Aenigmatite,sodic pyroxene,arfvedsonite and associated minerals in syenites from Morotu,Sakhalin

Aenigmatite, sodic pyroxene and arfvedsonite occur as interstitial minerals in metaluminous to weakly peralkaline syenite patches in alkali dolerite, Morotu, Sakhalin. Aenigmatite is zoned from Ca, Al, Fe³⁺-rich cores to Ti, Na, Mn, Si-rich rims reflecting the main substitutions Fe²⁺Ti⁴⁺Fe³⁺, NaSiCaAl and Mn²⁺Fe²⁺. Aenigmatite replaces aegirine and ilmenite supporting the existence of a no-oxide field in — T space. In one case aenigmatite has apparently formed by reaction between ilmenite and arfvedsonite. Titanian aegirine (up to 3.0 wt% TiO₂) and Fe-chlorite may replace aenigmatite. Sodic pyroxene occurs as zoned crystals with cores of aegirine-augite rimmed by aegirine and in turn by pale green aegirine containing 93 mol% NaFe³⁺Si₂O₆. Additional substitution of the type NaAlCaFe²⁺ is indicated by significant amounts (up to 6 mol%) of NaAlSi₂O₆. Arfvedsonite is zoned with rims enriched in Na, Fe and depleted in Ca which parallels the variation of these elements in the sodic pyroxenes.The high peralkalinity of the residual liquid from which the mafic phases formed resulted from the early crystallization of microperthite (which makes up the bulk of the syenites) leading to an increase in the Na₂O/(Na₂O+K₂O) and (Na₂O+K₂O)/Al₂O₃ ratios of the remaining interstitial liquid which is also enriched in Ti, Fe, and Mn. Bulk composition of the melt, , temperature and volatile content were all important variables in determining the composition and stability of the peralkaline silicates. in the residual liquid appears to have been buffered by arfvedsonite-aegirine and later by the arfvedsonite-aenigmatite and aenigmatite-aegirine equilibria under conditions of a no-oxide field. An increase in , above that of the alkali buffer reactions, is inferred by an increase of Ti and Mn in aenigmatite rims. The latest postmagmatic vapour crystallization stage of the syenites is marked by extremely low which may have been facilitated by exsolution of a gas phase. Low is supported by the replacement of aenigmatite by titanian aegirine, and the formation of rare Ti-rich garnet with a very low (Ti⁴⁺+Fe³⁺)/(Ti+Fe) ratio of 0.51, associated with leucoxene alteration of ilmenite.     

Comparison of surface current variations observed by TOPEX altimeter with TOLEX-ADCP data

Variations of surface current velocity derived by the TOPEX altimeter are compared with data from Tokyo-Ogasawara Line Experiment (TOLEX)-Acoustic Doppler Current Profiler (ADCP) monitoring for a period from October 1992 to July 1993. Since the locations of ADCP ship track and TOPEX altimeter ground tracks do not coincide with each other, and the temporal and spatial sampling are also different between the ADCP and altimeter observations, re-sampling, interpolation and smoothing in time and space are needed to the ADCP and altimeter data. First, the interpolated TOPEX sea surface height is compared with sea level data at Chichijima in the Ogasawara Islands. It is found that aliasing caused by the tidal correction error for M2 constituent in the TOPEX data is significant. Therefore, comparison of the TOPEX data with the TOLEX-ADCP data is decided to be made by using cross-track velocity components of the surface current, which are considered to be relatively less affected by the errors in the tidal correction. The cross-track velocity variations derived from the TOPEX sea surface heights agree well with those of the ADCP observations. The altimeterderived velocity deviations associated with transition of the Kuroshio paths coincide with the ADCP data. It is quantitatively confirmed that the TOPEX altimeter is reliable to observe the synoptic variations of surface currents including fluctuations of the Kuroshio axis.     

New type of pycnostad in the western subtropical-subarctic transition region of the North Pacific: Transition Region Mode Water

A new type of pycnostad has been identified in the western subtropical-subarctic transition region of the North Pacific, based on the intensive hydrographic survey carried out in July, 2002. The potential density, temperature and salinity of the pycnostad were found to be 26.5–26.7 σ _θ , 5°–7°C and 33.5–33.9 psu respectively. The pycnostad is denser, colder and fresher than those of the North Pacific Central Mode Water and different from those of other known mode waters in the North Pacific. The thickness of the pycnostad is comparable to that of other mode waters, spreading over an area of at least 650 × 500 km around 43°N and 160°E in the western transition region. Hence, we refer to the pycnostad as Transition Region Mode Water (TRMW). Oxygen data, geostrophic current speed and climatology of mixed layer depth in the winter suggest that the TRMW is formed regularly in the deep winter mixed layer near the region where it was observed. Analysis of surface heat flux also supports the idea and suggests that there is significant interannual variability in the property of the TRMW. The TRMW is consistently distributed between the Subarctic Boundary and the Subarctic Front. It is also characterized by a wide T-S range with similar density, which is the characteristic of such a transition region between subtropical and subarctic water masses, which forms a density-compensating temperature and salinity front. The frontal nature also tends to cause isopycnal intrusions within the pycnostad of the TRMW.     

North Pacific Tropical Water: its climatology and temporal changes associated with the climate regime shift in the 1970s

North Pacific Tropical Water (NPTW) is characterized as a subsurface salinity maximum flowing in the North Equatorial Current and is the main source of salt for the North Pacific. We briefly describe the climatological features of its formation and circulation, and then examine temporal changes in its properties associated with the climate regime shift in the 1970s. We use a variety of data, which include the repeat hydrographic sections along 130°E, 137°E, 144°E and 155°E meridians, the hydrographic data from the Hawaii Ocean Time-series, the World Ocean Atlas 1994, and available gridded data of wind stress and evaporation. The classical idea that NPTW originates from the zone of the highest sea surface salinity at 20°–30°N centered around the international date line and spreads along the isopycnal geostrophic flow patterns is confirmed. Further, it is shown that the meridional extent of NPTW along 137°E is from 10°N to 23°N on average and the highest salinity core lies at about 15°N and 24.0σ_θ, and that the portion of NPTW north (south) of about 15°N originates from the formation region west (east) of the date line. NPTW in the 137°E section changed remarkably associated with the mid-1970s regime shift. North of 15°N NPTW increased both in its salinity and thickness while to the south of 15°N only its salinity increased and its thickness remained unchanged. The westward geostrophic velocity is increased significantly in both the southern and northern parts of NPTW. The northern thickening and speedup and the southern speedup increased NPTW transport across 137°E. The changes in the thermohaline forcing such as evaporation and Ekman salt convergence in the NPTW formation region possibly contributed to the increases in salinity in the southern part of NPTW, but not to that of the northern part. On the other hand, the increased Ekman pumping accounts for the increase of the NPTW inventory and transport at 137°E. The increased salinity of NPTW at 137°E, especially its northern portion, was presumably caused by an increase in its formation rate rather than changes in the sea surface salinity in its formation region; the thicker the NPTW layer is, the saltier is the core that tends to survive the mixing processes.     

Ventilation of the North Pacific subtropical pycnocline and mode water formation

The annual subduction rate of the North Pacific was calculated based on isopycnally averaged hydrographic climatology (HydroBase), high-resolution winter mixed-layer climatology (NWMLC), and various wind stress climatologies from ship reports, numerical weather prediction products, and satellite products. The calculation was performed using Lagrangian coordinates in the same manner as in previous works, except a less smoothed oceanic climatology (HydroBase and NWMLC) was used instead of a World Ocean Atlas. Differences in the wind stress climatologies have very little effect on subduction rate estimates. The subduction rate census for density classes showed peaks corresponding to subtropical mode water (STMW), central mode water (CMW), and eastern subtropical mode water (ESTMW). The deeper mixed layer and the associated sharper mixed-layer fronts in the present climatology resulted in a larger lateral induction, which boosted the subduction rate, especially for the potential density anomaly (σ_θ) range of the lighter STMW (25.0 < σ_θ < 25.2 kg m⁻³) and lighter CMW (26.0 < σ_θ < 26.2 kg m⁻³), compared to previous estimates. The renewal time of permanent pycnocline water was estimated as the volume of water divided by the subduction rate for each σ_θ class: 2–4 years for ESTMW (24.5 < σ_θ < 25.2 kg m⁻³), 2 years for the lighter STMW (25.0 < σ_θ < 25.3 kg m⁻³), 5–9 years for the denser STMW (25.3 < σ_θ < 25.6 kg m⁻³), 10–20 years for the lighter CMW (26.0 < σ_θ < 26.2 kg m⁻³), 20–30 years for the middle CMW (26.2 < σ_θ < 26.3 kg m⁻³), and 60 years or longer for the denser CMW (26.3 < σ_θ < 26.6 kg m⁻³). A comparison of the water volume and subduction rate in potential temperature–salinity (θ–S) space indicated that the upper permanent pycnocline water (25.0 < σ_θ < 26.2 kg m⁻³) was directly maintained by nondiffusive subduction of winter surface water, including STMW and lighter CMW. The lower permanent pycnocline water (26.2 < σ_θ < 26.6 kg m⁻³) may be maintained through the subduction of fresher and colder water from the subarctic–subtropical transition region and subsequent mixing with saltier and warmer water. Diagnosis of the potential vorticity (PV) of the subducted water demonstrated that the low PV of STMW was mainly due to the large subduction rate, whereas that of both ESTMW and CMW was due mainly to the small density advection rate (cross-isopycnal flow). Additionally, a relatively large subduction rate probably contributes to the low PV of part of the lighter CMW (ESTMW) formed in the region around 38°N and 170°W (28°N and 145°W), which is characterized by a relatively thick winter mixed layer and an associated mixed-layer front, causing a large lateral induction rate.     

Distribution of heterotrophic nanoflagellates and their importance as the bacterial consumer in a eutrophic coastal seawater

Seasonal and vertical changes in abundances of bacteria and heterotrophic nanoflagellates (HNF), and HNF grazing on bacteria were investigated in a small eutrophic inlet of Uranouchi-Wan throughout the years. Bacterial densities in the surface water ranged from 1.2 to 11 (average 4.3)×10⁶ cells ml^–1 with a couple of maxima following the algal blooming. Densities of HNF ranged from 0.54 to 73 (average 16.4)×10³ cells ml^–1 in the surface, and showed almost similar fluctuation pattern to that of bacteria with a time lag of about 1 to 2 weeks. Grazing rates of HNF on bacteria obtained by FLB method were 4.78 to 16.9 (average 10.3±SD 4.8) cells HNF^–1h^–1 in the surface layer in summer, and consequent total bacterial consumption rates by HNF fluctuated from 4 to 99×10⁴ cells ml^–1h^–1. In deeper layers, however, as HNF densities and grazing rates on bacteria were low, the grazing pressure of HNF on bacteria was small. Turnover times of bacteria by HNF grazing in the surface layer were calculated as relatively constant values of 40 to 60 h, however, it decreased to as low as 6 to 7 h when the HNF activity was highest. These results indicate that bacteria grew so actively by consuming organic matter in seawater as to compensate high HNF grazing pressure, and that bacteria and HNF in the microbial loop play important roles on the turnover of substrates in coastal ecosystems.     

Correlation between dissolved He concentration and Cl in groundwater at Äspö, Sweden

Tunnel excavation at Äspö Island, Sweden, has caused severe groundwater disturbance, gradually extending deeper into the tunnel as present-day Baltic seawater intrudes through fractures connecting to the surface. However, the paleo-hydrogeochemical conditions have remained in the deep highly saline waters that have avoided mixing. A correlation has been observed between dissolved ⁴He concentration and Cl⁻ ion concentration, measured every two years from 1995 to 2001 at Äspö. Groundwater mixing conditions can be examined by the correlations between 1/Cl, ³⁶Cl/Cl, and ³H concentrations. Subsurface production is responsible for the majority of the ³⁶Cl and excess dissolved ⁴He of interstitial groundwater in fractures. The secular equilibrium ratio of ³⁶Cl/Cl in rock was theoretically estimated to be (5.05 ± 0.82) × 10⁻¹⁴ based on the neutron flux intensity, a value comparable to the measured ³⁶Cl/Cl ratio in rock and groundwater. The degassing crustal ⁴He flux was estimated to be 2.9 × 10⁻⁸  1.3 × 10⁻⁶ (ccSTP/cm²a) using the HTO diffusion coefficient for the Äspö diorite. The ⁴He accumulation rate ranges from 6.8 × 10⁻¹⁰ (for the in situ accumulation rate) to 7.0 × 10⁻⁹ (ccSTP/(g_water · a) considering both ⁴He in situ production and the degassing flux, assuming ⁴He is accumulated constantly in groundwater. By comparing the subsurface ³⁶Cl increase with ⁴He concentrations in groundwater, the ⁴He accumulation rate was determined from data for groundwater arriving at the secular equilibrium of ³⁶Cl/Cl. The ⁴He accumulation rate was found to be (1.83 ± 0.72) × 10⁻⁸ ccSTP/(g_water · a) without determining the magnitude of degassing ⁴He flux.     

Interannual variations in the Hawaiian Lee Countercurrent

The Hawaiian Lee Countercurrent (HLCC) is an eastward surface current flowing against the broad westward flow of the North Pacific subtropical circulation. Analyses of satellite altimeter data over 16 years revealed that the HLCC is characterized by strong interannual variations. The strength and meridional location of the HLCC axis varied significantly year by year. The eastward velocity of the HLCC was higher when the location of the axis was stable. Mechanisms for the interannual variations were explored by analyses of the altimeter data and results from a simple baroclinic model. The interannual variations in the strength of the HLCC did not correlate with those of the wind stress curl (WSC) dipole formed on the leeward side of the Hawaii Islands, although the WSC dipole has been recognized as the generation mechanism of the HLCC. Meridional gradients of the sea surface height anomaly (SSHA) across the HLCC generated by baroclinic Rossby waves propagating westward from the east of the Hawaii Islands were suggested as a possible mechanism for the interannual variations in the HLCC. The spatial patterns in the observed SSHAs were reproduced by a linear baroclinic Rossby wave model forced by wind fields from a numerical weather prediction model. Further analysis of the wind data suggested that positive and negative anomalies of WSC associated with changes in the trade winds in the area east of the Hawaii Islands are a major forcing for generating SSHAs that lead to the HLCC variations with a time lag of about 1 year.     

Anticyclonic Eddy Revealing Low Sea Surface Temperature in the Sea South of Japan: Case Study of the Eddy Observed in 1999–2000

Various kinds of datasets, such as satellite-derived sea surface temperature (SST), sea surface height, surface velocity produced by combining surface drifter and satellite altimeter data, and hydrographic data, led to the discovery of an anticyclonic eddy with lower SST than those of surrounding waters in the Kuroshio recirculation region south of Shikoku, as if the eddy were cyclonic. This anticyclonic eddy was formed east of Kyushu in late August to early September 1999 from the merger of two anticyclonic eddies which had migrated in the recirculation region to the sea south of Japan from the east. After the merger, the anticyclonic eddy strengthened abruptly and began to exhibit the low SST. In October, this eddy coalesced with the Kuroshio and moved swiftly eastward, accompanied by an amplitude growth of the Kuroshio meander. In mid November, off the Kii Peninsula, the eddy detached from the meandering Kuroshio. It then moved southwestward and again slowly propagated westward along the 30°N line. During this period, at least from late October 1999 to January 2000, SSTs over the anticyclonic eddy were found to be continuously lower than those of surrounding waters. This case tells us that we have to pay careful attention to the interpretation of mesoscale SST distributions. This revised version was published online in July 2006 with corrections to the Cover Date.