samples exposed to 4 mg/L lanthanide at pH 3.5 and 6 were analysed using XAS. Surface complexation modelling was consistent with the light lanthanides adsorbing to phosphate sites, whereas the adsorption of middle and heavy lanthanides could be modelled equally well by carboxyl and phosphate sites. The existence of such mixed mode coordination was confirmed by Extended X-ray Absorption Fine Structure (EXAFS) analysis, which was also consistent with adsorption to phosphate sites at low pH, with secondary involvement of carboxyl sites at high adsorption density (high pH). Thus, the two approaches yield broadly consistent information with regard to surface site identity and lanthanide coordination environment. Furthermore, spectroscopic analysis suggests that coordination to phosphate sites is monodentate at the metal/biomass ratios used. Based on the best-fitting pK_a site, we infer that the phosphate sites are located on N-acetylglucosamine phosphate, the most likely polymer on gram-negative cells with potential phosphate sites that deprotonate around neutral pH.     

Particle acceleration by ultrarelativistic shocks: theory and simulations

We consider the acceleration of charged particles near ultrarelativistic shocks, with Lorentz factor     . We present simulations of the acceleration process and compare these with results from semi-analytical calculations. We show that the spectrum that results from acceleration near ultrarelativistic shocks is a power law,     , with a nearly universal value     for the slope of this power law.
We confirm that the ultrarelativistic equivalent of the Fermi acceleration at a shock differs from its non-relativistic counterpart by the occurrence of large anisotropies in the distribution of the accelerated particles near the shock. In the rest frame of the upstream fluid, particles can only outrun the shock when their direction of motion lies within a small loss cone of opening angle     around the shock normal.
We also show that all physically plausible deflection or scattering mechanisms can change the upstream flight direction of relativistic particles originating from downstream by only a small amount:     . This limits the energy change per shock crossing cycle to     , except for the first cycle where particles originate upstream. In that case the upstream energy is boosted by a factor     for those particles that are scattered back across the shock into the upstream region.     

High-temperature flares observed in broadband soft X-rays

Broadband soft solar X-rays monitored by the GOES satellites have been used to detect high-temperature flares (> 25 MK). The data suggest that there are two general categories of high-temperature flares: those that are intrinsically hot and recur repeatedly in particular active regions and those that show enhanced temperatures because of their proximity to the solar limb. Intrinsically hot flares associate with gamma-ray flares and impulsive hard X-ray flares. Hot flares show a small incidence with gradual hard X-ray flares, but those cases are either extremely intense flares or limb flares. The apparently hot flares occur near the visible limb, which suggests the strong thermal stratification of flare plasmas as demonstrated by over-the-limb events; even on the visible disk near the limb, the lower, cooler plasmas are somehow partially occulted.     

The reversal of the solar polar magnetic fields

Some theoretical difficulties confronting the current model of the polar magnetic reversal by cancellation with the flux remnants of decaying active regions are discussed. It is shown that the flux transport equation does not adequately describe the essential physical consequences of the transport of large-scale fields, linked to deep subsurface toroids, over distances comparable with the solar radius. The possibility that subsurface reconnections may release these fields to form U-loops is discussed but it is shown that, in this event, the loops will quickly rise to the surface. Mechanisms whereby the flux may escape through the surface are considered.     

Orbit of the Murchison meteorite

Abstract— Because the path of the Murchison meteorite fortuitously intersected the Earth's path at an angle of only a few degrees, the visual observations establish the entry velocity to be within 2 km/s of 13 km/s and determine the nature of its orbit with a precision quite unusual for visually sighted falls.     

The reversal of the solar polar magnetic fields

Observations of the first large-scale patterns of magnetic fields near the sunspot minimum of 1986 (the start of cycle 22) are presented using synoptic magnetic data provided by the National Solar Observatory and contour maps constructed from data provided by the Mount Wilson Solar Observatory. The latter are compared with simulated contour maps derived from numerical solutions of the flux transport equation using data from particular Carrington rotations as initial conditions.The simulated evolutions of the large-scale magnetic fields are qualitatively consistent with observed evolutions, but differ in several significant respects. Some of the differences can be removed by varying the diffusivity and the parameters of the large-scale velocity fields. The remaining differences include: (i) the complexity of fine structure, (ii) the response to differential rotation, (iii) the evolution of decaying active regions, and (iv) the emergence of new elements in the weak, large-scale fields independent of the evolution of the observed active regions.It is concluded that the patterns of weak magnetic fields which comprise the large-scale features cannot be formed entirely by the diffusive decay of active regions. There must be a significant contribution to these patterns by non-random flux eruptions within the network structure, independent of active regions.     

Structure of the Venus mesosphere and lower thermosphere from measurements during entry of the pioneer Venus probes

Data on the thermal structure of the nightside middle atmosphere of Venus, from 84 to 137 km altitude, have been obtained from analysis of deceleration measurements from the third Pioneer Venus small probe, the night probe, which entered the atmosphere near the midnight meridian at 27°S latitude. Comparison of the midnight sounding with the morning sounding at 31°S latitude indicates that the temperature structure is essentially diurnally invariant up to 100 km, above which the nightside structure diverges sharply from the dayside toward lower temperatures. Very large diurnal pressure differences develop above 100 km with dayside pressure ten times that on the nightside at 126 km altitude. This has major implications for upper atmospheric dynamics. The data are compared with the measurements of G. M. Keating, J. Y. Nicholson, and L. R. Lake (1980, J. Geophys. Res., 85, 7941–7956) above 140 km with theoretical thermal structure models of Dickinson, and with data obtained by Russian Venera spacecraft below 100 km. Midnight temperatures are ～ 130°K, somewhat warmer than those reported by Keating et al.     

Three-dimensional strain produced by >50 My of episodic extension, Horse Prairie basin area, SW Montana, U.S.A.

The Horse Prairie basin of southwestern Montana is a complex, east-dipping half-graben that contains three angular unconformity-bounded sequences of Tertiary sedimentary rocks overlying middle Eocene volcanic rocks. New mapping of the basin and its hanging wall indicate that five temporally and geometrically distinct phases of normal faulting and at least three generations of fault-related extensional folding affected the area during the late Mesozoic (?) to Cenozoic. All of these phases of extension are evident over regional or cordilleran-scale domains. The extension direction has rotated 90° four times in the Horse Prairie area resulting in a complex three-dimensional strain field with 60% east–west and >25% north–south bulk extension. Extensional folds with axes at high angles to the associated normal fault record most of the three-dimensional strain during individual phases of extension (phases 3a, 3b, and 4). Cross-cutting relationships between normal faults and Tertiary volcanic and sedimentary rocks constrain the ages of each distinct phase of deformation and show that extension continued episodically for more than 50 My. Gravitational collapse of the Sevier fold and thrust belt was the ultimate cause of most of the extension.